Sharif Digital Repository

Al-5083 and St-12 alloys sheets were friction stir lap welded at various travel and rotation speeds of the welding tool. Microscopic examinations indicate that the joint strength is due to the macroscopic and microscopic mechanical lockings and also atomic diffusion. The reaction zone of the welded joints consists of mixed layers of ultra-fine grains and the intermetallic compounds. The microhardness and nano indentation results prove that the intermetallic phase layer is more brittle in comparison to base metals and ultra-fine grain region. The fracture surfaces are a combination of brittle and ductile fractures. The fracture loads show that the joint strength improves significantly by... 

The taping mode Atomic Force Microscopic (T-AFM) can be properly described by a sinusoidal excitation of its base and nonlinear potential interaction with sample. Thus the cantilever may cause chaotic behavior which decreases the performance of the sample topography. In this paper a nonlinear delayed feedback control.is proposed to control.chaos in a single mode approximation of a T-AFM system. Assuming model parameters uncertainties, the first order Unstable Periodic Orbits (UPOs) of the system is stabilized using the sliding nonlinear delayed feedback control. The effectiveness of the presented methods is numerically verified and the results show the high performance of the control.er  

Identification and minimization of error sources are important issues in experimental investigations. Mainly in micro-scale problems, precise settings should be applied to high-tech test beds to reduce disturbance and induced motion. An experimental study is conducted to assess the role of induced forces and velocity fields in a particulate system used for particle identification and separation. Two main effects caused by disturbances are sampling errors and induced motion in the channel, either on fluid or dispersed phases. Different disturbance scenarios are implemented on the test bed and then the system response is reported. In order to assess induced motion as a result of applied... 

Gold nanoparticles are potentially very attractive components for therapeutic delivery since they can be synthesized with any diameter from 1 to 200 nm to carry a payload of therapeutic molecules into a cell without triggering an immune response. Gold nanoparticles must undergo surface transformations before coupling to therapeutic molecules to become eligible for this purpose. It is now more understood that amine groups can bind to gold nanoparticles strongly, which has enabled surface modification of gold nanoparticles with amino acid lysine through its amine group. These lysine capped gold nanoparticles can further be coupled to therapeutic molecules for delivery purposes. In this study... 

In this study a novel alginate-g-poly(acrylic acid)/alumina composite was synthesized and characterized. Preparation of the composite hydrogels involved free radical polymerization of a combination of alginate, acrylic acid (AA) and distilled water, in appropriate amounts and N,N-methylene bisacrylamide (MBA) as crosslinking agent. The composite formation was confirmed by Fourier transform infrared spectroscopic (FTIR). The surface morphologies of the synthesized hydrogels were assessed by scanning electron microscopy. Systematically, the different variables of the graft copolymerization were optimized to achieve maximum swelling capacity. The swelling of superabsorbent hydrogels was... 

Hydrogels of poly(acrylic acid) grafted onto salep with excellent water absorption and water retention abilities under neutral conditions were successfully synthesized for the first time and employed for different applications. The effect of reaction variables to achieve maximum swelling capacity was investigated. In our procedure, ammonium persulfate (APS) as a water-soluble initiator and methylenebisacrylamide (MBA) as a suitable crosslinking agent were used and the best synthesis conditions described. The structure of the final product was confirmed by Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy SEM and TGA analysis and a mechanism for superabsorbent... 

The interaction of dislocation with strengthening particles, including primary and secondary γ′, during different stages of creep of Rene-80 was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During creep of the alloy at 871 °C under stress of 290 MPa, the dislocation network was formed during the early stages of creep, and the dislocation glide and climb process were the predominant mechanism of deformation. The density of dislocation network became more populated during the later stages of the creep, and at the latest stage of the creep, primary particles shearing were observed alongside with the dislocation glide and climb. Shearing of γ′... 

We demonstrate that Markov processes play a fundamental role in probing rough surfaces and characterizing their topography. The surface topography obtained by a probe, as in the atomic force microscopy (AFM) technique, is based on the probe-surface interactions. When the size of the probe tip is comparable with the height of the surface fluctuation, the surface image can be aberrated from its origin. Due to the tip effect, there is a crossover in the structure function of the surface. For scales smaller than the Markov length -the minimum length scale over which a process is Markovian - the stochastic function that describes a rough surface is non-Markovian, whereas for length scales larger... 

A novel full-polysaccharide hydrogel was prepared by crosslinking of chitosan with periodate-oxidized sucrose. A tetraaldehyde molecule is synthesized via periodate oxidation of sucrose and then applied as a crosslinking agent to form a new hydrogel network. A mechanism for the superabsorbent hydrogel formation via reductive N-alkylation was also suggested. The structure of the hydrogel was confirmed by FTIR spectroscopy, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). It is shown that crosslinking of chitosan can improve its thermal stability. The effects of crosslinker concentration, pH, and inorganic salt on the swelling behavior of the hydrogel were studied. The... 

This article examines the physical and mechanical characteristics of mixtures of two different synthetic rubbers, namely styrene-butadiene rubber (SBR) and nitril-butadiene rubber (NBR), with novolac type phenolicresin (PH). According to Taguchi experimental design method, it is shown that the addition of PH increases the crosslinking density of rubber phase probably due to its curative effects. Thermal analysis of the blends indicates that, contrary to NBR/PH blend, thermal stability of SBR/PH blend is dependent on sulfur content due to predominant polysulfidic crosslinks formed in SBR. Slight shift in glass-transition temperature (Tg) of pure SBR and NBR vulcanizates by the addition of PH... 

We prepared copper-carbon nanocomposite films by co-deposition of RF-Sputtering and RF-PECVD methods at room temperature. These films contain different copper concentration and different size of copper nanoparticles. The copper content of these films was obtained from Rutherford Back Scattering (RBS) analyze. We studied electrical resistivity of samples versus copper content. A metal-nonmetal transition was observed by decreasing of copper content in these films. The electrical conductivity of dielectric and metallic samples was explained by tunneling and percolation models respectively. In the percolation threshold conduction results from two mechanisms: percolation and tunneling. In the...