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    Low Salinity Water Assisted by Surfactants for Enhanced Oil Recovery: Mechanistic Study and Spontaneous Imbibition Tests

    , M.Sc. Thesis Sharif University of Technology Heidari, Mehdi (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Enhanced Oil Recovery (EOR) techniques have become of the main priorities of the oil industry during the high oil price era. It is interesting to note that the common method to increase production from reservoirs is the water injection method, which recovers a very low amount of oil from the oil-wet matrices due to the lack of water imbibition. Previous studies have shown that changing the wettability of rock would critically increase the oil recovery efficiency. This could be achieved by the low-salinity water injection method. In recent years, extensive studies have been conducted on this technique to evaluate its effectiveness for various types of oil reservoirs. Simultaneous injection... 

    Experimental and Modeling Study of Controlled Salinity Water Injection for Enhanced Oil Recovery from one of Iranial Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Shojaei, Mohammad Javad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Masihi, Mohsen (Co-Advisor)
    Abstract
    From previous years, water injection was considered as one of the most common methods for enhanced oil recovery. But recently much attention has been paid on the use of low salinity water (LSW) as an enhanced oil recovery fluid. The main mechanism that causes improve oil recovery is wettability alteration to a more water wet state. The change observed in recovery factor during LSW flooding induced from changes in relative permeability and capillary pressure when different levels of salinity are used. However, a few researchers tried to evaluate how macroscopic flow functions depend on the salinity of injected water. To this end, a series oil displacements by water performed on sandstone rock... 

    Experimental Investigation of Asphaltene Precipitation and Deposition in Enhanced Oil Recovery by Low Salinity Waterflooding

    , M.Sc. Thesis Sharif University of Technology Hosseini, Ali (Author) ; Ayatollahi, Shahabadin (Supervisor) ; Fatemi, Mobin (Supervisor)
    Abstract
    Asphaltenes are a polydisperse mixture of the heaviest and most polarizable fractions of the crude oil. They are defined according to their solubility properties as being soluble in aromatic solvents but insoluble in light paraffin solvents. Asphaltenes are usually responsible for many problems like wettability changes of the reservoir rock, pore clogging in the reservoir porous matrix and fouling in wellbore tubing and production surface facilities. Most of the studies in the literature, addressing the asphaltene precipitation and deposition (APD), are investigating natural depletion or gas injection process such as CO2 flooding. These studies show that asphaltene deposition and... 

    Pore-Scale Investigation of the Roles of Oil Types and Pore Structure in Low Salinity Waterfloogin Using Glass Micromodel

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Saheb (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Oil composition plays an undeniable role on the low salinity water flooding (LSWF) efficiency. This property directly affects the kinetics of wettability alteration through electrostatic interactions and interfacial tension (IFT). For instance, mixing in stagnant zones through a thin water film is considered as one of the most important diffusion controlled phenomenon which is goverened by Non-Fickian solute transport model. The major two potentials controlling the solute transport in thin film are salinity gradient and electrostatic potentials, which can be affected by oil composition and surface charges. This study aims to investigate the effect of oil composition on low salinity... 

    Pore-scale Simulation of Trapping Phenomena and Hysteresis Effect in Porous Media

    , M.Sc. Thesis Sharif University of Technology Tabibnejad Azizi, Mehdi (Author) ; Fatemi, Mobeen (Supervisor)
    Abstract
    So far, many studies have been carried out on the core-scale regarding the effects of hysteresis on the macro-scale properties of systems including fluids and porous rock, however, many issues related to the physics of the problem (especially regarding the way fluids are distributed and the trapping of the non-wetting phase) at the pore-scale need further investigation. In the process of multiphase fluid flow in porous media, hysteresis refers to the dependence of the results of the fluids’ displacements on the history of fluid saturation and the direction of saturation changes (increasing or decreasing). The first step to investigate the hysteresis effect is to determine the amount of fluid... 

    Study the Effect of Specific Salt Ions on Interfacial Tension of Water (Lowsalinity/Smart) and Reservoir Fluid in Surface Tension Reducing Materials Flooding by Molecular Dynamic Simulation

    , M.Sc. Thesis Sharif University of Technology Zeighami, Amir Reza (Author) ; Ayatollahi, Shahabodin (Supervisor)
    Abstract
    Water injection is known as one of the most efficient and affordable techniques to displace the oil in the reservoirs. To increase oil recovery efficiency through water injection operation, recently low salinity water injection or water containing a certain amount of effective ions (engineered/low salinity water) is proposed. Besides, improving this technique is also adopted in the oil industry using certain chemicals like surfactants to change the interfacial tension or rock wettability for more oil recovery. In order to study and model the mechanisms involved during surfactant flooding, molecular dynamics simulation is utilized here as a novel technique. The advantage of this method over... 

    Relative permeability and capillary pressure curves for low salinity water flooding in sandstone rocks

    , Article Journal of Natural Gas Science and Engineering ; Volume 25 , July , 2015 , Pages 30-38 ; 18755100 (ISSN) Shojaei, M. J ; Ghazanfari, M. H ; Masihi, M ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Recently much attention has been paid to the use of low salinity water (LSW) as an enhanced oil recovery fluid. The change observed in recovery factor during LSW flooding is induced from changes in relative permeability and capillary pressure when different levels of salinity are used. However, a few researchers tried to evaluate how macroscopic flow functions depend on the salinity of the injected water. To this end, a series of oil displacement by water was performed on a sandstone rock aged with crude oil in the presence of connate water. The capillary pressure and relative permeability curves are evaluated from inverse modeling of the obtained pressure drop and oil production data. Then,... 

    Performance of sea water dilution on the surface free energies of the crude oils in water-flooded carbonate rock

    , Article Journal of Adhesion Science and Technology ; 2017 , Pages 1-10 ; 01694243 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Although several investigations have studied the low-salinity water injection (LSWI) performance during the past decades, the effect of crude oil type on the interfacial tension (IFT) and wettability alteration is still in dark. In this regard, this study is aimed to obtain the thermodynamic energies including adhesion, cohesion and spreading coefficient during LSWI. To achieve this goal, IFT and static contact angle values of three different crude oils (i.e. light, medium and heavy) are measured as a function of sea water salinity. The obtained results revealed that the dilution of sea water can change the wettability of reservoir rock from oil wet state towards water wet state, while crude... 

    Performance of sea water dilution on the surface free energies of the crude oils in water-flooded carbonate rock

    , Article Journal of Adhesion Science and Technology ; Volume 32, Issue 12 , 2018 , Pages 1359-1368 ; 01694243 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    Although several investigations have studied the low-salinity water injection (LSWI) performance during the past decades, the effect of crude oil type on the interfacial tension (IFT) and wettability alteration is still in dark. In this regard, this study is aimed to obtain the thermodynamic energies including adhesion, cohesion and spreading coefficient during LSWI. To achieve this goal, IFT and static contact angle values of three different crude oils (i.e. light, medium and heavy) are measured as a function of sea water salinity. The obtained results revealed that the dilution of sea water can change the wettability of reservoir rock from oil wet state towards water wet state, while crude... 

    Smart water flooding performance in carbonate reservoirs: an experimental approach for tertiary oil recovery

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 9, Issue 4 , 2019 , Pages 2643-2657 ; 21900558 (ISSN) Darvish Sarvestani, A ; Ayatollahi, S ; Bahari Moghaddam, M ; Sharif University of Technology
    Springer  2019
    Abstract
    Smart water flooding as a developing technique utilizes modified water chemistry in terms of salinity and composition to prepare the best-suited brine composition for a specific brine/oil/rock system to obtain higher oil recovery efficiency. Huge amount of unrecovered oil is expected to be remained in carbonate reservoirs; however, few research works on incremental oil recovery during smart water injection in carbonate cores at reservoir condition are reported. Several core flooding tests using one of the Iranian carbonate reservoir rock are conducted to check the effectiveness of smart water injection for more oil recovery efficiency. The results reaffirm the positive effect of sulfate ions... 

    Effect of SO4 −2 ion exchanges and initial water saturation on low salinity water flooding (LSWF) in the dolomite reservoir rocks

    , Article Journal of Dispersion Science and Technology ; Volume 41, Issue 6 , 2020 , Pages 841-855 Safavi, M. S ; Masihi, M ; Safekordi, A. A ; Ayatollahi, S ; Sadeghnejad, S ; Sharif University of Technology
    Taylor and Francis Inc  2020
    Abstract
    The low salinity water injection has become one of the most important studies in the oil industry for improving oil recovery compared to conventional seawater injection. Thus, extensive studies have been conducted in carbonate and sandstone reservoirs to investigate how the physical properties of rocks and the chemical composition of fluids influence low salinity effect, while, the carbonate reservoir rocks requires more investigation of the effect of molecular and/or ionic interactions. In this experimental work, the effectiveness of various water flooding schemes in carbonate reservoir rock samples is investigated. In this regard, the oil recovery potential of seawater (SW), reservoir... 

    Detailed analysis of the brine-rock interactions during low salinity water injection by a coupled geochemical-transport model

    , Article Chemical Geology ; Volume 537 , 2020 Shabani, A ; Zivar, D ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Enhanced Oil Recovery (EOR) methods have been widely used around the world to improve oil production from petroleum reservoirs. Recently, the injection of the low salinity/smart water has gained popularity among the EOR methods. Different mechanisms are believed to exist during low salinity/smart water injection, including dissolution, precipitation, and ion exchange at the rock surface. In this study, a coupled geochemical-transport model is presented for the detailed analysis and investigation of the interactions between brine, sandstone and carbonate rocks. The proposed model presents the coupling of a geochemical software (PHREEQC) and a species transport model. This coupled method makes... 

    Experimental investigation on the dominating fluid-fluid and rock-fluid interactions during low salinity water flooding in water-wet and oil-wet calcites

    , Article Journal of Petroleum Science and Engineering ; Volume 204 , 2021 ; 09204105 (ISSN) Farhadi, H ; Fatemi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Low salinity water flooding (LSWF) has the potential to enhance the oil recovery by affecting the fluid-fluid and rock-fluid interactions. Therefore, a systematic investigation on the effect of initial wetting state (water-wet or oil-wet) of pure calcite is conducted to study the importance of these interactions on the effectiveness of LSWF. In the case of initially water-wet cores, more oil recovery efficiency is observed for more saline water cases. To shed light on the possible involved mechanisms, dynamic IFT, dynamic contact angle (CA), oil/brine and rock/brine surfaces zeta potentials, and effluent pH are measured. It is shown that the short-term effect of IFT reduction and long-term... 

    Impact of rock morphology on the dominating enhanced oil recovery mechanisms by low salinity water flooding in carbonate rocks

    , Article Fuel ; Volume 324 , 2022 ; 00162361 (ISSN) Farhadi, H ; Ayatollahi, S ; Fatemi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Because of the complex nature of carbonate reservoirs, the required conditions for effective Low Salinity Water Flooding (LSWF) in these reservoirs need further and in depth investigation. In the present study, three calcite cores, i.e. Cal-1, Cal-2, and IL, with the same chemical composition are subjected to tertiary low salinity water flooding (LSWF), while the crude oil and composition of flooding brine kept the same. The experimental results show significant difference in the amount of enhanced oil recovery, as IL had the most additional oil recovery (20.8 % of IOIP), followed by Cal-2 (10.5 % of IOIP) and Cal-1 (3.9 % of IOIP). The results of contact angle, zeta potential, and effluent... 

    Microfluidics experimental investigation of the mechanisms of enhanced oil recovery by low salinity water flooding in fractured porous media

    , Article Fuel ; Volume 314 , 2022 ; 00162361 (ISSN) Mahmoudzadeh, A ; Fatemi, M ; Masihi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Spontaneous imbibition of water from fracture into the matrix is considered as one of the most important recovery mechanisms in the fractured porous media. However, water cannot spontaneously imbibe into the oil-wet rocks and as a result oil won't be produced, unless the capillary pressure barrier between fracture conduits and matrix is overcome. Wettability alteration is known as the main affecting mechanism for low salinity water flooding (LSWF), however, its effectiveness in fractured porous media has been less investigated, especially in the case of possible pore scale displacement mechanisms. In this study, the effectiveness of LSWF (diluted seawater) on oil recovery is compared to the... 

    Coupling Flow and Geochemistry for Numerical Simulation of Low Salinity/Smart Waterflooding in Carbonates

    , M.Sc. Thesis Sharif University of Technology Alipour, Sina (Author) ; Ayatollahi, Shahab (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Due to the decrease in oil reserves in the world, increasing population and the growing demands for oil consumption in the world, increasing the oil recovery from oil reservoirs has become more important. Increasing the amount of oil production efficiency by using low salinity water/modified salinity water has been highly appreciated during the last two decades. Low-salt water is a new method, due to its advantages such as low cost, simplicity of operation and low environmental hazards. It is believed that low salinity water can alter the rock wettability from a more oil-wetting state to a more water-wetting state. In order to be able to predict the performance of low salinity water... 

    Experimental Analysis of the Effect of Fluid/Fluid and Fluid/Rock Interactions on the Pore Scale Displacement Mechanisms of Oil by Lswi

    , M.Sc. Thesis Sharif University of Technology Siadatifar, Emad (Author) ; Fatemi, Mobeen (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Visual investigation of the low salinity water injection into micromodel is the goal of this research. Although many researches have been performed to realize the dominating mechanism behind the increased oil recovery after low salinity water injection, many contradictions exist among the studies. Mechanisms are generally divided into two classes. One class is due to fluid/fluid interactions and the other one is due to fluid/rock interactions. A comprehensive set of experiments are conducted in this study to find out the dominating mechanism behind low salinity water injection under the existing conditions of the experiments. Effect of different wettability condition and presence and absence... 

    Experimental Investigation and Modeling of Nonorganic Scale Formation in Porous Media at Microscopic Scale

    , M.Sc. Thesis Sharif University of Technology Mirzaalian Dastjerdi, Ali (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Taghikhani, Vahid (Supervisor)
    Abstract
    Inorganic scale deposition has been found to affect many industrial processes,including water injection into the oil reservoirs. Major formation damage because of incompatibility of high sulfate ion content of seawater with formation water containing calcium ion results in formation damage and production decline.In this study, several simultaneous techniques are utilized for qualitative and quantitative analysis of calcium sulfate scale to get more insight into the damage of formation during smart water flooding at micro and Nano scales. In the experimental section, calcium sulfate deposition due to the mixing of the formation water and seawater samples was investigated using the dynamic... 

    Mechanistically Investigation of Residual Oil Saturation in Heterogeneous Glass Micromodel during Low Salinity Water Injection

    , M.Sc. Thesis Sharif University of Technology Safdari, Mojtaba (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Oil and gas reservoirs in various parts of the world have declined over time, despite a high percentage of oil. Due to the increasing need for hydrocarbon resources, the need for more cost-efficient harvesting methods and less environmental damage is felt. Injection of saline water is one of the most cost-effective ways of harvesting due to the need for no expensive additives. On the other hand, microscopic glass modeling can be used to better understand and understand the performance of saline water at the microscopic scale. In this study we have been able to visualize the effective factors in infusion of saline water. Improved interfacial tensile and particle migration in kaolin-coated... 

    Experimental Study of LSW Injection in Fractured Porous Media: Fracture Geometrical Properties at Pore Scale

    , M.Sc. Thesis Sharif University of Technology Mahmoudzadeh Zarandi, Atena (Author) ; Masihi, Mohsen (Supervisor) ; Fatemi, Mobeen (Supervisor)
    Abstract
    Enhancing oil production from fractured reservoirs is challenging. The flow characteristics observed in naturally fractured reservoirs are complicated due to interaction between the two different flow domains: fracture and matrix. Spontaneous imbibition is one of the most important recovery processes in water-wet fractured reservoirs. Oil cannot be spontaneously produced from oil-wet rocks, unless the capillary pressure barrier between fracture conduits and matrix is overcome. The flow characteristics in fractured systems thus relate to the wettability of the rocks. Low salinity water injection has been widely studied as a method of enhancing oil recovery in recent years. However, its impact...