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    The influence of lanthanide on NiO-MgO-SiO2 catalysts for syngas production via propane steam reforming

    , Article Molecular Catalysis ; Volume 499 , 2021 ; 24688231 (ISSN) Barzegari, F ; Rezaei, M ; Kazemeini, M ; Farhadi, F ; Keshavarz, A ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    In this study, 15 wt. % NiO-MgO-SiO2 catalysts modified by La2O3 promoter were prepared through a co-precipitation route and employed for syngas production via propane steam reforming. Various techniques including X-Ray diffraction, BET, TPR, CO2-TPD, CO-chemisorption, TPO, and Scanning electron microscopy were utilized to characterize the final samples. The results indicated that the incorporation of La2O3 enhanced the metal-support interaction providing less reducible Ni species. In comparison with the La-free catalyst, the promoted ones possessed higher metal dispersion and smaller Ni particles. Nonetheless, excessive amounts of La covering the active sites negatively decreased the Ni...