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    Marangoni instabilities for convective mobile interfaces during drop exchange: Experimental study and CFD simulation

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Vol. 441, issue , 2014 , pp. 846-854 ; ISSN: 09277757 Javadi, A ; Karbaschi, M ; Bastani, D ; Ferri, J. K ; Kovalchuk, V. I ; Kovalchuk, N. M ; Javadi, K ; Miller, R ; Sharif University of Technology
    Abstract
    The inflow pattern of liquid into a droplet is studied experimentally using a surface active dye and compared with results of CFD simulations. The results show visual agreement between experiments and simulations. The CFD simulations show also good agreement with the surface tension measured by drop profile analysis tensiometry (PAT). The inflow of the surfactant induces a Marangoni instability caused by the local arrival of the surfactant at the drop surface. The onset of this Marangoni instability observed experimentally has a delay of about 10. s when compared with the simulation results. Different scenarios are discussed, including a boundary layer barrier, a kinetic-controlled...