Sharif Digital Repository

Chemical Vapor Synthesis route was used for synthesis of titanium dioxide (TiO2) nanoparticles in hot-walled reactor at 800degreeC using TiCl4 as precursor. The effect of processing parameters e.g., temperature and amount of precursor on phase structure, size, purity, coagulation and agglomeration of nanoparticles were investigated in this respect. Also, the H2O effects on the size, crystallinity, phase transformation and purity of nanoparticles were studied. Comprehensive experimental observations were confirmed by transmission electron microscopy, X-ray diffraction analysis and thermal gravimetric-differential thermal analysis results. The obtained results showed that by increasing the... 

We present both numerical and analytical studies of graphene roughness with a crystal structure including 500×500 atoms. The roughness can effectively result in a random gauge field and has important consequences for its electronic structure. Our results show that its height fluctuations in small scales have a scaling behavior with a temperature dependent roughness exponent in the interval of 0.6<χ<0.7. The correlation function of height fluctuations depends on temperature with a characteristic length scale of ≈90 Å (at room temperature). We show that the correlation function of the induced gauge field has a short-range nature with a correlation length of about 2-3 Å. We also treat the... 

The present study is concerned with introducing a new configuration of equal channel angular extrusion (ECAE) process nominated as multi-stage ECAE. This die configuration is not a real processing die and is just used to calculate strain in ECAE dies with outer curved corner. A solution is presented for evaluating total strain in those dies consisting of two or more ECAE sub-dies. The solution is extended for calculating strain in frictionless ECAE dies with outer curved corner. A complete agreement is found between calculated and previously published results by other authors. © 2006 Elsevier B.V. All rights reserved  

In this research, deformation of material in equal channel angular extrusion (ECAE) process with outer curved corner is analyzed using an upper bound solution. The effects of die angle, friction between the sample and the die walls, and the angle of the outer curved corner, on the extrusion pressure are all considered in the analysis. It is found that the extrusion pressure decreases with increasing both the die angle and the outer curved corner angle and increases with increasing the friction coefficient. Moreover, a good agreement is found between the predicted and experimental results of extrusion pressure relating to two dies of different outer curved corner angles used in ECAE tests of... 

After about two decades of intense research since the discovery of high-temperature superconductivity (HTSC) in cuprates, although many aspects of the physics and chemistry of these cuprate superconductors are now well understood, the underlying pairing mechanism remains elusive. Magnetism and superconductivity are usually thought as incompatible, but in number of special materials including HTSCs these two mutually excluding mechanisms are found to coexist. The presence in a system of superconductivity and magnetism, gives rise to a large number of interesting phenomenon. This article provides perspective on recent developments and their implications for our understanding of the interplay... 

In this research the deformation of wire in flat rolling process has been investigated. A theoretical relationship has been developed to relate the reduction in height of wire to the width of contact area between the rolls and wire. This relationship depicts that the width of contact area is proportional to square root of reduction in height of wire. Using that relationship the width of contact area for wires of different diameter have been calculated and compared with the appropriate experimental data after flat rolling. Also, a relationship is developed to assess the effect of reduction in height of wire on the lateral spread in wire flat rolling process. Moreover, the effect of material... 

X-ray Powder Diffraction beamline is one of the first priorities of Iranian Light Source Facility day-onebeamlines. This beamline will cover the research requirements of scientific community in the fields of physics, material science, chemistry, etc and also have benefits for industries. This paper shortly reports the ray tracing calculations for the optical design of this beamline. The results show that bending magnet source would satisfy the nowadays users requirements, although insertion device should also be considered for covering the requirements of the future users. In this paper the effects of the optical elements on the users' requirements have been discussed to obtain the... 

In spite of the fact that the experimental results indicate the significant effect of strain rate on forming limits of sheets, this effect is neglected in all theoretical methods of prediction of Forming Limit Diagrams (FLDs). The purpose of this paper is to modify the most renowned theoretical method of determination of FLDs (e.g., M-K model) so as to enable it to take into account the effect of strain rate. To achieve this aim, the traditional assumption of preexistence of an initial geometrical inhomogeneity in the sheet has been replaced with the assumption of a preexisting "material" inhomogeneity. It has been shown that using this assumption, the strain rate would not be omitted from... 

Effect of sandblasting of the copper electrode structures before deposition of gold thin film for micro electrical impedance tomography (EIT) system has been studied experimentally. The comparison has been performed on the unmodified copper electrodes and the sandblasted electrodes before deposition of gold layer, using structural analysis while their performance in EIT system has been measured and analyzed. The results of scanning electron microscopy and atomic force microscopy show that the sandblasting of the electrodes results in the deposition of gold film with smaller grain size and uniformly, comparing to the unmodified structure. The measurement of impedance shows that the... 

In this research an intelligent emotional learning controller, Takagi- Sugeno- Kang (TSK) is applied to govern the dynamics of a novel Ionic-Polymer Metal Composite (IPMC) actuated manipulator. Ionic-Polymer Metal Composites are active actuators that show very large deformation in existence of low applied voltage. In this research, a new IPMC actuator is considered and applied to a 2-dof miniature manipulator. This manipulator is designed for miniature tasks. The control system consists of a set of neurofuzzy controller whose parameters are adapted according to the emotional learning rules, and a critic with task to assess the present situation resulted from the applied control action in... 

The effective properties of elastic solids are strongly linked to their interacting micro-constituent phases. For materials containing dilute distributions of single-phase inhomogeneities, the overall behavior can be estimated in a straightforward manner. But in the non-dilute case, due to the complex inter-particle and particle-matrix interactions the treatment is rather involved. When the particles are heterogeneous, not only become the mentioned interactions more complex, but must properly account for the intra-particle interactions as well. The present work addresses an analytical approach to determine the overall moduli of elastic solids containing random distributions of arbitrarily... 

In this paper, the nonlinear cylindrical bending of a functionally graded plate is studied. The material properties of the plate are assumed to be graded continuously in the direction of thickness. The variation of the material properties follows a simple power-law distribution in terms of the volume fractions of constituents. The von Karman strains are used to construct the nonlinear equilibrium equations of the plates subjected to in-plane and transverse loadings. The governing equations are reduced to linear differential equation with nonlinear boundary conditions yielding a simple solution procedure. The results show that the functionally graded plates exhibit different behavior from... 

With the development of computing systems for data processing, the image processing and image analyzing methods have been developed on the basis of pixel assessment. These methods can analyze and detect the images by assigning a value for each pixel and using the matrices calculations. In the present research, two methods have been used to assess the simulated material microstructures. In the first method, the vertices of the microstructure are counted to determine accurately the mean grain size by the Euler's relationship, while in the second method, the image processing and image analyzing methods are utilized to assess the microstructure image. To verify the accuracies of the methods... 

Heap leaching is a process extensively used by the mining industry to recover metals from low-grade ores and large quantities of submarginal material resources. Understanding flow through a packed particle bed is important to enhance the performance of heap leaching with respect to design and operating considerations. Complex fluid behavior in porous media, such as film flow, fragmentation, coalescence of droplets, and rivulet flow with or without meandering, has been widely observed in laboratory experiments. In this study, to provide detailed information of momentum and mass transfer phenomena in a granular bed direct numerical simulations (DNS) were performed. In this case the liquid-gas... 

In this study friction stir welding of Al-Cu laminated composites were carried out by two different tool geometries. Welding procedure was carried out from both sides of Al and Cu. Analyzing cross section of welds showed that different contact conditions between shoulder and material, offers different material flow behavior which is dependent on the tool geometry. SEM analyses showed that mixing of materials in nugget region is more pronounced in the advancing side. Also XRD results indicated that welding from Cu side, leads to intermetallic formation in mixed regions  

Data are presented on the solidification of aluminum alloys and their macro segregation behavior. Three alloys with different solidification ranges were prepared in two temperatures. Two types of molds were also prepared by sand and metallic materials. The solidification of Al alloys were studied and the effects of four parameters were determined, including cooling rate, casting temperature, degassing and nucleation effects on solidification and a comparison was conducted to Scheil model performance. Three types of aluminum alloys (Al-12.1%Si, Al-6.9%Si and Al-4.4% Cu) with short, medium and wide solidification ranges were studied and the results showed that degassing, nucleation, increasing... 

The present work develops direct graded boundary integral equation formulation for behavior investigation of the inhomogeneous media made of functionally graded materials. The isoparametric boundary elements, the elastostatic governing equations and a weighted residual technique are implemented with the material characteristics that vary continuously along a given dimension. The resulting algorithm is capable of solving the quasistatic problems for elastic functionally graded media with a variety of the boundary conditions and loadings. The inhomogeneous media is made of a ceramic-metal mixture, in which the material properties vary continuously according to a power law graded distribution... 

The objective of this study is to develop a general finite element formulation associated with an incremental adaptive procedure which established for thermoviscoelastic stress analysis of orthotropic cylinders made of polymers. This paper concerned with development of a numerical algorithm for the solution of the quasistatic initial/boundary value problems involving the linear viscoelastic media with thermal and mechanical deformations. The viscoelastic constitutive equations, represented in an integral form and involving relaxation functions, are transformed into an incremental algebraic relation. An incremental relaxation is then developed for the finite element formulation to deal with... 

Isotropic tensor valued functions of tensor arguments play an important role in the formulation of the equations governing the behavior of solid materials in the field of continuum mechanics. When the tensor argument is non-symmetric, the complexity and the difficulty in dealing with the tensor functions are high. In this work, the issue of expressing an isotropic tensor valued tensor function of a non-symmetric tensor argument is attention by utilizing the Dunford-Taylor integral. An important subclass of the isotropic tensor functions is considered with the commutative property  

In this paper, after studying the demands and requirements of a perfect smart grid and specifications of network topology and sensor nodes utilized in a Wireless Sensor Network [WSN], a manipulated version of them is proposed to be combined with smart grid in order to improve the data acquisition step, increase the security and facilitate the process of information and desired commands from users. We will take the advantage of computer simulations to illustrate improved capacity and speed of this method. Finally, we will analyze the advantages of employing this proposed structure in a smart grid