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morphology-and-crystallizations
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Fabrication of perovskite solar cells based on vacuum-assisted linear meniscus printing of MAPbI3
, Article Solar Energy Materials and Solar Cells ; Volume 191 , 2019 , Pages 148-156 ; 09270248 (ISSN) ; Abdollah zadeh, A ; Akbari, H. R ; Taghavinia, N ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Scale-up deposition methods in perovskite solar cell research, are mostly used under humidity environment outside the glove-box. Also, the as-printed absorbing layer before the post-annealing process is always wet. Thus, controlling the morphology and crystallization of perovskite thin-films in up-scaled deposition systems is difficult and strongly investigated by the researchers. In this work, we introduce an anti-solvent-free meniscus printing method in which, the absorbing perovskite film with optimal performance is achieved. To this end, we check the printing parameters to get to the optimized film characteristics. Also, a vacuum chamber (<100 Pa) is used for 30 s to remove the solvent...
A simple low pressure method for the synthesis of TiO2 nanotubes and nanofibers and their application in DSSCs
,
Article
Electronic Materials Letters
;
Volume 11, Issue 4
,
July
,
2015
,
Pages 625-632
;
17388090 (ISSN)
; Mashhoun, S
; Mollaei, M
; Molaei, M
; Taghavinia, N
;
Sharif University of Technology
Kluwer Academic Publishers
2015
Abstract
TiO2 nanotubes were synthesized using a modified autoclave-free thermal method from as-prepared initial powders. The size of initial powders (IP) was found to be critical in determining the morphology and crystal structure of the final product. Oleylamine (OA) was used as the polymer agent in the preparation of initial powders with different mol ratios of OA/Ti: 1, 5, and 10. X-ray diffraction analysis depicted that the increase of mole ratio up to 10 resulted in smaller nanoparticles with the sizes of about 8 nm. It was also deliberated that low temperature thermally treated IP showed the characteristic diffraction pattern of titanate phase of nanotubes. Scanning electron...
A single layer deposition of Li-doped mesoporous TiO2beads for low-cost and efficient dye-sensitized solar cells
, Article New Journal of Chemistry ; Volume 45, Issue 5 , 2021 , Pages 2470-2477 ; 11440546 (ISSN) ; Nouri, E ; Mohsenzadegan, N ; Mohammadi, M. R ; Martinez Chapa, S. O ; Sharif University of Technology
Royal Society of Chemistry
2021
Abstract
Herein, we report a new strategy for improving the efficiency and reducing the fabrication cost of dye-sensitized solar cells (DSCs) by elimination of the three- or four-fold layer deposition of TiO2. This is performed by replacing a single layer deposition of mesoporous TiO2 beads, with sub-micrometer size, high surface area and tunable pore size, synthesized by a combination of sol-gel and solvothermal methods. Furthermore, superior electronic properties gained by a reduction in electronic trap states are achieved through doping of pristine TiO2 beads with lithium. The beads have a spherical shape with monodispersed texture consisting of anatase-TiO2 nanocrystals and ultra-fine pores. The...