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    Optimizing carbonaceous nanostructure composition as a substrate to grow co electrocatalysts

    , Article Iranian Journal of Physics Research ; Volume 17, Issue 5 , 2018 , Pages 753-760 ; 16826957 (ISSN) Pourreza, M ; Naseri, N ; Ghasemi, S ; Sharif University of Technology
    Isfahan University of Technology  2018
    Abstract
    Global warming and other adverse environmental effects of fossil fuels have forced humans to consider clean and renewable energy resources. In this context, hydrogen production from water splitting reaction is a key approach. In order to reduce required overpotential for water oxidation reaction, it is necessary to use low cost and earth abundant electrocatalysts like Co, Cu, Fe, Mn, Ni and Zn nanostructures. Herein, cobalt nanostructures on steel-mesh substrate were applied. Electrochemical method was used for growth of Co nanoflakes because of its simplicity and scalability for commercial approach. On the other hand, using carbonaceous support layers including nanomaterials such as... 

    Optimizing Co Nanoflakes Growth Parameters and Modifying Their Electro-catalytic Performance Using Carbon Nanostructures for Water Oxidation Reaction

    , M.Sc. Thesis Sharif University of Technology Pourreza, Mohammad (Author) ; Naseri, Naimeh (Supervisor)
    Abstract
    Ease of solar hydrogen production using water splitting and its environmental benefits, distinct hydrogen from other energy carriers. Hydrogen is the most abundant material in the world that make up more than 90% of the world compounds. So applying this material as a clean fuel is the best way to prevent environmental problems caused by fossil fuels. For efficient hydrogen production from water, a suitable electrocatalyst with low overpotential, high mechanical strength and reasonable catalytic activity must be utilized. In this research, cobalt based electrocatalyst was used considering that electrodepositon conditions play an important role in its final efficiency. On the other hand,... 

    Fabrication and Investigation of Co3O4 Sponged Shape Nanostructured Supercapacitor Layer Electrodes Modified by Graphene

    , Ph.D. Dissertation Sharif University of Technology Qorbani, Mohammad (Author) ; Moshegh, Alireza (Supervisor) ; Naseri, Naima (Supervisor)
    Abstract
    Recently, Supercapacitors, as one of the most important energy storage devices, have attracted attensions by the scientists. Supercapcitor devices with appoporate design can store energy by two different mechanisms: i) physical (like conventional capacitors, i.e. by using polarization of the electrolyte, and ii) formation of electric double layer) and chemical mechanisms (like batteries, with reversible faradic reactions). These energy storage mechanisms allow these devices not only store high energy density but also they can provide high power density. In this project, two Co3O4/Co(OH)2 and Co3O4@Sponge-like rGO electrodes are made with chemical and electrochemical methods. To characterize... 

    Evaluation and Optimization of Physical Properties of Graphene Oxide Nano Flakes to Confront Antibiotic Resistant Bacteria

    , M.Sc. Thesis Sharif University of Technology Najafi, Fahimeh (Author) ; Naseri, Naimeh (Supervisor)
    Abstract
    Antibacterial resistance towards existing antibiotics has become a major problem in medicine and health in recent years. Therefor it has become a challenge for scientists in different fields to find new antibiotics. Graphene and its derivatives, specially Graphene Oxide has gained attention in this area due to their unique physical properties. Graphene Oxide is considered to be a promising 2D nanomaterial for biomedical applications, due to its ease of production, stability in water, unique chemical and mechanical properties and its biocompatibility compared to other nanomaterials. In this study, graphene Oxide was synthesized using modified Hummers’ method. In order to investigate the... 

    Studying Graphene Oxide Nanoflakes Size Effect on Antibiotic Resistant Bacteria

    , M.Sc. Thesis Sharif University of Technology Homa, Kinza (Author) ; Naseri, Naimeh (Supervisor)
    Abstract
    Two-dimensional (2D) nanomaterials are ultrathin nanomaterials with a high degree of anisotropy and chemical functionality. Research on 2D nanomaterials is still in its infancy, with the majority of research focusing on elucidating unique material characteristics and few reports focusing on biomedical applications of 2D nanomaterials. Here we report the properties and application of 2Dnanomaterials in field of bio technology while used main material in our project is graphene oxide for investigating its antibacterial properties. Because the properties of graphene oxide (GO)-based materials strongly depend on the lateral size and size distribution of GO nanosheets; therefore, GO and its... 

    Electrochemical Preparation and Study of Transitional Metal Mixed Oxides as Supercapacitor Electrodes

    , Ph.D. Dissertation Sharif University of Technology Jafarzadeh, Sanaz (Author) ; Gobal, Fereydoon (Supervisor)
    Abstract
    In this thesis, the improving effects of deposited metal oxides onto or next to each other and the advantages of every metal oxide were considered. In the next step, the substrate improvement was studied and the porous metal oxides with ideal supercapacitive properties with porosity increase of substrate were obtained.CoFeO2 supercapacitor was prepared by chronoamperometric ethod.CoFeO2waselectrodeposited at room temperature and presents wide potential window and good capacitive properties in comparison with other metal oxides.Layers of cobalt and manganese oxides were co-deposited or deposited on top of each other or next to each other by chronometric method onto stainless steel substrate.... 

    Facile synthesis and simulation of MnO2 nanoflakes on vertically aligned carbon nanotubes, as a high-performance electrode for Li-ion battery and supercapacitor

    , Article Electrochimica Acta ; Volume 390 , 2021 ; 00134686 (ISSN) Abdollahi, A ; Abnavi, A ; Ghasemi, F ; Ghasemi, S ; Sanaee, Z ; Mohajerzadeh, S ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    This study reports the successful fabrication of high-performance flexible binder-free lithium-ion battery anode and supercapacitor based on the synthesis of 3D hierarchical MnO2 nanoflakes (NFs) on vertically aligned carbon nanotubes (VACNTs) grown upon stainless steel (SS). The experimental results revealed that the prepared electrodes were well served as supercapacitors with a tremendous specific capacitance of MnO2 NFs VACNT/SS 1131 F/g at 0.25 A/g in 0.5 mol.L−1 Na2SO4, 518.8% more than VACNT/SS (218 F/g). Compared to other MnO2 NFs/CNT composites, as-fabricated binder-free MnO2 NFs/VACNTs electrode achieves outstanding performance with high initial discharge and charge capacities of... 

    Facile synthesis and simulation of MnO2 nanoflakes on vertically aligned carbon nanotubes, as a high-performance electrode for Li-ion battery and supercapacitor

    , Article Electrochimica Acta ; Volume 390 , 2021 ; 00134686 (ISSN) Abdollahi, A ; Abnavi, A ; Ghasemi, F ; Ghasemi, S ; Sanaee, Z ; Mohajerzadeh, S ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    This study reports the successful fabrication of high-performance flexible binder-free lithium-ion battery anode and supercapacitor based on the synthesis of 3D hierarchical MnO2 nanoflakes (NFs) on vertically aligned carbon nanotubes (VACNTs) grown upon stainless steel (SS). The experimental results revealed that the prepared electrodes were well served as supercapacitors with a tremendous specific capacitance of MnO2 NFs VACNT/SS 1131 F/g at 0.25 A/g in 0.5 mol.L−1 Na2SO4, 518.8% more than VACNT/SS (218 F/g). Compared to other MnO2 NFs/CNT composites, as-fabricated binder-free MnO2 NFs/VACNTs electrode achieves outstanding performance with high initial discharge and charge capacities of... 

    Copper oxide nanoflakes as highly sensitive and fast response self-sterilizing biosensors

    , Article Journal of Materials Chemistry ; Volume 21, Issue 34 , Jul , 2011 , Pages 12935-12940 ; 09599428 (ISSN) Akhavan, O ; Ghaderi, E ; Sharif University of Technology
    2011
    Abstract
    Vertical copper oxide nanoflakes were synthesized on a Cu foil through oxidation in alkaline conditions. X-ray photoelectron spectroscopy showed that after exposing the nanoflakes to an Escherichia coli bacterial suspension, the outermost surface of the nanoflakes was chemically reduced through the glycolysis process of the bacteria. Current-voltage (I-V) characteristics of the nanoflakes (measured perpendicular to surface of the Cu foil by using conductive atomic force microscopy) indicated that electrical resistivity of the nanoflakes increased about one order of magnitude after exposure to the bacterial suspension. The nanoflakes reduced by the bacterial suspension could also be... 

    Hierarchical Co3O4/Co(OH)2 nanoflakes as a supercapacitor electrode: experimental and semi-empirical model

    , Article ACS Applied Materials and Interfaces ; Volume 7, Issue 21 , 2015 , Pages 11172-11179 ; 19448244 (ISSN) Qorbani, M ; Naseri, N ; Moshfegh, A. Z ; Sharif University of Technology
    American Chemical Society  2015
    Abstract
    In this research, facile and low cost synthesis methods, electrodeposition at constant current density and anodization at various applied voltages, were used to produce hierarchical cobalt oxide/hydroxide nanoflakes on top of porous anodized cobalt layer. The maximum electrochemical capacitance of 601 mF cm-2 at scan rate of 2 mV s-1 was achieved for 30 V optimized anodization applied voltage with high stability. Morphology and surface chemical composition were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analysis. The size, thickness, and density of nanoflakes, as well as length of the porous anodized Co layer were measured about 460 ± 45 nm,... 

    Selecting Support Layer for Electrodeposited Efficient Cobalt Oxide/Hydroxide Nanoflakes to Split Water

    , Article ACS Sustainable Chemistry and Engineering ; Volume 4, Issue 6 , 2016 , Pages 3151-3159 ; 21680485 (ISSN) Naseri, N ; Esfandiar, A ; Qorbani, M ; Moshfegh, A. Z ; Sharif University of Technology
    American Chemical Society  2016
    Abstract
    Energy and environment crises motivated scientists to develop sustainable, renewable, and clean energy resources mainly based on solar hydrogen. For this purpose, one main challenge is the low cost flexible substrates for designing earth abundant efficient cocatalysts to reduce required water oxidation overpotential. Here, a systematic morphological and electrochemical study has been reported for cobalt oxide/hydroxide nanoflakes simply electrodeposited on four different commercially available substrates, titanium, copper sheet, steel mesh, and nickel foam. Remarkable dependence between the used substrate, morphology, and electrocatalytic properties of nanoflakes introduced flexible porous... 

    Engineered cost-effective growth of Co-based nanoflakes as a sustainable water oxidation electrocatalyst

    , Article Journal of Physics D: Applied Physics ; Volume 50, Issue 47 , 2017 ; 00223727 (ISSN) Pourreza, M ; Naseri, N ; Sharif University of Technology
    Abstract
    Developing low-cost, scalable and reproducible synthesis methods for water oxidation reaction (WOR) catalysts is highly desirable and also challenging in energy, environmental and industrial applications. In this context, electrochemical deposition is known as an easy and cost-effective technique in nanomaterial growth. Herein, cobalt-based nanoflakes were grown on a flexible and commercially available steel mesh substrate by electrodeposition approach with a crystalline structure as a mixture of oxide, hydroxide and oxyhydroxide phases. For the first time, the correlation between electrodeposition parameters, time and current density, and morphological characteristics of the grown... 

    On the performance of vertical MoS2 nanoflakes as a gas sensor

    , Article Vacuum ; Volume 167 , 2019 , Pages 90-97 ; 0042207X (ISSN) Barzegar, M ; Iraji zad, A ; Tiwari, A ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Despite their potential applications, a limited number of studies for synthesizing vertical MoS2 nanoflakes especially via CVD have been reported so far, which generally involve tedious complex- and/or multi-step growth processes. In this study, direct synthesis of vertical MoS2 nanoflakes grown on the SiO2/Si substrate during a rapid sulfidation process by CVD method has been reported. Material characterization was performed using Raman spectroscopy, XRD and FE-SEM. The XRD results indicated the dominant phase of 2H–MoS2 within the synthesized layers. The characteristic distance between the two dominant peaks of E1 2g and A1g in the Raman spectra confirms the multi-layered structure for... 

    Sustainable starfish like cobalt electrocatalyst grown on optimized CNT-graphene hybrid host for efficient water oxidation

    , Article Applied Surface Science ; Volume 524 , 15 September , 2020 Naseri, N ; Ghasemi, S ; Pourreza, M ; Moshfegh, A. Z ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Solar energy generation is one of the most efficient approach to solve emerging environment and energy challenges. In this context, solar assisted dissociation of water into oxygen and hydrogen utilizing scalable and high performance electrocatalysts plays key role since the produced hydrogen is a clean energy carrier. Here, cobalt based nanoflakes with metallic core and oxidized surface were grown on the designed carbonaceous layer for anodic oxygen evolution reaction (OER) using an electrochemical approach. Carbonaceous layers containing proper amount of carbon nanotubes (CNT) and reduced graphene oxide (rGO) species were used to optimize the system. Although higher weight percent of rGO... 

    Sensing behavior of flower-shaped MoS2 nanoflakes: Case study with methanol and xylene

    , Article Beilstein Journal of Nanotechnology ; Volume 9, Issue 1 , 2018 , Pages 608-615 ; 21904286 (ISSN) Barzegar, M ; Berahman, M ; Iraji zad, A ; Sharif University of Technology
    Beilstein-Institut Zur Forderung der Chemischen Wissenschaften  2018
    Abstract
    Recent research interest in two-dimensional (2D) materials has led to an emerging new group of materials known as transition metal dichalcogenides (TMDs), which have significant electrical, optical, and transport properties. MoS2 is one of the well-known 2D materials in this group, which is a semiconductor with controllable band gap based on its structure. The hydrothermal process is known as one of the scalable methods to synthesize MoS2 nanostructures. In this study, the gas sensing properties of flower-shaped MoS2 nanoflakes, which were prepared from molybdenum trioxide (MoO3) by a facile hydrothermal method, have been studied. Material characterization was performed using X-ray... 

    Mesoporous nanostructures of NiCo-LDH/ZnCo2O4 as an efficient electrocatalyst for oxygen evolution reaction

    , Article Journal of Colloid and Interface Science ; Volume 604 , 2021 , Pages 832-843 ; 00219797 (ISSN) Shamloofard, M ; Shahrokhian, S ; Amini, M. K ; Sharif University of Technology
    Academic Press Inc  2021
    Abstract
    Increasing energy demands for pollution-free and renewable energy technologies have stimulated intense research on the development of inexpensive, highly efficient, and stable non-noble metal electrocatalysts for oxygen evolution reaction (OER). In this study, a superior OER performance was achieved using a tri-metallic (Zn, Co, Ni) high-performance electrocatalyst. We successfully fabricated a peony-flower-like hierarchical ZnCo2O4 through an additive-free hydrothermal reaction followed by heat treatment. Then NiCo-LDH (layered double hydroxides) nano-flakes was electrodeposited on the ZnCo2O4/GCE surface to prepare NiCo-LDH/ZnCo2O4/GCE which was used as electrode for OER. The structure and...