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    Behaviour of alumina-spinel self-flowing castables with NANO-alumina particles addition

    , Article Ceramics - Silikaty ; Volume 53, Issue 2 , 2009 , Pages 98-101 ; 08625468 (ISSN) Otroj, S ; Marzban, R ; Nemati, Z. A ; Sajadi, N ; Nilforoushan, M. R ; Sharif University of Technology
    2009
    Abstract
    The purpose of this study is to determine the influence of nano-alumina particles on the self-flow characteristics of aluminaspinel self-flowing castables. for this reason, the self-flow characteristics such as; self-flow value and working time of the alumina-spinel castables with different amount of nano-alumina particles have been studied. Also, the mechanical properties and microstructure of these castables have been studied. for the study of nano-alumina (d50 =4 3 nm) addition on selfflow characteristics and other properties of these castables, reactive alumina is substituted by nano-alumina powder in 0-4 wt.% range. The results show that the nano-alumina particles have great effect on... 

    Preparation of High Temperature Shift Catalyst

    , M.Sc. Thesis Sharif University of Technology Haghighi, Farzad (Author) ; Baghalhs, Morteza (Supervisor) ; Kazemeyni, Mohammad (Supervisor)
    Abstract
    Water-gas shift reaction (CO(g) + H2O(g) ↔ CO2(g) + H2(g)) is performed as the key step in the hydrogen and ammonia industrial plant. In this work, Fe/Cr/Cu high temperature water gas shift catalysts were synthesized by coprecipitation method, using sulfate precursors, in order to improve the catalytic performance and particular emphasis is placed on the catalytic activity affected by aging time, precipitating agent and ways of increasing the mechanical strength. Finally the prepared and industrial catalysts were compared when they were situated in the operating conditions (at 360oC and 2 bar) and were characterized by BET, XRD, TPR, TEM and crushing strength analysis. Catalysts being made... 

    Design and Synthesis of Heterogeneous Nano Catalyst Based on Immobilized Palladium Metal on Double Network Hydrogel and Its Application in Organic Reactions

    , M.Sc. Thesis Sharif University of Technology Ghasemzadeh, Solmaz (Author) ; Pourjavadi, Ali (Supervisor)
    Abstract
    In the past few decades, many attempts have been made to combine the benefits of homogeneous and heterogeneous catalysts. The immobilization of homogeneous catalysts onto the surface of heterogeneous supports is the result of such efforts. In this research, immobilized heterogeneous catalysts were designed and synthesized based on double network hydrogels, which produce from interpenetrating of two biocompatible and biodegradable polymer networks. In order to provide magnetic responsibility and easy separation of catalyst from the reaction mixture, the magnetic nanoparticles were dispersed onto the surface of double network hydrogel. Finally, various metal nanoparticles such as palladium and... 

    Design and Fabrication of Conductive Nanofibrous Scaffolds in Nerve Tissue Engineering

    , M.Sc. Thesis Sharif University of Technology Soleymani, Maryam (Author) ; Mashayekhan, Shohreh (Supervisor) ; Ramezani Saadat, Ahmad (Supervisor)
    Abstract
    The nervous system is the most important communication machine in body which regulates the function of other organs. Peripheral nerves in contrary to central nervous system have the potential for regeneration, but regrowth requires proper environmental conditions and supporting growth factors. Tissue engineered scaffolds create a suitable milieu for disconnected axon to regenerate. The aim of this study in the first stage is the fabrication of nanostructured of conductive polymers (graphene and polyaniline) within a bed of gelatin polymer and then conducting some analyses including conductance, degradation rate and tensile test besides morphological analyses of fibers through SEM and... 

    Design, Construction and Experimental Study of the 3D Bending Device for spinal Column Stabilizing Rods

    , M.Sc. Thesis Sharif University of Technology Hashami Najafabadi, Ali (Author) ; Durali, Mohammad (Supervisor) ; Farahmand, Farzam (Supervisor)
    Abstract
    Deformity is one of the common diseases of the spine. For example, in the case of scoliosis, which is a three-dimensional deviation in the spine, the prevalence of 2% to 32% among adults has been reported [1]. In case of severe deformity, surgical methods are usually used to correct it. In surgical methods, rods with appropriate curvature are placed next to the spine and the deviation is completely or partially corrected by connecting the vertebrae to said rods. In general, the curvature of the rods is determined based on the clinical indicators of the patient, the tissue fault strength, the stiffness of the soft tissues, the movement limitation of the vertebrae and the level of spinal cord... 

    Effect of stress direction on the cyclic resistance of sand

    , Article Proceedings of the Institution of Civil Engineers: Geotechnical Engineering ; Volume 171, Issue 2 , April , 2018 , Pages 109-120 ; 13532618 (ISSN) Jafarzadeh, F ; Zamanian, M ; Sharif University of Technology
    ICE Publishing  2018
    Abstract
    In total, 55 undrained cyclic torsional shear tests were conducted at a constant mean confining stress, σ0m, constant intermediate principal stress ratios, b = (σ2 − σ3)/(σ1 − σ3), and principal stress directions, α. The cyclic resistance of loose, isotropically consolidated specimens exhibited a dip in strength, with the lowest values for α being 45°, an angle at which α was oriented such that the potential shear band directions dovetailed with the plane having the weakest strength (i.e. horizontal plane). For a given α, the cyclic resistance decreased to the lowest values for b = 0·5, at which the value of the principal stresses was different in the three major directions. For dense... 

    The effect of nano-size additives on the electrical conductivity of matrix suspension and properties of self-flowing low-cement high alumina refractory castables

    , Article Ceramics International ; Volume 36, Issue 4 , 2010 , Pages 1411-1416 ; 02728842 (ISSN) Otroj, S ; Sagaeian, A ; Daghighi, A ; Nemati, Z. A ; Sharif University of Technology
    Abstract
    Influence of two nano-size additives oSubject:A. Suspensions. Subject:C. Electrical conductivity. Subject:Castable. Subject:E. Refractories. Subject:Castables. Subject:Electrical conductivity. Subject:Electrical property. Subject:High alumina. Subject:matrix. Subject:Mechanical strength. Subject:Nano-size. Subject:Polycarboxylate ethers. Subject:Refractory castables. Subject:Working time. Subject:Alumina. Subject:Cement additives. Subject:Electric conductivity. Subject:Ethers. Subject:Suspensions (fluids) Subject:Refractory materials. n electrical properties of suspension matrix of self-flowing low-cement high alumina refractory castable is investigated. For this purpose, castament FS 10 and... 

    SiC fines effects on the microstructure and properties of bauxite-based low-cement refractory castables

    , Article Ceramics International ; Volume 45, Issue 13 , 2019 , Pages 16338-16346 ; 02728842 (ISSN) Mavahebi, S ; Bavand vandchali, M ; Nemati, A ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    In the present paper, the effect of silicon carbide (SiC) fines was studied on the phase and microstructural properties of bauxite-based low-cement refractory castables (LCC) at different firing temperatures. XRD and SEM techniques were employed to evaluate phase and microstructure analysis, and physical/mechanical properties were measured according to standard methods. The results showed that the oxidation of SiC particles related to the oxygen partial pressure and active/passive oxidation behavior of SiC fines could markedly affect the microstructure and properties of bauxite-based LCC fired at high temperatures. Despite the negative influence of addition of SiC fines on cold mechanical... 

    Design of a SF6 Load Breaker Switch for Compact Distribution Substation

    , M.Sc. Thesis Sharif University of Technology Akbari, Mohammad (Author) ; Vakilian, Mehdi (Supervisor)
    Abstract
    Electrical energy customer and load growth on the one hand and the problems of allocation of land for the development of the power networks on the other hand, make the tendency to use less space in the electrical industries. One of the solutions used in power distribution networks, especially in crowded areas is compact substation which requires less space than ordinary substations and also the prefabricated types of this substation can be used in the distribution system. In a compact distribution substation, all components must be designed with a minimum size. Therefore, the insulation system of the compact substation should be designed based on these requirements.
    In the distribution... 

    The annealing phenomena and thermal stability of severely deformed steel sheet

    , Article Materials Science and Engineering A ; Volume 528, Issue 15 , June , 2011 , Pages 5212-5218 ; 09215093 (ISSN) Khodabakhshi, F ; Kazeminezhad, M ; Sharif University of Technology
    2011
    Abstract
    However, there are many works on annealing process of SPDed non-ferrous metals, there are limit works on annealing process of SPDed low carbon steel. Therefore, in this study the annealing responses after constrained groove pressing (CGP) of low carbon steel sheets have been investigated. The sheets are subjected to severe plastic deformation at room temperature by CGP method up to three passes. Nano-structured low carbon steel sheets produced by severe plastic deformation are annealed at temperature range of 100-600 °C for 20. min. The changes of their microstructures after deformation and annealing are studied by optical microscopy. The effects of large strain and annealing temperature on... 

    Effects of temperature and torsion speed on torsional properties of single-walled carbon nanotubes

    , Article Materials Science and Engineering C ; Volume 31, Issue 2 , March , 2011 , Pages 452-457 ; 09284931 (ISSN) Khoei, A. R ; Ban, E ; Banihashemi, P ; Abdolhosseini Qomi, M. J ; Sharif University of Technology
    2011
    Abstract
    Carbon nanotubes (CNTs) are excellent candidates for torsional elements used in nanoelectro-mechanical systems (NEMS). Simulations show that after being twisted to a certain angle, they buckle and lose their mechanical strength. In this paper, classical molecular dynamics simulations are performed on single-walled carbon nanotubes (CNTs) to investigate the effects of torsion speed and temperature on CNT torsional properties. The AIREBO potential is employed to describe the bonded interactions between carbon atoms. The MD simulations clearly show that the buckling of CNTs in torsion is a reversible process, in which by unloading the buckled CNT in opposite direction, it returns to its... 

    Production of granulated-copper oxide nanoparticles for catalytic application

    , Article Journal of Materials Research ; Volume 25, Issue 10 , 2010 , Pages 2025-2034 ; 08842914 (ISSN) Hosseinpour, M ; Ahmadi, S. J ; Mousavand, T ; Outokesh, M ; Sharif University of Technology
    2010
    Abstract
    Ultra fine CuO nanoparticles In the range of 2 ± 0.2 nm were synthesized by the supercritical hiydrotliermal method in a batch reactor. Itwas demonstrated that elevating the pH of the Cu2+ precursor solution to around 6 (neutral condition) not only does not lead to excessive agglomeration of the particles, but also reduces particle size and in general promotes their nanoscale characteristics. Prepared nanoparticles were immobilized in the biopolymcric matrix of barium alginate and calcined at different temperatures resulting in micro spherical granules of high porosity and elevated mechanical strength. The fabricated samples were characterized using x-ray diffractometry (XRD), transmission... 

    Fabrication and characterisation of ultrafine-grained Al-5vol%Al 2O3 nanocomposite

    , Article International Journal of Nanomanufacturing ; Volume 5, Issue 3-4 , 2010 , Pages 341-351 ; 17469392 (ISSN) Razavi Hesabi, Z ; Simchi, A ; Seyed Reihani, S. M ; Simancik, F ; Sharif University of Technology
    Abstract
    Nanocrystalline Al-5vol%Al2O3 nanocomposite was synthesised by mechanical milling of a mixture containing nanometric alumina with an average particle size of 35 nm. Morphology of as-synthesised powder was investigated by SEM while crystallite size of Al matrix was determined by XRD analysis. The results confirmed formation of nanocrystalline Al matrix induced by severe plastic deformation during mechanical milling. Nanocomposite bars were produced by hot powder extrusion route. TEM investigation of as-extruded nanocomposite revealed formation of elongated grains along the extrusion direction decorated by alumina nanoparticles. Tensile and compressive properties of as-extruded nanocomposite... 

    Supersolidus liquid phase sintering of Al6061/SiC metal matrix composites

    , Article Powder Metallurgy ; Volume 52, Issue 1 , 2009 , Pages 28-35 ; 00325899 (ISSN) Asgharzadeh, H ; Simchi, A ; Sharif University of Technology
    2009
    Abstract
    The aim of the present work is to study the effect of reinforcement content and sintering temperature on the densification and microstructural development during sintering of Al6061/SiC composite compacts. Prealloyed Al6061 powder was mixed with various amounts of SiC particles up to 27 vol.-% and compacted at 350 MPa. Sintering was carried out in a dry nitrogen atmosphere at 580-620°C. It was shown that the presence of SiC particles retards the densification of the prealloyed powder during solid phase sintering and liquid phase sintering. This effect is particularly noticeable at SiC fractions higher than ∼9 vol.-%, at which continuous networks of the hard particles are formed. Increasing... 

    Roles of preoxidation, Cu2O particles, and interface pores on the strength of eutectically bonded Cu/α-Al2O3

    , Article Materials and Design ; Volume 30, Issue 4 , 2009 , Pages 1098-1102 ; 02641275 (ISSN) Ghasemi, H ; Kokabi, A. H ; Faghihi Sani, M. A ; Riazi, Z ; Sharif University of Technology
    2009
    Abstract
    The influences of CuO layer thickness, Cu2O particles, and pores on mechanical properties and microstructure of alumina-copper eutectic bond have been investigated. The furnace atmosphere in the first stage was argon gas with 2 × 10-6 atm oxygen partial pressure. In the second stage, the furnace atmosphere was same as the first stage except for the cooling interval between 900 and 1000 °C, the hydrogen gas was injected into furnace atmosphere. Finally, in the last stage a vacuum furnace with 5 × 10-8 atm pressure was chosen for bonding procedure. Peel strength of first stage specimens shows that CuO layer with 320 ± 25 nm thick generates the maximum peel strength (13.1 ± 0.3 kg/cm) in joint... 

    Inclusion of carbon nanotubes in a hydroxyapatite sol-gel matrix

    , Article Ceramics International ; Volume 35, Issue 7 , 2009 , Pages 2987-2991 ; 02728842 (ISSN) Najafi, H ; Nemati, Z. A ; Sadeghian, Z ; Sharif University of Technology
    2009
    Abstract
    In this study, the inclusion of multi-walled carbon nanotubes as the second phase in the hydroxyapatite matrix, in order to improve the mechanical strength, has been performed via the sol-gel process. The stability of carbon nanotube sol with the changes of pH and dispersant values (sodium dodecyl sulfate) was evaluated by zeta potential analysis. The results indicated that synthesis of hydroxyapatite particles in the presence of the carbon nanotubes had the best result in homogenization of the carbon nanotube dispersion and faster crystallization of hydroxyapatite. The crystallization of hydroxyapatite phase was investigated with differential scanning calorimetry (DSC) and X-ray diffraction... 

    Plasma based surface modication of poly (dimethylsiloxane) electrospun membrane proper for organ-on-a-chip applications

    , Article Scientia Iranica ; Volume 26, Issue 2 , 2019 , Pages 808-814 ; 10263098 (ISSN) Kiyoumarsioskouei, A ; Saidi, M. S ; Moghadas, H ; Firoozabadi, B ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    Electrospun porous membrane; Superhydrophilic surfaces; Superhydrophobic surfaces; Cell culture; Organ on a chip; Flexible membrane; Strong membrane; Surface modications  

    Plasma based surface modication of poly (dimethylsiloxane) electrospun membrane proper for organ-on-a-chip applications

    , Article Scientia Iranica ; Volume 26, Issue 2 , 2019 , Pages 808-814 ; 10263098 (ISSN) Kiyoumarsioskouei, A ; Saidi, M. S ; Moghadas, H ; Firoozabadi, B ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    onstructing of the scaffolds for cell culture applications has long been of interest for engineering researchers and biologist. In this study, a novel process is utilized for construction of suitable membrane with a high mechanical strength and appropriate surface behavior. Poly (dimethylsiloxane) (PDMS) is electrospun into fine fibers using poly (methyl methacrylate) (PMMA) as the carrier polymer in different weight ratios. Since the surface behavior of all PDMS substrates is moderately hydrophobic (120 < contact angle (CA) < 150), the electrospun membranes with higher PDMS ratios show slightly higher hydrophilicity. Direct plasma treatment is utilized to change the interfacial wettability... 

    Highly stretchable, self-adhesive, and self-healable double network hydrogel based on alginate/polyacrylamide with tunable mechanical properties

    , Article Journal of Polymer Science ; Volume 58, Issue 15 , 2020 , Pages 2062-2073 Pourjavadi, A ; Tavakolizadeh, M ; Hosseini, S. H ; Rabiee, N ; Bagherzadeh, M ; Sharif University of Technology
    John Wiley and Sons Inc  2020
    Abstract
    A number of synthetic hydrogels suffer from low mechanical strength. Despite of the recent advances in the fabrication of tough hydrogels, it is still a great challenge to simultaneously construct high stretchability, and self-adhesive and self-healing capability in a hydrogel. Herein, a new type of double network hydrogel was prepared based on irreversible cross-linking of polyacrylamide chains and Schiff-base reversible cross-linking between glycidyl methacrylate-grafted ethylenediamine and oxidized sodium alginate (OSA). The combination of both cross-linkings and their synergistic effect provided a novel hydrogel with high strength, stretchable, rapid self-healing, and self-adhesiveness... 

    Effect of post annealing treatment on nano-structured low carbon steel sheets processed by constrained groove pressing

    , Article Materials Science Forum, 21 March 2011 through 25 March 2011 ; Volume 667-669 , March , 2011 , Pages 1009-1014 ; 02555476 (ISSN) ; 9783037850077 (ISBN) Khodabakhshi, F ; Kazeminezhad, M ; Azarnush, M ; Miran, S. H ; National Natural Science Foundation of ; The Ministry of Science and Technology of China; Chinese Academy of Sciences, Institute of Metal Research; Baoshan Iron and Steel Co., Ltd ; Sharif University of Technology
    2011
    Abstract
    There are many works on annealing process of SPDed bulk metals but there are limited works on annealing process of SPDed sheets. Therefore, in this study the annealing response after constrained groove pressing (CGP) of low carbon steel sheets has been investigated. These sheets are subjected to severe plastic deformation at room temperature by CGP method up to three passes. Nano-structured low carbon steel sheets produced by severe plastic deformation are annealed at temperature range of 100 to 600 °C for 20 min. The microstructural changes after deformation and annealing are studied by optical microscopy. The effects of CGP strain and annealing temperature on microstructure, strength and...