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    Numerical simulation of electro-deposition process influenced by force convection and migration of ions

    , Article Journal of Electroanalytical Chemistry ; Volume 782 , 2016 , Pages 117-124 ; 15726657 (ISSN) Zahraei, M ; Saidi, M. S ; Sani, M ; Sharif University of Technology
    Elsevier B.V  2016
    Abstract
    Electro-deposition process is one of the main steps in the LIGA procedure to fabricate microstructures. In this paper, one-dimensional modeling of Nickel electro-deposition process is implemented on Rayan and developed for simulation of time-dependence diffusion and migration of charge species with reduction reactions on the cathode surface. This model is proposed by considering governing equations on electro-kinetic phenomena consist of Nernst-Plank equation and Poisson's equation of electric potential. Transport of ions toward the cathode is considered based on the effect of convection, reaction rate, diffusion and migration. The numerical results cover two series of data consisting of... 

    Dynamics of electrostatic interaction and electrodiffusion in a charged thin film with nanoscale physicochemical heterogeneity: Implications for low-salinity waterflooding

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 650 , 2022 ; 09277757 (ISSN) Pourakaberian, A ; Mahani, H ; Niasar, V ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    The slow kinetics of wettability alteration toward a more water-wetting state by low-salinity waterflooding (LSWF) in oil-brine-rock (OBR) systems is conjectured to be pertinent to the electrokinetic phenomena in the thin brine film. We hypothesize that the nanoscale physicochemical heterogeneities such as surface roughness and surface charge heterogeneity at the rock/brine interface control further the dynamics of electrodiffusion and electrostatic disjoining pressure (Πel), thus the time-scale and the magnitude of the low salinity effect (LSE). In this regard, film-scale computational fluid dynamics (CFD) simulations were performed. The coupled Poisson-Nernst-Planck (PNP) equations were...