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    Multistep reduction of oxygen on polycrystalline silver in alkaline solution

    , Article Cuihua Xuebao/Chinese Journal of Catalysis ; Volume 31, Issue 5 , 2010 , Pages 541-546 ; 02539837 (ISSN) Jafarian, M ; Gobal, F ; Mahjani, M. G ; Hosseini Aliabadi, M ; Sharif University of Technology
    Abstract
    Oxygen reduction on a polycrystalline silver electrode was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The reaction occurred by a two-electron pathway. The steps in the mechanism were observed in the cyclic voltammograms recorded with different scan rates. The intermediates formed in the steps were detected by electrochemical impedance spectroscopy