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    “Modeling and Control of Methanol to Propylene Reactor”

    , M.Sc. Thesis Sharif University of Technology Taherifar, Roghayeh (Author) ; Shahrokhi, Mohammad (Supervisor)
    Abstract
    Methanol to Olefin (MTO) process is a part of the Methanol to Gasoline (MTG) production in a catalytic bed. Usually for this process, HZSM-5 or SAPO-n catalyst is used. In this research, dynamic modeling and simulation of the methanol to olefin catalytic reactor using HZSM-5 as the catalyst is done. The system is modeled based on the kinetic model for HZSM-5 presented by Castilla in 1999 [22]. Since the reaction is exothermic, taking use of a cooling system is essential. According to the high reactor temperature, a molten salt environment is used as the cooling media. In this cooling system, the molten salt absorbs heat of reaction from the reactor tubes and transfers it to a coil connected... 

    Simulation, Integration, Optimization of Conversion of Natural Gas to Olefins by Methanol Production Process with ASPEN PLUS and GAMS Softwares

    , M.Sc. Thesis Sharif University of Technology Foroughi Doust, Mohsen (Author) ; Rashtchian, Davoud (Supervisor) ; Sharifzadeh, Mahdi (Supervisor)
    Abstract
    Considering the supply and demand market of natural gas, methanol, propylene and ethylene and the propylene value chain, it is expected that the design of the propylene production process from methanol produced from natural gas and its implementation in Iran country can significantly flourish the production of polypropylene, acrylonitrile and Etc. On the other hand, with the industrialization of this process, the uncontrolled export of methanol from Iran to countries such as China and the devaluation of methanol will be prevented. In this report, the process of producing synthetic gas from natural gas using autothermal reactor and heat exchange reforming, separation and storage of carbon... 

    Effect of SAPO-34's composition on its physico-chemical properties and deactivation in MTO process

    , Article Applied Catalysis A: General ; Volume 364, Issue 1-2 , 2009 , Pages 48-56 ; 0926860X (ISSN) Izadbakhsh, A ; Farhadi, F ; Khorasheh, F ; Sahebdelfar, S ; Asadi, M ; Feng, Y. Z ; Sharif University of Technology
    2009
    Abstract
    Several SAPO-34 samples with different Si/Al ratio (0.05-0.5) of synthesis gel were prepared hydrothermally at crystallization temperature of 190-215 °C. The products were characterized by XRD, SEM/EDX, NH3-TPD, FT-IR and nitrogen adsorption techniques. EDX data showed a deviation of elemental composition of products with respect to the Al, Si, and P from that of the gel mixture, but the increasing trend of Si/Al ratio of the products was confirmed. According to XRD and SEM results, crystallinity of samples increased with Si/Al ratio up to the low to medium range of ca. 0.13. However, a reduction in the crystallinity was observed with further increase of the silicon content of the synthesis...