Sharif Digital Repository

A dense membrane of La0.6Sr0.4Co0.8Fe0.2O3- δ (LSCF) perovskite was prepared by a new chelating agent, ethylene diamine N,N,N′,N′-tetra N-acetyl diamine (EDTNAD). As a potent ligand, EDTNAD provided a facile one-step method to form complexes of the four metal ions, simultaneously. The oxygen permeation flux through the pure perovskite LSCF dense membrane was measured over temperature range of 1073-1223 K, thickness of 0.7-1.0 mm and oxygen partial pressure of 0.1-1.0 bar. Oxidative coupling of methane (OCM) reaction using LSCF disk in the atmospheric membrane reactor and over the temperature range of 1073-1173 K showed a C2 selectivity of 100% and C2 yield of 5.01% at 1153 K. Furthermore,... 

A two-dimensional non-isothermal mathematical model has been developed for the ethane dehydrogenation reaction in a fixed-bed catalytic membrane reactor. Since ethane dehydrogenation is an equilibrium reaction, removal of produced hydrogen by the membrane shifts the thermodynamic equilibrium to ethylene production. For further displacement of the dehydrogenation reaction, oxidative dehydrogenation method has been used. Since ethane dehydrogenation is an endothermic reaction, the energy produced by the oxidative dehydrogenation method is consumed by the dehydrogenation reaction. The results show that the oxidative dehydrogenation method generated a substantial improvement in the reactor... 

Removal of dissolved oxygen (DO) from water has gained much attention in recent decades to prevent different problems such as corrosion, bio-fouling, and performance degradation in many industries. The traditional physical and chemical methods for DO removal have found wide application in industries. However, physical methods have low efficiency and chemical methods often produce undesirable products. Therefore, catalytic reduction by hydrogen has been regarded by a variety of industries recently. In this study, catalytic reduction of DO from water is examined using membrane reactors. The mathematical model of this system is developed while considering the axial dispersion, membrane... 

The catalytic reduction of dissolved oxygen (DO) from water was examined using membrane reactors and a mathematical model that considers axial dispersion, membrane permeation, and chemical reaction. The model is solved in steady state mode and the effect of various parameters on the DO removal was assessed. The results of steady state mode were employed as initial conditions for solving the model in dynamic mode. The impact of operating conditions, e.g., water flow rate, DO concentration of influent water, hydrogen flow rate, and hydrogen pressure on the performance of the DO process was studied. Results of the dynamic simulation suggested that hydrogen pressure is the best option to be used... 

In this study, a fixed-bed catalytic membrane reactor was used for the production of ethylene and cyclohexane from ethane and benzene. A two-dimensional non-isothermal mathematical model was used for estimating the performance of the membrane reactor. Furthermore, the effect of inlet temperature (720–1080 K), feed molar ratio (3–10) and the reactor spacetime (1–76 kgCat.s/mol) was studied on the conversion of ethane to ethylene and benzene to cyclohexane. The results of modeling showed that with the increase of inlet temperature the conversion of both (de)-hydrogenation reactions increased and the 95% of ethane conversion was achieved when the molar ratio of benzene/ethane was fixed on 3.... 

A comprehensive mathematical model has been developed for the simulation of simultaneous chemical absorption of carbon dioxide and hydrogen sulfide by means of Monoethanolamine (MEA) aqueous solution in hollow fiber membrane reactors is described. In this regard, a perfect model considering the entrance regions of momentum, energy, and mass transfers was developed. Computational Fluid Dynamics (CFD) techniques were applied to solve governing equations, and the model predictions were validated against experimental data reported in the literature and excellent agreement was found. Effects of different disturbances on the dynamic behavior of the reactor were investigated. Moreover, effects of... 

Three dense membranes of types SrCo0.8Fe0.2O 3-δ (SCF(82)), La0.6Sr0.4Co 0.8Fe0.2O3-δ (LSCF(6482)) and La 0.8Sr0.2Co0.6Fe0.4O 3-δ (LSCF(8264)) perovskites were prepared by complexation applying a chelating agent, ethylene diamine N,N,N′,N′-tetra-N- acetyl-diamine (EDTNAD). The oxygen permeation flux through the perovskite membranes was measured as a function of temperature within 1,073-1,223 K as well as the oxygen partial pressure of 0.1-1.0 bar. The oxygen permeation fluxes for the membranes, SCF(82), LSCF(6482), LSCF(8264) with the thickness of 0.85 mm were observed as 9.2×10-7 (mol/cm2 s), 1.7×10-7 (mol/cm2 s), and 1.0×10-7 (mol/cm2 s) in these cases at 1,153 K. The results indicated the... 

A compartment model was developed to describe the flow pattern of gas within the dense zone of a tapered membrane-assisted fluidized-bed reactor (TMAFBR), in the bubbling mode of operation for steam reforming of methane under wall heat flux. The parameters of the developed model (i.e., number of compartments for the bubble and emulsion phases) were determined using the experimental data reported elsewhere [Adris AM, Lim CJ, Grace JR. The fluidized bed membrane reactor system: a pilot scale experimental study. Chem Eng Sci 1994; 49:5833-43.] and good agreements were obtained between model predictions and corresponding experimental data. The developed model was then utilized to predict the... 

The results of three cases of two consecutive reactors are studied in two types of co-current and counter-current flow in second reactor where two consecutive reactors are oxidative coupling of methane (OCM) and Fischer-Tropsch (FT) reactors. FT reactor can be fixed bed or membrane fixed bed reactor with a hydrogen perm-selective membrane. Effect of CH4/O2 ratio, contact time, inlet temperature, and amount of N2 in OCM feed on C2 to C5+ hydrocarbons produced in FT reactor were studied. Results show that use of counter-current hydrogen-perm selective membrane FT reactor that sequenced after OCM reactor improves the C5+ yield as a desirable product and reduces the amount of CH4 and CO2 as... 

A catalytic membrane reactor was synthesized by coating a 4-5 micron thick Ni/γ-Al2O3 layer on top of a hydrogen selective SiO2/Al2O3 composite membrane using a sol-gel method. Mercury intrusion and BET analysis indicated a uniform size distribution with an average pore size of 285 nm and average surface area of 279 m2 g-1. Single-component permeation tests were carried out for H2, CH4 and CO2 in the temperature range of 650-800 °C and the results showed the same permeance and selectivity values for hydrogen as the composite membrane without a catalytic layer. Performance of the catalytic membrane was evaluated by using as a membrane reactor for the methane steam reforming reaction with a... 

A compartment model was developed to describe the flow pattern of gas within the dense zone of a membrane-assisted fluidized-bed reactor (MAFBR), in the bubbling mode of operation for steam reforming of methane both with (adiabatic) and without (isothermal) entering oxygen. Considering such a flow pattern and using the experimental data reported elsewhere [Roy S, Pruden BB, Adris AM, Grace JR, Lim CJ. Fluidized-bed steam methane reforming with oxygen input. Chem Eng Sci 1999; 54:2095-2102.], the parameters of the developed model (i.e., number of compartments for the bubble and emulsion phases) were determined and fair agreements were obtained between model predictions and experimental data.... 

In this paper simulation results for integration of CO2 pre-combustion capture by steam methane reforming (SMR) in membrane reactors (MR) with natural gas fired combined cycle (NGCC) power plants are presented. The integrated combined cycle was simulated by GTPRO (Thermoflow) simulator along with the results from simulation of membrane reactor for SMR process developed in this work. The results show that the overall efficiency of the integrated combined cycles decreased due to the energy required for SMR process. On the other hand, by integration of MR in combined cycles, emissions of CO2 to the atmosphere can be avoided. © 2009 Elsevier Ltd. All rights reserved  

The coupling of photocatalysis with membrane technology, which is known as photocatalytic membrane reactors (PMRs), has received great consideration in recent years and become a promising approach with the high potential to improve the fouling of membranes. In this paper, the photocatalyst of g-C3N4 treated with H2O2 was incorporated with a polysulfone membrane to enhance the anti-fouling properties of the membrane. AFM, FE-SEM images, porosity, and contact angle analysis indicated that the membrane properties like hydrophilicity, porosity, and surface roughness were improved. Also, UV–visible DRS, PL spectra, EIS analysis confirmed that the treated g-C3N4 (H2O2-g-C3N4) had high light... 

Catalytic reduction of nitrobenzene is the leading technological step in aniline production. The hydrogen required for this stage, is dominantly produced from fossil fuels through reforming processes, which take much energy and emit large amounts of CO2. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming to reduce the dependence on hydrocarbon resources and mitigate climate change. This research aims to analyze a mass- and heat-integrated multi-tubular membrane reactor, containing nitrobenzene hydrogenation (exothermic-side) and glycerol steam reforming (endothermic-side) for co-production of aniline and syngas. In this process, hydrogenation... 

Photocatalytic membrane reactors (PMRs), coupling photocatalysts and membranes in a single system, have shown a considerable potential to reduce membrane fouling, which is one of the major drawbacks of using membranes to treat water and wastewater. In this study, the visible light-activated photocatalysts were incorporated into the polyacrylonitrile (PAN) casting solution to synthesize the photocatalytic composite membranes. The physicochemical properties and the morphology of the membranes and photocatalysts were characterized by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray diffraction analysis (XRD), ultraviolet–visible diffuse reflectance...