Sharif Digital Repository

Smoothed Particle Hydrodynamics (SPH) is a Lagrangian method for simulation of fluid flow. Movable particles are used to interpolate fluid properties instead of fixed Eulerian grids in this method. By essence, the aforesaid particles are movable points which carry the fluid properties such as temperature, enthalpy, density, etc. these variables can also be the stress, strain or the rheological properties of the fluid. Thus, this method needs no grids and the fluid properties are calculated using an interpolation mechanism which classifies this method as meshless. A computational code is designed using SPH for the simulation of multiphase flows. Usage of the Lagrangian formulation has made it... 

Today, due to a massive increase in accuracy of reservoir characterization models, multiphase flow simulation on real permeability fields faces a serious challenge. Using multiscale methods in reservoir flow simulation of a heterogeneous environment has led to huge speed-up of the simulation. In multiscale methods, instead of replacing a heterogeneous medium by an equivalent homogeneous medium, used in upscaling, the problem is solved on the original resolution. In this thesis, multiscale finite volume method (MSFV) has been used to simulate flow and saturation behavior of a black oil model. Unlike the original multiscale finite volume methods that were unable to solve compressible fluid... 

In this thesis an SPH method is used for simulating multiphase two- and three-dimensional Newtonian fluid flows. The weakly compressible algorithm consists of two steps of prediction and correction. In the prediction step, the velocity field is integrated forward in time without enforcing incompressibility. The correction step consists of enforcing incompressibility by solving the pressure Poisson equation which creates a trade-off between the pressure and density variations. The surface tension force is applied in the linear momentum conservation equation by the divergence of the surface stress tensor. Advanced techniques are applied to achieve better convergence and reduce pressure-related... 

In this study various ionic liquids (ILs) and their mixtures were coated on Pt/Al2O3 catalyst and the resulted IL-coated catalyst were used in synchronous hydrogenation of cyclohexene and acetone. The rate constants (k) and seletivities (S) toward C=O hydrogenation were determined for several catalysts in various solvents. The solvatochromic parameters (ETN, normalized polarity parameter; π*, dipolarity/polarizability; β, hydrogen- bond acceptor basicity; α, hydrogen-bond donor acidity) were determined for used ILs and solvents and all obtained selectivities were modeled based on solvatochromic parameters of IL layer and bulk solvent using Multiparameter Linear Regression (MLR) method for... 

In a single chemical plant, the operation of each unit operation is not independent of each other. In the other hand, the main operations are performed in reactors following by several separation steps including distillation and purification units. The total energy requirements are sullied by the heat exchanger networks. The performance of these systems is improved by integration and intensification of the reactor and distillation column in a single unit. The main objective of the present work is to provide an effective design approach to intensify the reactor and distillation column. In a reactive distillation column, the reaction and separation is done in a single unit. Increasing... 

Functionally graded materials (FGMs) are categorized in a branch of composite materials in which the local volume fraction of contributing phases are not fixed throughout the spatial domain, but vary gradually as a function of position. This spatial variation leads to the gradual variation of physical and mechanical properties inside the materials. It provides us the opportunity of designing multiple purpose materials by the variation of local volume fractions according to our goal. The optimal distribution of local volume fractions is a function of the spatial domain geometry and loading conditions, and in general situations, due to the complexity of the problem, it is not possible to... 

By exploring huge gas-condensate reservoirs, three-phase transient flow modeling demonstrates its crucial role in designing dynamic kill, relief well parameters and kill procedure of such wells. Controlling gas-condensate well needs robust transient three phase models capable of capturing discontinuities in density, geometry and velocity of phases. In this paper, two phase Advection-Upstream-Splitting-Method hybrid scheme is extended to three-phase model capable of modeling blowout and dynamic kill in gas-condensate-water wells. Density and viscosity changes are calculated using Peng-Robinson equation of state and in according, flow model parameters are corrected.The capability of this model... 

Smoothed Particle Hydrodynamics (SPH) is a numerical Lagrangian meshless method which has numerous applications in astrophysics, hydrodynamics, free-surface flows, jets and sprays formation. Atomization of continuum liquid to fine droplets or in other words, liquid breakup processes are emerged in many engineering applications such as fuel sprays inside the combustion chamber of internal combustion engines that sizes of produced sprays significantly influence the engine’s efficiency. This research is accomplished to investigate the one-phase and two-phase flows of liquid jet breakup. For this aim, an open source code called SPHysics which solves the flow field by SPH method is utilized. This... 

Asphaltene, the heaviest and most polarizable fraction of crude oil, has a potential to precipitate, deposit and plug pipelines, causing considerable production costs. The main objective of this study is to contribute to the thermodynamic and transport modeling of asphaltene in order to predict its precipitation, segregation and deposition. Potential calculation of some thermophysical properties of asphaltene is also explored. Predicting the flow assurance issues caused by asphaltene requires the ability to model the phase behavior of asphaltene as a function of pressure, temperature and composition. It has been previously demonstrated that the Perturbed Chain form of Statistical Association... 

Different modeling and simulation techniques, new numerical methods and analyzing effects of different parameters on operation of bubble columns are continuously under study for optimized design, scale-up and prediction of industrial bubble columns. Tools for analyzing and developing gas-liquid systems are experimental techniques and computational fluid dynamics (CFD). In order to describe accurately the fluid dynamics of complex gas-liquid systems, more advanced mathematical models are required. To obtain a feasible numerical solution, efficient numerical techniques must be devised. One of such models that considerably reduces the assumptions and consequently increases the accuracy of... 

Bimetallic nanoparticles with unique structure, synergistic effect between two metals, and the tunable physical/chemical properties have been used for catalysis. Various methods exist for the staibility, and improvement of the catalytic performance of nanoparticles. In this thesis, different co-catalysts were applied to increase tha staibility, and activity of nanoparticles and metal oxides. In this way, Ni-based bimetallic nanoparticles including CuNi, CoNi, and AgNi, and AgPt with different concentrations were synthesized on the cerium oxide nanorods derived from cerium metal-organic frameworks and magnetic graphene oxide nanosheets, respectively and characterized. The catalytic... 

The effect of using backpressure of air injection in a microchannel on internal flow pressure drop were investigated in this study. Multiphase flows are commonly encountered in gas and oil industries. Flow fields in production operations are often complex and include multiphase flows of gas and liquid. Previously, because of their complex nature, these flow patterns have been mostly investigated only experimentally and empirical correlations based on the experimental data. From another point of view, it is almost impossible to experimentally realize all the flow conditions for each of the flow patterns. Nowadays computer facilities provide the tool to construct and use large-scale... 

Formation and detachment of drops are of fundamental importance in studying two-phase flows, such as ink jet printing, emulsion, and spray. Drops are formed under the effects of surface tension forces. After formation, forces like gravity detach the drop from the rest of the fluid. The flow rate is varied from dripping to jetting regime. In this project, formation and detachment of drops were simulated, using LBM with phase field model, which can simulate flows with high-density ratios and is a robust method for applying wetting condition on the walls. Results were validated using single-phase and two-phase flows. After code validation, the oscillations caused by formation and detachment of... 

Because of the importance of simulations in the oil industry, there are different software applications designed for this purpose. The purpose of the simulation in the oil industry is to reduce operational errors during the operation and to achieve the most ideal mode of operation. However, in the simulation of multiphase fluid flow because of the special circumstance, simulation plays an important role in the oil industry. OLGA multiphase flow simulation software is a strong simulation software for water, oil, Gas wells, wellhead facilities, refineries and pipelines and it is capable of simulating pipelines under various dynamic conditions. Simulation of drilling hydraulic parameters is...