Sharif Digital Repository

Potential applications of the molecularly imprinted polymers (MIPs) demand physical configurations in different size ranges. Nowadays, research on MIPs is focused on the development of new or improved morphologies, which involves control and modification of the different parameters during the synthesis. In this study, the effect of different synthesis conditions on the particle size and morphology is investigated. Carbamazepine-imprinted polymers were prepared using precipitation polymerization under various conditions such as: the amounts of cross-linker and functional monomers, initiator, porogen, temperature and time of polymerization. We studied the polymerization conditions to obtain... 

In this paper, Mindlin's second strain gradient theory is formulated and presented in an arbitrary orthogonal curvilinear coordinate system. Equilibrium equations, generalized stress-strain constitutive relations, components of the strain tensor and their first and second gradients, and the expressions for three different types of traction boundary conditions are derived in any orthogonal curvilinear coordinate system. Subsequently, for demonstration, Mindlin's second strain gradient theory is represented in the spherical coordinate system as a highly-practical coordinate system in nanomechanics. Second strain gradient elasticity have been developed mainly for its ability to capture the... 

In this paper, we present a formulation based on the Green's function to study the backaction cooling of a levitated nanosphere in an arbitrary structure. This formulation has enabled us to study the dynamical backaction effect and the possibility of cooling in the absence of a cavity or when the nanosphere is trapped outside a cavity and excites a continuum of electromagnetic modes. We also investigate the roles of the Stokes and anti-Stokes processes, separately, and show that the anti-Stokes process is not necessarily the sole cooling agent. This is in sheer contrast with the intracavity cooling scenario. © 2019 American Physical Society  

For the first time graphene nanosheets and carbon nanospheres/chitosan (GNS-CNS/CS) based nanocomposite film modified electrode was used for the electro-oxidation of mebendazole (MD). MD is a benzimidazole drug that is used to treat human infections caused by parasitic worms. MD causes slow immobilization and death of the worms by selectively and irreversibly blocking uptake of glucose. The electrochemical behavior of MD at GNS-CNS/CS modified glassy carbon electrode has been investigated using cyclic and differential pulse voltammetry in aqueous media at different pHs. The prepared electrode showed an excellent electrochemical activity toward the electro-oxidation of MD leading to a... 

A novel nanocarrier based-on hollow mesoporous carbon nanospheres (HMCNs) with primary amines on its surface, a large cavity, and good hydrophilicity was synthesized by a hydrothermal reaction. The primary amine functionalities on the mesoporous carbon were used as the initiation sites for growing poly (epichlorohydrin) (PCH) chains. The chlorine groups in the side chain of PCH were replaced with imidazole as the pendant groups. Calcium chloride (CaCl2) was applied as a capping agent. The coordination bonding was formed between pendant imidazole groups and calcium ions. Doxorubicin (DOX) was selected as a model of hydrophilic anticancer drug and was loaded onto the nanocarrier and released... 

In this contribution, spinel MgAl2O4 nanospheres prepared by the combustion method were coupled with thermally-exfoliated g-C3N4 nanosheets (TE-GCN) through an efficient isoelectric point-assisted calcination technique. Physical characteristics of the synthesized nanocomposite were understudied utilizing the XRD, FT-IR, FE-SEM, TEM, BET-BJH, UV–Vis DRS, PL, and EIS analyses. This material was used as a novel nano-photocatalyst for degradation of reactive red 195 (RR195) industrial dye contaminant. Results revealed that, a successful synthesis of a heterojunction between the components of the nanocomposite was achieved. This exhibited an enormously improved electron-hole separation leading to... 

In recent years, development of high-performance supercapacitor electrode materials has stimulated a great deal of scientific research. The electrochemical performance of a supercapacitor strongly depends on its material structures. Herein, we report a simple strategy for high-performance supercapacitors by building pseudocapacitive CuS nanospheres with nanoporous structures, nanosized walls (<10 nm) and relatively large specific surface area of 65 m2/g. This electrode demonstrates excellent electrochemical performance including a maximum specific capacitance of 814 F/g at 1 A/g, significant rate capability of 42% capacitance retention at an ultrafast rate of 50 A/g, and outstanding... 

In this paper, we investigate cooling of a levitated nanosphere in a system of coupled cavities in the resolved sideband regime. Thanks to the presence of an extra resonance in the coupled cavity cooling system, the coupling strength can be maximized at the optimum detuning. In this fashion, the intracavity photon number is increased, and thereby the cooling rate is enhanced and the strong coupling regime is achieved without resorting to increased driving laser power. The underlying physics of the increased cooling efficiency in the system of coupled cavities in the resolved sideband regime proposed here and that of the already reported system of coupled cavities in the unresolved sideband... 

In this study, a hybrid of silica nanosphere/multiwall carbon nanotube (MWCNT) has been synthesized by wet chemical method at room temperature. The effect of MWCNTs, silica nanospheres and hybrid nanostructures (80% silica nanosphere/20% MWCNT and 50% silica nanosphere/50% MWCNT) on the thermal conductivity of distilled water has been investigated. SDBS was used as the dispersant to stabilize nanomaterials in the aqueous suspension and its concentration was 1.5 times of the concentration of nanomaterials. As results show, by increasing the concentration of nanomaterials, effective thermal conductivity of nanofluids increased. The most and the least enhancement in the effective thermal... 

In this article, the synthesis procedure of mesoporous carbon nanospheres (MCNSs) using silica hard-templates, doping of the nanospheres with walnut extract, and their impact on active protective properties of an epoxy coating are presented. Field emission scanning electron microscope (FE-SEM) results showed that the synthesis of these nanocontainers was successfully done in spherical form. Thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR) results showed that walnut extract as a green inhibitor was doped into the pores of nanocapsules. Corrosion resistance of the mild steel samples in the 3.5 wt.% NaCl solution in the presence and absence of walnut extract... 

Regarding the importance of rheological properties of water based drilling fluids, the effects of silica nanospheres, multiwall carbon nanotubes (MWCNTs) and two types of their hybrid, i.e. H1 (80 wt.% silica nanosphere/20 wt.% MWCNT) and H2 (50 wt.% silica nanosphere/50 wt.% MWCNT) on the viscosity and density of distilled water were investigated. According to the results, viscosity and density of the nanofluids increased with the concentration, while they were reduced by increasing the temperature. At high concentrations, the least increase in the viscosity of distilled water by adding the nanomaterials is related to H2 (8.2% increase at 1.0 wt.%). Likewise, the optimum operating... 

A novel ultrasensitive modified electrode was fabricated with a graphene nanosheets and carbon nanospheres (GNS-CNS)-based nanocomposite film as a powerful platform. Pt nanoparticles (PtNPs) were simply electrodeposited onto the GNS-CNS-coated glassy carbon electrode creating a PtNPs/GNS-CNS hybrid nanocomposite modified electrode. Scanning electron microscopy, energy dispersive X-ray spectroscopy and linear sweep voltammetry (LSV) techniques were used for the characterization of the prepared modified electrode. The results of investigation of electrochemical response characteristics of cefepime (CP) revealed a considerable improvement in the oxidation peak current of CP on PtNPs/GNS-CNS/GCE... 

In this work the plasmonic photocatalytic activity of ZnO/noble metals nanocomposites has been investigated. Ag nanowires and Au nanospheres were prepared and mixed with ZnO in order to prepare the nanocomposites. It was demonstrated that the composites containing the plasmonic Ag nanowires and ZnO nanoparticles showed a significant photocatalytic activity enhancement compared to the pure ZnO in decomposition of methylene blue (MB). By investigation of mechanisms governing the performance of plasmonic photocatalysts, it was found that the photocatalytic activity enhancement can be attributed to the energy transfer from Ag nanowires to the ZnO nanoparticles induced by the surface plasmonic... 

There has been a growing demand for materials with superior absorption capabilities, such as strong absorbing capacity, thin thickness, and light weight, to solve challenges related to EM radiation pollution. While the majority of the research is focused on optimizing material compositions, component microstructure and absorber structure are also critical factors for improving microwave absorption performance. In this research, we show how the microstructure of components and absorber design may increase dissipation features. Solvothermal and hydrothermal methods were utilized for synthesizing mesoporous CuS micro-particles with a 3D hierarchical structure as a dielectric component and... 

For the efficient removal of some anionic dyes, a novel adsorbent was developed. The adsorbent was prepared by coating a synthetic polymer on magnetite nanosphere surface as a magnetic carrier. The synthesized nano-adsorbent was fully characterized using Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer, X-ray diffractometer, scanning electron microscope, and transmission electronic microscopy measurements. The synthesized nano-adsorbent showed high adsorption capacity towards removal of some anionic dyes (221.4, 201.6, and 135.3 mg g-1 for reactive red 195, reactive yellow 145, and reactive blue 19 dye, respectively) from aqueous samples. The dye adsorption was... 

Over the last few years, substantial efforts have been made to develop earth-abundant bi-functional catalysts for urea oxidation and energy-saving electrolytic hydrogen production due to their low cost and the potential to replace traditional noble-metal-based catalysts. Nevertheless, finding a straightforward and effective route to prepare efficient catalysts with unique structural features and optimal supports still is a big challenge. Among the various candidates, metal-organic framework (MOF)-derived materials show great advantages as new kinds of active non-precious catalysts. On the other hand, the controllable integration of MOFs and carbon-based nanomaterials leads to further... 

In the present work, N-doped hollow carbon nanospheres (N-HCNSs) is prepared by direct carbonization of polyaniline-co-polypyrrole (PACP) hollow spheres without template needing. Two different NiO nanostructures (nanosheets and nanowires) are prepared by forming a shell around the N-HCNSs via simple hydrothermal/calcination processes (NiO-NSs@N-HCNSs and NiO-NWs@N-HCNSs). The morphology and structure of the nanostructures are characterized using field emission scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The prepared nanocomposites are used as catalysts for the electrocatalytic... 

During the last few decades, nanotechnology has established many essential applications in the biomedical field and in particular for cancer therapy. Not only can nanodelivery systems address the shortcomings of conventional chemotherapy such as limited stability, non-specific biodistribution and targeting, poor water solubility, low therapeutic indices, and severe toxic side effects, but some of them can also provide simultaneous combination of therapies and diagnostics. Among the various therapies, the combination of chemo- and photothermal therapy (CT-PTT) has demonstrated synergistic therapeutic efficacies with minimal side effects in several preclinical studies. In this regard,... 

Exploring bi-functional electrocatalysts with excellent activity, good durability, and cost-effectiveness for electrochemical hydrogen and oxygen evolution reactions (HER and OER) in the same electrolyte is a critical step towards a sustainable hydrogen economy. Three main features such as high density of active sites, improved charge transfer, and optimized electronic configuration have positive effects on the electrocatalyst activity. In this context, understanding structure–composition–property relationships and catalyst activity is very important and highly desirable. Herein, for the first time, we present the design and fabrication of novel MOF-derived ultra-small Ru/RuO2 nanoparticles...