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    Quantum dots for photocatalysis: synthesis and environmental applications

    , Article Green Chemistry ; Volume 23, Issue 14 , 2021 , Pages 4931-4954 ; 14639262 (ISSN) Jouyandeh, M ; Mousavi Khadem, S ; Habibzadeh, S ; Esmaeili, A ; Abida, O ; Vatanpour, V ; Rabiee, N ; Bagherzadeh, M ; Iravani, S ; Saeb, M. R ; Varma, Rajender. S ; Sharif University of Technology
    Royal Society of Chemistry  2021
    Abstract
    Quantum dots (QDs) with unique properties have been widely employed for energy, environmental, and health care applications. Green natural resources, because of their renewability, sustainability, abundance, low cost, and environmental-friendliness, can be utilized for the synthesis of diverse nanoarchitectures. This critical review highlights the recent advancements in the greener and sustainable synthesis of carbon, graphene and metal-based QDs, as well as their significant environmental applications such as photocatalytic hydrogen production, degradation of hazardous contaminants/pollutants and reduction of CO2, with emphasis on the important challenges and future perspectives. © The... 

    Effects of initial precursor and microwave irradiation on step-by-step synthesis of zinc oxide nano-architectures

    , Article Materials Letters ; Volume 67, Issue 1 , 2012 , Pages 342-345 ; 0167577X (ISSN) Kajbafvala, A ; Samberg, J. P ; Ghorbani, H ; Kajbafvala, E ; Sadrnezhaad, S. K ; Sharif University of Technology
    Abstract
    ZnO nano-architectures were produced with the aid of a fast, simple and low cost microwave-assisted synthesis method. Solid semispherical ZnO nanoparticles on the order of 600 nm in diameter along with rice-like ZnO nanorods 95 nm thick were produced from butanol, triethanolamine (TEA), and zinc acetate dihydrate. Solid spherical ZnO nano-architectures with an average diameter of 250 nm were produced from the same starting materials in addition to NaOH. X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used to characterize the ZnO nano-architectures as well as the precursor. This method is cheap, fast and simple; capable of producing large quantities... 

    A well-dispersed Pt/Ni/TiO 2 nanotubes modified electrode as an amperometric non-enzymatic glucose biosensor

    , Article Sensor Letters ; Volume 9, Issue 5 , October , 2011 , Pages 1598-1605 ; 1546198X (ISSN) Mahshid, S. S ; Luo, S ; Yang, L ; Mahshid, S ; Dolati, A ; Ghorbani, M ; Cai, Q ; Sharif University of Technology
    2011
    Abstract
    In this study a novel Pt/Ni nanostructure consisting of nano-bushes and nanocubes was fabricated onto TiO 2 nanotubes. The scanning electron microscopy images showed that a large amount of well-dispersed nano-architectures had uniformly covered all over the surface which made an electrode with high surface area. It was obviously seen that the nanocube structures mainly consists of Ni had been grown on top of each other while the Pt colonies represented bush-like structures. As a non-enzymatic glucose biosensor, the Pt/Ni TiO 2 nanotubes modified electrode exhibited an excellent performance. The proposed biosensor had two linear ranges for detection of glucose from 0 to 0.12 mM (correlation... 

    Synergistic enhancement of photocatalytic antibacterial effects in high-strength aluminum/TiO2 nanoarchitectures

    , Article Ceramics International ; Volume 46, Issue 15 , October , 2020 , Pages 24267-24280 Mesbah, M ; Sarraf, M ; Dabbagh, A ; Nasiri Tabrizi, B ; Paria, S ; Banihashemian, S. M ; Bushroa, A. R ; Faraji, G ; Tsuzuki, T ; Madaah Hosseini, H. R ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Unlike gold and silver, aluminum shows a localized surface plasmon resonance (LSPR) over a wide spectral range from ultraviolet (UV) to the visible region. Herein, we demonstrate a new process to optically couple TiO2 nanotubes (NTs) with a high-strength aluminum substrate, to achieve a synergistic enhancement of photocatalytic antibacterial effects through controlled LSPR of aluminum. The high-strength aluminum substrate was produced by tubular channel angular pressing (TCAP). Their LSPR was tailored through the formation of superficial nano-concave arrays (NCAs) with desired concave diameters. A layer of aligned TiO2 NTs was fabricated on the surface of aluminum nano-concave arrays (Al...