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    Reduced graphene oxide–melamine formaldehyde as a highly efficient platform for needle trap microextraction of volatile organic compounds

    , Article Microchemical Journal ; Volume 157 , 2020 Dorabadi Zare, F ; Allahdadlalouni, M ; Baktash, M. Y ; Bagheri, H ; Sharif University of Technology
    Elsevier Inc  2020
    Abstract
    A superhydrophobic extractive phase was prepared and packed in a needle trap microextraction device for extraction of volatile organic compounds, followed by their determination by gas chromatography. The superhydrophobic phase was prepared by surface modification of melamine formaldehyde (MF) sponge embedded by reduced graphene oxide (rGO). The overall properties of the modified MF along with its high sorption capacity and low cost fabrication were indicative of its feasibility to be highly suitable for extraction of organic pollutants. The determined water contact angle (>150o) from the surface of melamine formaldehyde–reduced graphene oxide (MF–rGO) revealed its high affinity toward... 

    Preparation and Application of Superhydrophobic Melamine Formaldehyde Modified by Graphene Sorbent for Extraction of Chlorobenzenes from Aqueous Samples by Needle-trap Device

    , M.Sc. Thesis Sharif University of Technology Dorabadi Zare, Farzaneh (Author) ; Bagheri, Habib (Supervisor)
    Abstract
    Superhydrophobic surfaces have attracted much attention in recent years due to their unique properties. Artificial superhydrophobic surfaces can be fabricated by employing chemical modifying a hierarchical structured surface (micro- and nanostructures) with a low surface free energy material. In this report, we used a simple one-step coating process to prepare superhydrophobic sorbents with a large surface area. Surface chemistry and porosity are fundamental parameters for an efficient sorbent capable of extracting low levels of analytes. Considering physical and chemical peroperties of chlorobenzenes, superhydrophobic materials make to be good sorbents. So in this project melamine...