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    Simulation of a 10000 bbl/day G.T.L. plant

    , Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 KheradRanjbar, R ; Gholamtamimi, M ; Hayati, R ; Sobati, M. A ; Sharif University of Technology
    2008
    Abstract
    Gas-to-Liquid (GTL) is a multi-staged process in which natural gas is converted to liquid fuels. The stages of GTL process are discussed. A GTL plant with 10,000 bpd capacity and have similar specifications with the SASOL process was simulated using the Aspen-Plus software and the simulation results were compared with the SASOL process data. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering (Prague, Czech Republic 8/24-28/2008)  

    Nanodeposition and characterization of cobalt particles inside synthesized faujasitic support for preparing a catalyst for fischer-tropsch reaction

    , Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 Fotovat, F ; Kazemian, H ; Kazemeini, M ; Sharif University of Technology
    2008
    Abstract
    The importance of the gas-to-liquid process is increasing due to growing demand for a high quality, less expensive, and cleaner fuel. Faujasite zeolites, e.g,. zeolites type X and Y, are well-known catalysts in the petrochemical industry. Faujasitic supports (mainly X zeolites) were prepared via hydrothermal synthesis with different Si/Al ratios from pure chemical materials and fly ash as a source of silicon. A high quantity of cobalt oxides was deposited on supports by varying samples Si/Al ratios during the zeolite preparation procedure. Using fly ash in synthesizing the zeolitic support resulted in a A-X zeolite material with a very high cation exchange capability and final cobalt... 

    Metal promoted mordenite catalyst for methanol conversion into light olefins

    , Article Petroleum Science and Technology ; Vol. 32, Issue. 11 , 2014 , Pages 1349-1356 ; ISSN: 10916466 Shareh, F. B ; Kazemeini, M ; Asadi, M ; Fattahi, M ; Sharif University of Technology
    Abstract
    Methanol conversion was investigated on dealuminated mordenite (DM) as well as a series of promoted DM (i.e., metal/DM) catalysts prepared by impregnation. Prepared catalysts characterized by the powder XRD, BET, and NH3-TPD techniques. Chemical analysis was performed using induced coupled plasma (ICP) method. The conversion of methanol over different metal/mordenite catalysts was compared at 460C and WHSV of 1 h-1. Several metals including Fe, La, and Ca had been used to prepare metal/DM catalysts, which displayed high selectivity toward propylene production. Ultimately, La/DM catalyst was determined to be the best material amongst those investigated for methanol conversion based upon its... 

    Optimizing Structure of Catalysts and Development of Kinetic Parameters for Synthesis Gas to Olefin Reaction

    , Ph.D. Dissertation Sharif University of Technology Shayegh, Flora (Author) ; Ghotbi, Siroos (Supervisor) ; Bozorg Mehri, Ramin (Supervisor) ; Zarrinpashne, Saeid (Supervisor)
    Abstract
    Synthesis gas to light olefin reactions especially propylene production is one of the important path for clean fuel production in gas conversion processes. The object of this study is to define true kinetic model of process first step (e.g. Synthesis gas to light Olefins). For that, kinetic model for Co/Mn/TiO2 catalyst, which has the best conversion and selectivity for propylene, has been developed. Kinetic reaction parameters were measured by kinetic modeling in (220-300)0C temperature , (1-5)bar pressure , H2/CO=(1:3) and (450-600)hr-1 space velocity .After studying with significant models ,the best fitting can obtained with "KPCO P 1/2H2/(1+aPco+bPH2 1/2)2"equation. Later to... 

    Performance Evaluation of H-ZSM-5 Catalyst Improved With Boron in Methanol to Propylene Process

    , M.Sc. Thesis Sharif University of Technology Ahmadpour, Somayeh (Author) ; Khorasheh, Farhad (Supervisor)
    Abstract
    Propylene is one of the key material in petrochemical industries. In recent years, as propylene demand increases, development of new methods alongside traditional ways in production of propylene seems essential. The production of propylene from methanol using zeolitic catalysts is as one of this new methods. This method in recent years has got attention. H-ZSM-5 zeolite is one of the best catalysts appropriate for this process. However, rapid deactivation is the main problem this catalyst at the present time. Therefore, more research in order to increase stability and lifetime has been performed. The uses of promoters are as one of the simplest improvement methods of H-ZSM-5 zeolite.... 

    Light olefin production on the Co-Ni catalyst: Calcination conditions, and modeling and optimization of the process conditions by a statistical method

    , Article New Journal of Chemistry ; Volume 44, Issue 18 , 2020 , Pages 7467-7483 Arsalanfar, M ; Akbari, M ; Mirzaei, N ; Abdouss, M ; Sharif University of Technology
    Royal Society of Chemistry  2020
    Abstract
    The present work is comprised of two main parts. In part 1 the Co-Ni/γ-Al2O3 catalyst was prepared using a sol-gel procedure. Then the effect of calcination variables including the calcination temperature and time on the catalytic performance for production of light olefins was investigated and optimized. The obtained results have shown that the catalyst which was calcined at 550 °C for 6 h has revealed the better catalytic performance for production of light olefins. In part 2 the effect of process conditions including the reaction temperature, H2/CO feed ratio and total reaction pressure on the catalytic performance (CO conversion%, (C2-C4) selectivity% and C5+ selectivity%) was... 

    Effect of operation conditions on the catalytic performance of the Co/Mn/TiO2 catalyst for conversion of synthesis gas to light olefins

    , Article Scientia Iranica ; Volume 17, Issue 2 C , November , 2010 , Pages 168-176 ; 10263098 (ISSN) Shayegh, F ; Ghotbi, C ; Bozorgmehry Boozarjomehry, R ; Rashtchian, D ; Sharif University of Technology
    Abstract
    The effect of operation variables, such as the H2/CO molar feed ratio, gas hourly space velocity (GHSV), temperature, and pressure, on the catalytic performance of the Co/Mn/TiO2 catalyst prepared at the Research Institute of the Petroleum Industry (RIPI) was investigated, and optimum reactor conditions were obtained to produce the maximum amount of light olefins. The catalyst was prepared by co-precipitation of Co and Mn phases in the presence of commercial TiO2 with maximum selectivity for ethylene and propylene production. It was found that the [H2]/[CO]=2/1, space velocity (GHSV) of 1800 h-1, 280°C temperature and 4 bar pressure were optimum operating conditions for the modified catalyst...