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mizoroki-heck-reaction
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Synthesis and crystal structures of a series of (μ-thiophenolato)(μ-pyrazolato-N,N′) double bridged dipalladium(II) complexes and their application in Mizoroki-Heck reaction as highly efficient catalysts
, Article Inorganica Chimica Acta ; Volume 440 , 2016 , Pages 107-117 ; 00201693 (ISSN) ; Tavakoli, G ; Assoud, A ; Bagherzadeh, M ; Boghaei, D. M ; Sharif University of Technology
Elsevier S. A
Abstract
Three new binucleating S-protected ligand precursors, 2-(N,N-dimethylthiocarbamato)-5-methylisophthalaldehyde di-2′-hydroxy 5′-methylanil (1b), 2-(N,N-dimethylthiocarbamato)-5-tert-butylisophthalaldehyde di-2′-hydroxyanil (2a) and 2-(N,N-dimethylthiocarbamato)-5-tert-butylisophthalaldehyde di-2′-hydroxy 5′-methylanil (2b), have been synthesized. The reaction of these ligand precursors with PdCl2 in the presence of pyrazole under Pd-mediated S-C cleavage yielded a series of binuclear palladium(II) complexes of general formula [LPd2(pz)], where pz is the exogenous bridging pyrazolyl ligand and L3- represents a series of pentadentate thiophenol-based bridging ligands originated from their...
Pd(OAc)2 without added ligand as an active catalyst for Mizoroki-Heck reaction in aqueous media
, Article RSC Advances ; Volume 2, Issue 32 , 2012 , Pages 12091-12095 ; 20462069 (ISSN) ; Bagherzadeh, M ; Moradi Shoeili, Z ; Boghaei, D. M ; Sharif University of Technology
2012
Abstract
Conditions for an efficient ligand-free Heck C-C coupling reaction of aryl iodides and bromides with terminal olefins under aerobic conditions have been developed. Critical to the success of this new protocol is the use of palladium acetate as an extremely active catalyst for the Heck reaction in water and aqueous media. Both the base and the solvent were found to have a fundamental influence on the efficiency of the reaction, with K2CO3 and a mixture of (2:1) H2O/DMSO being the optimal base and solvent, respectively