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    Electrochemical Determination of Tyrosine and Tryptophan at the Surface of Pyrolytic Graphite Electrode Modified with Multi-Walled Carbon Nanotubes, New Coccine and Nitrazine

    , M.Sc. Thesis Sharif University of Technology Ebrahimi, Shiva (Author) ; Shahrokhian, Saeed (Supervisor)
    At the first part of this thesis, a pyrolitic graphite electrode (PGE) modified with new coccine/multi-walled carbon nanotubes film (NC/MWCNT) was applied as a sensitive electrochemical sensor for determination and study of electrochemical behavior of tyrosine (Tyr) in aqueous solutions. The results showed that NC/MWCNT caused a remarkable increase in the peak current so the NC/MWCNT/PGE electrode surface was far more sensitive to the concentration of Tyr than the PGE surface. The determination of Tyr was investigated by linear sweep voltammetry (LSV). Experimental parameters, such as scan rate, pH and amount of the modifier used on the PGE surface were optimized by monitoring the LSV... 

    Glassy carbon electrode modified with a bilayer of multi-walled carbon nanotube and polypyrrole doped with new coccine: Application to the sensitive electrochemical determination of Sumatriptan

    , Article Electrochimica Acta ; Volume 56, Issue 27 , November , 2011 , Pages 10032-10038 ; 00134686 (ISSN) Shahrokhian, S ; Kamalzadeh, Z ; Saberi, R. S ; Sharif University of Technology
    A promising electrochemical sensor was developed based on a layer by layer process by electro-polymerization of pyrrole in the presence of new coccine (NC) as dopant anion on the surface of the multi-walled carbon nanotubes (MWCNTs) pre-coated glassy carbon electrode (GCE). The modified electrode was used as a new and sensitive electrochemical sensor for voltammetric determination of sumatriptan (SUM). The electrochemical behavior of SUM was investigated on the surface of the modified electrode using linear sweep voltammetry (LSV). The results showed a remarkable increase (∼12 times) in the anodic peak current of SUM in comparison to the bare GCE. The effect of experimental variables such... 

    Electrochemical determination of clozapine on MWCNTs/new coccine doped ppy modified GCE: An experimental design approach

    , Article Bioelectrochemistry ; Volume 90 , 2013 , Pages 36-43 ; 15675394 (ISSN) Shahrokhian, S ; Kamalzadeh, Z ; Hamzehloei, A ; Sharif University of Technology
    The electrooxidation of clozapine (CLZ) was studied on the surface of a glassy carbon electrode (GCE) modified with a thin film of multiwalled carbon nanotubes (MWCNTs)/new coccine (NC) doped polypyrrole (PPY) by using linear sweep voltammetry (LSV). The pH of the supporting electrolyte (D), drop size of the cast MWCNTs suspension (E) and accumulation time of CLZ on the surface of modified electrode (F) was considered as effective experimental factors and the oxidation peak current of CLZ was selected as the response. By using factorial-based response-surface methodology, the optimum values of factors were obtained as 5.44, 10 μL and 300 s for D, E and F respectively. Under the optimized...