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    Application of 3D gold nanotube ensembles in electrochemical sensing of ultra-trace Hg (II) in drinkable water

    , Article Surfaces and Interfaces ; Volume 10 , 2018 , Pages 27-31 ; 24680230 (ISSN) Bahari Mollamahale, Y ; Ghorbani, M ; Dolati, A ; Ghalkhani, M ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    As a novel and highly sensitive sensor, three-dimensional gold nanoelectrode ensembles (3D GNE) prepared by gold deposition inside the parallel pores of a porous template have been successfully applied in electrochemical determination experiments. In this study, we report on the fabrication of 3D gold nanotubes (GNT) and their application in determination of Hg (II) in water. The morphology and crystal structure of the 3D GNT were characterized by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD), respectively. The sensitivity of the fabricated electrode towards Hg (II) was examined using anodic stripping voltammetry (ASV) as a powerful technique in... 

    Design and Fabrication of a Novel Mercury Micropump Actuated Electeromagneticaly

    , M.Sc. Thesis Sharif University of Technology Karmozdi, Mohsen (Author) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    Considering the advantages and disadvantages of reported micropumps, we aimed to introduce a novel idea to diminish the disadvantages and promote the advantages of PiezoElectric micropumps. This novel idea operates based on a mercury slug actuation in a microchannel. This cyclic motion of the mercury slug which is similar to a piston, push the fluid in the microchannel and pump the flow. However, to bring this idea into the practice, a control system must be designed. This system contains: LABVIEW code, DAQ board & a switching Board. The pattern of actuating mercury is drawn in LABVIEW. DAQ Board produces electrical signals according to LABVIEW code. Switching board will transform the... 

    Effective removal of mercury from aqueous solution using thiol-functionalized magnetic nanoparticles

    , Article Environmental Nanotechnology, Monitoring and Management ; Volume 7 , 2017 , Pages 130-138 ; 22151532 (ISSN) Oveisi, F ; Nikazar, M ; Razzaghi, M. H ; Mirrahimi, M. A. S ; Jafarzadeh, M. T ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    The present investigation demonstrates the effective removal of Hg(II) ions from aqueous solution by means of thiol-functionalized magnetic nanoparticles (TF-MNPs). After preparation, TF-MNPs have been characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transform-infrared spectroscopy (FT-IR), Thermogravimetric (TG) and vibrating sample magnetometer (VSM). The XRD and FESEM analyses revealed the presence of magnetic nanoparticles with an average particle size of 15–30 nm. The result of FT-IR analysis confirmed that the magnetite nanoparticles have been successfully functionalized by thiol groups. The particles illustrated enough response... 

    An efficient and convenient approach for synthesizing iodohydrin and iodoether from aromatic alkenes using Hg(BF4)2.SiO2 and I2

    , Article Polycyclic Aromatic Compounds ; 2021 ; 10406638 (ISSN) Hosseinzadeh, N ; Mousavi, S. R ; Ahmadi, Y ; Batooei, N ; Sotoudehnia Korrani, Z ; Mahdavi, M ; Sharif University of Technology
    Bellwether Publishing, Ltd  2021
    Abstract
    A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. © 2021 Taylor & Francis Group, LLC  

    An efficient and convenient approach for synthesizing iodohydrin and iodoether from aromatic alkenes using Hg(BF4)2.SiO2 and I2

    , Article Polycyclic Aromatic Compounds ; Volume 42, Issue 7 , 2022 , Pages 3975-3983 ; 10406638 (ISSN) Hosseinzadeh, N ; Mousavi, S. R ; Ahmadi, Y ; Batooei, N ; Sotoudehnia Korrani, Z ; Mahdavi, M ; Sharif University of Technology
    Taylor and Francis Ltd  2022
    Abstract
    A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. © 2021 Taylor & Francis Group, LLC  

    Lithium Isotopes Separation by Amalgam Electrolysis Method

    , M.Sc. Thesis Sharif University of Technology Aryanpur, Vahid (Author) ; Outokesh, Mohammad (Supervisor) ; Ahmadi, Javad (Supervisor)
    Abstract
    Lithium has two stable isotopes naturally including 6Li at 7.5% and 7Li at 92.5% relative abundance. In spite of the similarities of lithium isotopes in common chemical reactions, they have some completely distinctive behaviors in nuclear reactions. 6Li has considerable neutron cross section capturing in thermal neutron range about 945 barns while this feature for 7Li is insignificant about 0.037 barns. This difference makes them to play different roles in nuclear uses. 7LiOH is applied for pH adjustment of coolant in light water reactors. 6Li is not only used as a shielding material against thermal neutrons, but also is known as a source of tritium in the blanket of fusion reactors which... 

    Experimental Study of Movement of Mercury Droplets in Micro Channel by Electromagnetic Force

    , M.Sc. Thesis Sharif University of Technology Ardeshir Larijani, Morteza (Author) ; Afshin, Hossein (Supervisor)
    Abstract
    As today's tremendous advance occurred in biotechnology and nanotechnology, the microfluidic devices made a new success that was not possible with the traditional equipments. It was useful in such a way that by using a microliter volume of that fluid, we could have the ability to use it in biologics, medicine, aerospace, cooling electronic systems and medical discovery. One of the main component of fluidic microsystems are micropumps in which they divide into two types. Reciprocating micropumps have been worked by stimulating electromagnetic micropumps which is based on Lorentz law. In this project, we try to investigate the impact of effective parameters in the movement of the mercury mass.... 

    Mercury ion adsorption on AC@Fe3O4-NH2-COOH from saline solutions: Experimental studies and artificial neural network modeling

    , Article Korean Journal of Chemical Engineering ; Volume 35, Issue 3 , 2018 , Pages 671-683 ; 02561115 (ISSN) Pazouki, M ; Zabihi, M ; Shayegan, J ; Fatehi, M. H ; Sharif University of Technology
    Springer New York LLC  2018
    Abstract
    An efficient, novel functionalized supported magnetic nanoparticle (AC@Fe3O4-NH2-COOH) has been synthesized by co-precipitation method for removal of mercury ions from saline solutions. High dispersed supported magnetic nanoparticles with particle sizes less than 30 nm were formed over activated carbon derived from local walnut shell. Surface characterizations of supported magnetic nanoparticles were evaluated by Boehm test, Brunauer- Emmett-Teller (BET) surface area, X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and X-ray fluorescence (XRF). A three-layer artificial neural network (ANN) code... 

    Synthesis, characterization and fluorescence spectra of mixed ligand Zn(II), Cd(II) and Hg(II) complexes with 1,10-phenanthroline-5,6-dione ligand

    , Article Journal of Coordination Chemistry ; Volume 60, Issue 15 , 2007 , Pages 1629-1635 ; 00958972 (ISSN) Boghaei, D. M ; Behzadian Asl , F ; Sharif University of Technology
    2007
    Abstract
    The novel mixed ligand complexes [M(bpy)(phen-dione)](PF6)2 (M = Zn(II), Cd(II) and Hg(II), bpy = 2,2′-bipyridine and phen-dione = 1,10-phenanthroline-5,6-dione) have been synthesized and characterized by elemental analysis, IR, 1H NMR and electronic absorption spectroscopies. The ν(C=O) of coordinated phen-dione in these complexes are very similar to the free phen-dione ligand showing that phen-dione is not coordinated to metal ion from its C=O sites. Absorption spectra of the complexes show two absorption bands for intraligand transitions. These absorption bands show dependence to the dielectric constant of solvent. These complexes exhibit an intensive fluorescence band around 535 nm in... 

    Synthesis, characterization and fluorescence spectra of mononuclear Zn(II), Cd(II) and Hg(II) complexes with 1,10-phenanthroline-5,6-dione ligand

    , Article Journal of Coordination Chemistry ; Volume 60, Issue 3 , 2007 , Pages 347-353 ; 00958972 (ISSN) Boghaei, D. M ; Behzadian Asl, F ; Sharif University of Technology
    2007
    Abstract
    The mononuclear complexes of Zn(II), Cd(II) and Hg(II), [Zn(phen-dione)Cl2], [Cd(phen-dione)Cl2] and [Hg(phen-dione)Cl2], where phen-dione = 1,10-phenanthroline-5,6-dione, have been synthesized and characterized by elemental analysis and IR, 1H NMR and electronic absorption spectroscopies. The ν(C=O) of coordinated phen-dione ligands in these complexes shows that the phen-dione is not coordinated to metal ion from its C=O sites. Electronic spectra of the complexes show two absorption bands for intraligand transitions. These absorption bands show dependence on the dielectric constant of solvents. These complexes exhibit an intense fluorescence band around 545 nm in DMSO when the excitation... 

    Determination of very low levels of dissolved mercury(II) and methylmercury in river waters by continuous flow with on-line UV decomposition and cold-vapor atomic fluorescence spectrometry after pre-concentration on a silica gel-2-mercaptobenzimidazol sorbent

    , Article Talanta ; Volume 55, Issue 6 , 2001 , Pages 1141-1150 ; 00399140 (ISSN) Bagheri, H ; Gholami, A ; Sharif University of Technology
    Elsevier  2001
    Abstract
    A new, simple and sensitive method for the simultaneous determination of mercury(II) and methylmercury chloride at sub-ng 1-1 levels in river waters is described. Inorganic and organic mercury were preconcentrated from fresh water samples simultaneously on a laboratory-made column containing 2-mercaptobenzimidazol loaded on silica gel and then quantitatively eluted with 0.05 M KCN solution and 2.0 M HCl to desorp inorganic and methylmercury species, respectively. After irradiation with an intensive UV source, MeHg+ was decomposed and mercury vapours were generated from inorganic and organic mercury using an acidic SnCl2 solution in a continuous flow system and were subsequently determined... 

    Development of a novel method for determination of mercury based on its inhibitory effect on horseradish peroxidase activity followed by monitoring the surface plasmon resonance peak of gold nanoparticles

    , Article Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy ; Volume 153 , 2016 , Pages 709-713 ; 13861425 (ISSN) Khodaveisi, J ; Haji Shabani, A. M ; Dadfarnia, S ; Rohani Moghadam, M. R ; Hormozi Nezhad, M. R ; Sharif University of Technology
    Elsevier 
    Abstract
    A highly sensitive and simple indirect spectrophotometric method has been developed for the determination of trace amounts of inorganic mercury (Hg2 +) in aqueous media. The method is based on the inhibitory effect of Hg2 + on the activity of horseradish peroxidase (HRP) in the oxidation of ascorbic acid by hydrogen peroxide followed by the reduction of Au3 + to Au-NPs by unreacted ascorbic acid and the measurement of the absorbance of localized surface plasmon resonance (LSPR) peak of gold nanoparticles (at 530 nm) which is directly proportional to the concentration of Hg2 +. Under the optimum conditions, the calibration curve was linear in the concentration range of 1-220 ng mL- 1. Limits... 

    Rotary magnetohydrodynamic micropump based on slug trapping valve

    , Article Journal of Microelectromechanical Systems ; Volume 20, Issue 1 , December , 2011 , Pages 260-269 ; 10577157 (ISSN) Moghadam, M. E ; Shafii, M. B ; Sharif University of Technology
    2011
    Abstract
    A novel rotary magnetohydrodynamic (MHD) (RMHD) micropump is presented in this paper in order to both benefit exclusive advantages from the MHD micropumps and eliminate the current obstacles in their implementation. Lorentz force, which is the actuation mechanism in RMHD, is used to propel a mercury slug in a circular microchannel in order to suck the working fluid from the inlet and pump it to the outlet. This idea is integrated with a valve which prevents the working fluid from passing through, while allowing the mercury slug to pass, during each pumping loop. The performance of a fabricated RMHD is evaluated, considering parameters such as pressure difference, running duration, electric... 

    Water retention and volumetric characteristics of intact and re-compacted loess

    , Article Canadian Geotechnical Journal ; Volume 53, Issue 8 , 2016 , Pages 1258-1269 ; 00083674 (ISSN) Wang Wai Ng, C ; Sadeghi, H ; Belal Hossen, S. K ; Chiu, C. F ; Alonso, E. E ; Baghbanrezvan, S ; Sharif University of Technology
    Canadian Science Publishing  2016
    Abstract
    Alaboratory testing program was conducted to investigate the effects of microstructure on the water retention curve (WRC) and wetting-drying induced volume change in loess. The axis translation and vapor equilibrium techniques were adopted to control suction in the range of 0-400 kPa and 4-140 MPa, respectively. Hysteresis in the WRC of loess was observed for the entire range of suction studied. Compared to re-compacted loess, intact loess exhibits a more pronounced hysteresis in the suction range below 20 kPa, which can be explained by the ink-bottle pore neck effect or constricted pores. The hypothesis is supported by microstructural evidence of mercury intrusion porosimetry and scanning... 

    Synthesis of “L-cysteine–graphene oxide” hybrid by new methods and elucidation of its uptake properties for Hg(II) ion

    , Article Separation Science and Technology (Philadelphia) ; Volume 53, Issue 6 , 2018 , Pages 843-855 ; 01496395 (ISSN) Daneshmand, M ; Outokesh, M ; Akbari, A ; Kosari, M ; Tayyebi, A ; Sharif University of Technology
    Taylor and Francis Inc  2018
    Abstract
    This study introduces two new, simple, and scalable methods for synthesis of “cysteine–graphene oxide” hybrid, namely nucleophilic and covalent methods. Produced adsorbents could uptake 500 and 600 mg Hg2+/g, respectively, which are larger than capacities of most of the commercial adsorbents. By means of different instrumental techniques, chemical structures of the obtained graphene products were disclosed, and two pertinent mechanisms for their formations were suggested. Time for attaining uptake equilibrium for nucleophilic/covalent samples was 30 min/150 min, and kinetics was controlled by liquid film resistance/chemical reaction mechanisms, respectively. High selectivity and good... 

    Electrodeposition of gold nanotubes in porous templates

    , Ph.D. Dissertation Sharif University of Technology Bahari Mollamahale, Yaser (Author) ; Ghorbani, Mohammad (Supervisor) ; Dolati, Abolghasem (Supervisor) ; Vosoughi, Manouchehr (Co-Advisor)
    Abstract
    Detection and determination of ultra-trace electroactive materials using electrochemical methods have been widely employed by researchers since they offer a fast, easy and reliable approach. In this way, developing of new nanoelectrodes with special and unique properties plays a profound role on the achievement of better results.
    Gold nanoelectrode ensembles are one of the most important nanoelectrodes which due to the high surface area, chemical, electrochemical and physical stability, and integration of a large number of individual nanoelectrodes, introduce excellent opportunities to be employed as promising nanoelectrodes in determinations applications.
    In this work, preparation... 

    Numerical Simulation of Magneto Mercury Reciprocating Micropump

    , M.Sc. Thesis Sharif University of Technology Mehrabi, Ali (Author) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    In this investigation Magneto Mercury Reciprocating Micrpump (MMRM) the combination of Magneto-Hydrodynamic and Reciprocating micropumps has been analyzed. To achieve the analytical and numerical solution of one-tank and three-tank MMRM, the momentum, continuity, volume fraction and magnetohydrodynamic equations have been presented. The dimensionless analytical solution of one-phase and two-phase three dimensional MHD flow in the condition of using constant current and potential electrical source, has been offered.
    The boundary between mercury and air has been tracked via VOF method in OpenFOAM software. VOF equation has been solved by explicit method with variable time step and maximum... 

    Design and Fabrication of Reciprocating Micropumps with Actuated Fluid Slug

    , M.Sc. Thesis Sharif University of Technology Amiri Hezave, Hamid (Author) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    Design, fabrication and performance of the reciprocating micropumps with actuated fluid slug have been investigated. In these micropumps, pumping principle is based on reciprocating movement of a fluid slug. The fluid slug must be conductive in magnetohydrodaynamic micropump to be actuated by Lorentz force and have good magnetic properties in ferrofluidic micropumps to be actuated by an external magnetic field.
    On the other hand, a theory is developed in ahead of design and fabrication process to diagnose the critical and the most influential parameters. Magnetohydrodynamic micropumps in 4 distinict design using nozzle-diffuser element, passive ball valve and active mercury valve have... 

    Simultaneous removal of mercury ions and cationic and anionic dyes from aqueous solution using epichlorohydrin cross-linked chitosan @ magnetic Fe3O4/activated carbon nanocomposite as an adsorbent

    , Article Diamond and Related Materials ; Volume 124 , 2022 ; 09259635 (ISSN) Kaveh, R ; Bagherzadeh, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    An economical epichlorohydrin cross-linked chitosan @ magnetic Fe3O4/activated carbon nanocomposite, CH-EP@Fe3O4/AC, was successfully synthesized and used as a suitable adsorbent material for removal of a triphenylmethane cationic dye, Malachite green (MG), an anionic dye, Reactive red 120 (RR120), and Mercury ions (Hg2+) from aqueous solution. The prepared adsorbent has been characterized with Fourier transform infrared spectroscopy, X-ray diffraction, Scanning electron microscopy, Thermogravimetric analysis, Brunauer–Emmett–Teller analysis as well as Vibrating sample magnetometer. According to the result of Brunauer–Emmett–Teller isotherm, the prepared adsorbent has a specific surface area... 

    Light Induced Curing of TiO2 Mesoporous Layer Utilized in Perovskite Solar Cells

    , M.Sc. Thesis Sharif University of Technology Zamanpour, Fahimeh (Author) ; Taghavinia, Nima (Supervisor)
    Abstract
    The efficiencies of perovskite solar cells have increased rapidly in recent years and reached about 22%. Which hopes to make this type of solar cell more functional. In the normal structure of perovskite solar cells, the presence of mesoporous TiO2 mesoporous layer has increased sustainability and efficiency. To create this layer, a common method is placing the sample in a furnace for 30 minutes at 450°C-500°C. Using the furnace, in addition to being time consuming, has a high energy consumption. In this study, we tried to create a TiO2 mesoporous layer with the help of lighting. To create TiO2 mesoporous layer, What causes porosity in the layer is the removal of ethyl cellulose and create...