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    In-situ crosslinking of electrospun gelatin-carbodiimide nanofibers: fabrication, characterization, and modeling of solution parameters

    , Article Chemical Engineering Communications ; Volume 208, Issue 7 , 2021 , Pages 976-992 ; 00986445 (ISSN) Hajiabbas, M ; Alemzadeh, I ; Vossoughi, M ; Shamloo, A ; Sharif University of Technology
    Taylor and Francis Ltd  2021
    Abstract
    This work has focused on in-situ crosslinking of gelatin (G) to produce electrospun scaffold with improved fiber morphology retention and mechanical properties. As per this approach, we prepared G nanofibers through mixing G, 1-ethyl-3-(3 dimethylaminopropyl) carbodiimide hydrochloride (EDC) and N-hydroxysuccinimide (NHS) in the new solvent system. Response surface methodology (RSM) was employed to study the influence of solution parameters on fiber diameter. The morphological structure was examined, and the appropriate level of setting to obtain smooth fibers with a favorable diameter was reported. Results revealed using EDC/NHS for in-situ crosslinking improves the mechanical properties... 

    In-situ crosslinking of electrospun gelatin-carbodiimide nanofibers: fabrication, characterization, and modeling of solution parameters

    , Article Chemical Engineering Communications ; 2020 Hajiabbas, M ; Alemzadeh, I ; Vossoughi, M ; Shamloo, A ; Sharif University of Technology
    Taylor and Francis Ltd  2020
    Abstract
    This work has focused on in-situ crosslinking of gelatin (G) to produce electrospun scaffold with improved fiber morphology retention and mechanical properties. As per this approach, we prepared G nanofibers through mixing G, 1-ethyl-3-(3 dimethylaminopropyl) carbodiimide hydrochloride (EDC) and N-hydroxysuccinimide (NHS) in the new solvent system. Response surface methodology (RSM) was employed to study the influence of solution parameters on fiber diameter. The morphological structure was examined, and the appropriate level of setting to obtain smooth fibers with a favorable diameter was reported. Results revealed using EDC/NHS for in-situ crosslinking improves the mechanical properties... 

    Immobilization of laccase from trametes hirsuta onto CMC coated magnetic nanoparticles

    , Article International Journal of Engineering, Transactions A: Basics ; Volume 33, Issue 4 , 2020 , Pages 513-519 Sadeghzadeh, S ; Ghazvini, S ; Hejazi, S ; Yaghmaei, S ; Ghobadi Nejad, Z ; Sharif University of Technology
    Materials and Energy Research Center  2020
    Abstract
    In this study Fe3O4/CMC magnetic nanoparticles were synthesized through co-precipitation method. Afterward, laccase from Trametes hirsuta was immobilized onto Carboxymethyl cellulose (CMC)-coated magnetic Fe3O4 nanoparticles by covalent bonding between carboxyl groups of carboxymethyl cellulose and amine group of laccases. Also, the resulted magnetic nanoparticles and immobilized laccase were characterized by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and dynamic light scattering (DLS) analysis. Moreover, the vital factors in enzyme immobilization, such as contact time, amount of N-hydroxysuccinimide (NHS), and the amount of nanoparticles were...