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    Design and Fabrication of Supercapacitors Based on Modified Carbon Nanospheres Using Transition Metal Oxide/Hydroxide

    , M.Sc. Thesis Sharif University of Technology Abbasi, Samaneh (Author) ; Shahrokhian, Saeed (Supervisor)
    Abstract
    Herein a simple tow step method is developed to design hierarchical binder free structure of binary nickel cobalt carbonate hydroxide decorated hydrothermal carbon sphere. First carbon sphere were synthesized on nickel foam via hydrothermal process using glucose solution followed by carbonization process. Ni Co carbonate hydroxide core shell array were directly grown on binder free carbon spheres using hydrothermal method. The synthesized electrode afforded high specific capacitance (497/83 mAhg-1 at a current density of 1/4 A g-1) and good cyclic stability (85% after 1500 charge / discharge cycles). EIS measurement showed negligible internal resistance (0.638 Ω) which is attributed to the... 

    Preparation and Investigations of Flexible Supercapacitors Using Nanocomposites with Graphene-based Structures and Layered double hydroxide Ni/Co and Manganese Molybdate

    , Ph.D. Dissertation Sharif University of Technology Mehrabi Matin, Bahareh (Author) ; Shahrokhian, Saeed (Supervisor) ; Iraji-zad, Azam (Supervisor)
    Abstract
    In the first part of this research, for the first time, we introduced a flexible high performance graphene-based supercapacitor using silver fiber fabric as the current collector. The silver fiber fabric offers remarkable advantages such as light weight, mechanical flexibility and ease of integration with electronic textiles, which well-suited for wearable energy storage devices. A new hybrid material of graphene-silver fiber fabric (rGO/SFF) was prepared through a facile electrophoretic deposition of graphene and being used as a binder-free flexible supercapacitor electrode. In order to obtain the optimum condition, the effect of deposition time was investigated and a duration time of 10... 

    Investigation of Electrocatalytic Behavior of Some Transition Metal Oxides, Sulfides and Phosphides Nanostructures Toward Electrochemical Water Splitting

    , M.Sc. Thesis Sharif University of Technology Shamloofard, Maryam (Author) ; Shahrokhian, Saeed (Supervisor)
    Abstract
    Energy and the environment issues are among the most important concerns of the present age. Global demand for energy is growing rapidly and energy demand is projected to double in the coming years. However, today most of the energy consumption comes from fossil fuels, which have limited and unstable reserves and are among the sources of environmental pollution. Hence, the production and conversion of clean energy from renewable sources is considered as an intelligent solution to significantly reduce dependence on fossil fuels and protect the environment. Fuel cells, metal-air batteries, and water electrolysis are among the simplest, most efficient, and most reliable technologies among... 

    Nickel-cobalt layered double hydroxide ultrathin nanosheets coated on reduced graphene oxide nonosheets/nickel foam for high performance asymmetric supercapacitors

    , Article International Journal of Hydrogen Energy ; 2017 ; 03603199 (ISSN) Shahrokhian, S ; Rahimi, S ; Mohammadi, R ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    Here in, for the first time, we report a new and simple procedure for preparing reduced graphene oxide/nickel-cobalt double layered hydroxide composite on the nickel foam (Ni-Co LDH/rGO/NF) via a fast and simple two-step electrochemical method including potentiostatic routes in the presence of CTAB as a cationic surfactant. Graphene oxide coated nickel foam prepared by simple immersion method. After that, the prepared electrode reduced electrochemically to obtain rGO/NF electrode. Finally, the rGO/NF electrode was used as cathode for electrodeposition of Ni-Co LDH in the presence of CTAB as cationic surfactant. The prepared electrodes were characterized by field emission scanning electron... 

    Nickel-cobalt layered double hydroxide ultrathin nanosheets coated on reduced graphene oxide nonosheets/nickel foam for high performance asymmetric supercapacitors

    , Article International Journal of Hydrogen Energy ; Volume 43, Issue 4 , 2018 , Pages 2256-2267 ; 03603199 (ISSN) Shahrokhian, S ; Rahimi, S ; Mohammadi, R ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Here in, for the first time, we report a new and simple procedure for preparing reduced graphene oxide/nickel-cobalt double layered hydroxide composite on the nickel foam (Ni-Co LDH/rGO/NF) via a fast and simple two-step electrochemical method including potentiostatic routes in the presence of CTAB as a cationic surfactant. Graphene oxide coated nickel foam prepared by simple immersion method. After that, the prepared electrode reduced electrochemically to obtain rGO/NF electrode. Finally, the rGO/NF electrode was used as cathode for electrodeposition of Ni-Co LDH in the presence of CTAB as cationic surfactant. The prepared electrodes were characterized by field emission scanning electron...