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    Deep eutectic solvents: Cutting-edge applications in cross-coupling reactions

    , Article Green Chemistry ; Volume 22, Issue 12 , 2020 , Pages 3668-3692 Hooshmand, S. E ; Afshari, R ; Ramón, D. J ; Varma, R. S ; Sharif University of Technology
    Royal Society of Chemistry  2020
    Deep eutectic solvents (DESs), surmised as "the organic reaction medium of the century", have reverberated a new symphony throughout the present green millennium. A brief historical account of the DES systems and their physicochemical properties as task-specific and designer solvents for cross-coupling reactions are appraised including the hole theory that explains the underlying mechanistic pathway for this emerging neoteric medium. The insights into cross-coupling reactions and their applications are included, highlighting the significant achievements pertaining to the dual role of DESs as a solvent and catalyst. In addition, popular "name-reactions"for the carbon-carbon and...