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    Experimental investigation of dynamic asphaltene adsorption on calcite packs: The impact of single and mixed-salt brine films

    , Article Canadian Journal of Chemical Engineering ; Volume 97, Issue 7 , 2019 , Pages 2028-2038 ; 00084034 (ISSN) Monjezi, R ; Ghotbi, C ; Jafari Behbahani, T ; Bakhshi, P ; Sharif University of Technology
    Wiley-Liss Inc  2019
    Abstract
    In this study, the dynamic adsorption of asphaltene on a calcite surface is investigated. This study investigates the effect of mixed-salt brines on asphaltene adsorption. The results of this work can facilitate the understanding of the complex wettability behaviour of carbonate reservoirs. All experiments were performed in porous media, which were sand-packs filled with calcite powder, to study the influence of the type and concentration of salt on adsorption. The experiments were conducted with asphaltene concentration of 500 mg/L for brines of NaCl, Na2SO4, and a mixture of the two at various ionic strengths. In addition, two tests were performed with an asphaltene concentration of 2000... 

    Modeling electrolyte solutions with the SAFT-VR equation using Yukawa potentials and the mean-spherical approximation

    , Article Fluid Phase Equilibria ; Volume 236, Issue 1-2 , 2005 , Pages 241-255 ; 03783812 (ISSN) Behzadi, B ; Patel, B. H ; Galindo, A ; Ghotbi, C ; Sharif University of Technology
    Elsevier  2005
    Abstract
    An equation of state based on the statistical associating fluid theory for potentials of variable range (SAFT-VR) is used to model 7 hydrogen-bonding solvents and 23 electrolyte solutions. Solvent-solvent hydrogen bonding interactions are explicitly taken into account as in other versions of the SAFT approach. In addition, long-range Coulombic interactions between ionic species are accounted for using the non-restricted mean-spherical approximation, while solvent-solvent and solvent-ion dispersion interactions are included and are treated using Yukawa potentials. Previously a similar approach had been proposed in which the dispersion interactions were treated using square-well potentials. In...