Sharif Digital Repository

Drop size distribution plays a key role in the liquid extraction systems and related hydrodynamic and mass transfer parameters. In current research work, the size of drops in an extraction spray column has been measured by direct photography method, and the Sauter mean diameter has been obtained accordingly. Then, two types of models are assessed based on using dimensionless analysis and appropriate software. The interfacial tension in used chemical system is 1.8-32 dyne/cm. In first type of models, the correlation is established based on dimensionless parameters similar to approaches defined by other researchers. In second types, dimensional parameters have been used and therefore a new... 

Stagewise forward mixing model considering coalescence and redispersion of drops was used to predict the performance of Rotating Disc Liquid-Liquid Extraction Contactors. Experimental data previously obtained in two RDC columns of 7.62 cm diameter, 73.6cm height and 21.9cm diameter, 150cm height were used to evaluate the model predictions. Drop-side mass transfer coefficients were predicted applying Handlos-Baron drop model and Olney's model was used to predict drop velocities. According to the results obtained the followings could be concluded: (1) If the height of coalescence and redispersion i.e.: h = h pφp /φ could be estimated, the stagewise forward mixing with coalescence and... 

Due to substantial impacts of nanoparticles on mass and heat transfer, having knowledge about different types of nanoparticles can contribute to access high efficiencies. As an investigation, in the present study, a number of liquid-liquid extraction experiments were designed by the use of Taguchi design model in order to study the impacts of SiO2 and MgO nanoparticles on mass transfer, in the batch systems. Acetic acid was considered as solute in some organic phases (i.e., n-butanol, n-butyl acetate, toluene, and chloroform), and pure water was applied as solvent. Taguchi experiment design method made more precision and convenience in the work. Final results showed reduction of mass... 

An experimental study was conducted to investigate the extraction of oxidized sulfur compounds from gas oil. Solvents used for this purpose included acetone, acetonitrile, methanol and propanol. The effect of solvent concentration, solvent to gas oil ratio, temperature, time and number of stages was studied. To select the best solvent and conditions for extraction, two criteria were considered: high desulfurization and more hydrocarbon recovery. Results showed that extraction time and temperature have no significant effect. Methanol for low ability of extraction of oxidized sulfur compounds and propanol for low hydrocarbon recovery were excluded from further experiments. After the tests, the... 

In this research mass transfer coefficient under jetting regime in different directions (from dispersed to continuous and continuous to dispersed phase) has been studied using an experimental setup. n-Butanol-succinic acid-water with low interfacial tension has been selected as experimental chemical system. The effects of various parameters such as jet velocity, nozzle diameter and the height of the continuous phase above the nozzle, on mass transfer coefficient have been investigated. A correlation has also been derived in order to predict the mass transfer coefficient as a function of physical properties of both phases and aforementioned parameters. Based on the experimental results, mass... 

Hydrophobic titania nanoparticles were synthesized by a novel in situ sol-gel method and applied in a single drop liquid-liquid extraction column to enhance the overall dispersed-phase mass transfer coefficient (Kod). The chemical system of toluene, acetic acid and water was used, and the direction of solute (acetic acid) mass transfer was from dispersed phase, including: toluene and acetic acid to the continuous phase of water. For such system, much of the mass transfer resistance exists in the dispersed phase, which is nonpolar organic liquid. Hence, modified titania nanoparticles (MTNP's), prepared by sol-gel route, in five different concentrations of 0.001–0.005 wt.% were added in the... 

Effect of alkaline metal salts on the solvent extraction of platinum from leached spent dehydrogenation catalysts (Pt/Al2O3) in aqua-regia by the Trioctylphosphine oxide (TOPO) has been investigated. Best salting out effect was achieved using KCl as the additive salt in which process upto 90% of Platinum extraction achieved. Response Surface methodology utilized in order to design the experiments, model the extraction process for platinum and aluminum as well as; optimize the whole process. It was shown that solvent extraction of platinum by TOPO was kinetically fast and the needed equilibrium time for it was less than 30 seconds. In the present study, proposed models for platinum and... 

An experimental study was conducted on the desulfurization of non-hydrotreated kerosene with oxidation followed by liquid-liquid extraction. Various types of solvents including acetonitrile, methanol, and ethanol have been examined in the extraction of oxidized sulfur-containing compounds of kerosene. The performance of these solvents has been carefully examined and compared. It was found that their performance follows the order: acetonitrile > methanol > ethanol. The effects of number of extraction stages and solvent to kerosene ratio on the desulfurization and recovery of kerosene have been investigated. The experimental results show that for all three solvents, solvent/kerosene ratio and... 

Mass transfer rates to the drops in liquid-liquid extraction equipment are often likely to be reduced by the presence of surface active contaminants. This reduction in mass transfer is said to be due to a reduction in terminal velocity, and to changes in pattern of internal circulation. A single-drop extraction apparatus was used to investigate the dependency of mass transfer coefficient on the amount of surfactant added in a system of n-butanol/succinic acid/water. Three types of surfactants, SDS, DTMAC and Triton X-100, were used to study their effects on the inhibition of mass transfer in liquid-liquid extraction. The effect of surfactants concentration on extraction percentage, overall... 

A two impinging-jets contacting device (TIJCD) for liquid-liquid extraction processes was proposed and tested through the standard test system recommended by the European Federation of Chemical Engineering (EFCE), toluene-acetone-water, as a typical example of liquid-liquid extraction processes. The results obtained for the overall volumetric mass transfer coefficient (capacity coefficient) were more than three times higher than those reported in the conventional contactors and in an air-driven two impinging-streams contactor. These experimental results clearly indicate the greater performance capability of TIJCD relative to those of conventional contactors. To have a perfect study on the... 

Supercritical fluid extraction (SFE) is a relatively new separation technique that has received much attention in recent years. This process is an alternative to distillation or liquid extraction. Its main advantage over the conventional ones is that the dissolved extract may be completely separated from the supercritical fluid simply by decreasing the pressure. In recent years considerable effort has been devoted to the measurement of equilibrium solubility data for solids in supercritical fluids. A coal tar distillate, anthracene oil, which contains 34.46 mass-% phenanthrene, 33.8 mass-% anthracene, 13.89 mass-% carbazole and other impurities, was used as the model mixture. In this study,... 

In this article, droplet size and its distribution along a pulsed liquid-liquid extraction column, is studied where SiO2 nanoparticles with concentrations of 0.01, 0.05 and 0.1vol.% and different hydrophobicities are applied to the dispersed phase. Using ultrasonication, nanoparticles were dispersed in kerosene as the base fluid. Nanofluids' stability was ensured using a UV-vis spectrophotometer. Some 22,000 droplets were measured by photographic technique and results were compared with systems containing no-nanoparticles (Water-Acetic acid-Kerosene). Addition of nanoparticles changed the droplet shape from ellipsoidal to spherical. Also, there was a marked influence on droplet breakage and... 

This article investigates the effect of nanoparticles on mass transfer in the liquid–liquid extraction for the chemical system of n-butanol–succinic acid–water. For this purpose, nanofluids containing various concentrations of ZnO, carbon nanotubes (CNT), and TiO2 nanoparticles in water, as base fluid, were prepared. To examine the flow mode effect on mass transfer rate, different fluid modes including dropping and jetting were employed in the process. Results show that mass transfer rate enhancement depends on the kinds and the concentration of nanoparticles and the modes of flow. It was observed that after adding nanoparticles, the mass transfer rate significantly increases up to two-fold... 

The desulfurization of non-hydrotreated gas oil using oxidation followed by liquid/liquid extraction has been studied. The solvent extraction of oxidized sulfur- containing compounds of gas oil was carried out by utilizing various types of solvents, including acetonitrile, methanol, and 96 vol.-% ethanol. The performance of these solvents was carefully evaluated and compared by considering both desulfurization and gas oil recovery. It was found that their performance follows the order: acetonitrile > methanol > 96 vol.-% ethanol. The influences of operating conditions, such as number of extraction stages and solvent to gas oil ratio, on the desulfurization and recovery of gas oil, were... 

The impact of modified magnetite nanoparticles (MMNPs)on hydrodynamics and mass transfer in liquid–liquid extraction process was assessed using a ternary chemical system of toluene-acetic acid–water. The organic phase which contained toluene and acetic acid was dispersed through water, and the mass transfer of acetic acid between two phases was investigated. The hydrophobic modified magnetite nanoparticles (MMNPs)prepared through an optimized in-situ method were added to the dispersed phase at different concentrations (0.001−0.005 wt%). Two separate conditions were provided in the experiments, i.e. stagnant and stirred continuous phase. The latter case was provided by a rotor at two... 

An attempt was made to introduce a new approach for evaluating mass transfer during drop formation via definition of a parameter related to the extent of the convective mixing within the growing drop. For this purpose it was assumed that the entrance of the dispersed flow into the growing drop from the nozzle is analogous to the entrance of the flow from a smaller channel to a larger one. This transfer mechanism has been dubbed the "flow expansion." A global time-dependent Reynolds number of growing drop (Regd) was defined based on the equivalent diameter of growing drop as a length scale and also on a velocity scale, which is obtained using this flow expansion assumption. The results show... 

For the reason that flow expansion model (developed in our previous work) for evaluating mass transfer during droplet formation involves with manifest hydrodynamic aspects, in this research computational simulation of this phenomenon was done for characterization of hydrodynamics effects on the mass transfer during droplet formation. For this purpose, an Eulerian volume tracking computational code based on volume of fluid (VOF) method was developed to solve the transient Navier-Stokes equations for the axisymmetric free-boundary problem of a Newtonian liquid that is dripping vertically and breaking as drops into another immiscible Newtonian fluid. The effects of hydrodynamics effects on the... 

In salting-out liquid-liquid extraction (SALLE) technique, water-miscible organic solvents are used for extraction of polar analytes from saline solutions. In this study, for the first time, a coupled 1-mL syringes system was utilized to perform a miniaturized SALLE method. Sulfanilamide antibiotic was extracted and determined via the developed method followed by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The extraction process was carried out by rapid shooting of acetonitrile as extraction solvent (syringe B) into saline aqueous sample solution (syringe A), and then the shooting was repeated several times at a rate of 1 cycle s-1. Thereby, an extremely large... 

In industrial liquid-liquid extraction processes, the feed is not clean liquid but there are various kinds of contaminants in the feed entering the extractors. In this regard, a two-impinging-jets contacting device (TIJCD) was tested through the standard test system recommended by the European Federation of Chemical Engineering (EFCE), namely toluene-acetone-water, in the presence and absence of various types of surface-active agents (SAAs). The influences of anionic, cationic, and nonionic SAAs such as sodium dodecyl sulfate (SDS), dodecyl trimethyl ammonium chloride (DTMAC), and octylphenol decaethylene glycol ether (Triton X-100), respectively, on the extraction efficiency and overall...