Sharif Digital Repository

This work presents solid-state thermal decomposition synthesis of transition metal ferrites (MFe2O4, M = Zn, Ni, Cd). In this method, binary complexes of [Zn(en)3]3[Fe(ox)3]2, [Cd(en)3]3[Fe(ox)3]2 and [Ni(en)3]3[Fe(ox)3]2 (where en = ethylenediamine and ox = oxalate) are introduced as new single-source precursors to fabricate ZnFe2O4, CdFe2O4 and NiFe2O4 micro/nanostructures, respectively. X-ray powder diffraction (XRD) patterns show that pure CdFe2O4 and NiFe2O4 are formed by thermal decomposition of the single-source precursors at 800°C. When thermal decomposition of [Zn(en)3]3[Fe(ox)3]2 complex is carried out at 700 and 800°C, the final products are composed of ZnFe2O4 and metal oxides.... 

A simple and low-cost electrochemical deposition method is used to prepare reduced graphene oxide/polypyrrole/Cu2O-Cu(OH)2 (RGO/PPy/Cu2O-Cu(OH)2) ternary nanocomposites as the electrode material for supercapacitor application. First, graphene oxide-polypyrrole (GO/PPy) nanocomposite is electrochemically synthesized on Ni foam by electro-oxidation of pyrrole monomer in an aqueous solution containing GO and Tiron. Subsequently, the GO/PPy film is converted to the corresponding reduced form (RGO/PPy) by an effective and eco-friendly electrochemical reduction method. Then, a thin layer of Cu2O-Cu(OH)2 is formed on RGO/PPy film by chronoamperometry. The RGO/PPy/Cu2O-Cu(OH)2 nanocomposite is... 

In order to deal with the limitations of micro-pumps and micro-valves and meet the advantages of magnetic systems a novel plan is described here. The idea behind the plan is that magnetic particles, mixed and dispersed in a carrier liquid, can be accumulated and retained at specific sites to form pistons in a micro-tube using some external magnetic field sources along the tube. In other words, using some solenoids and switching them on and off, in a specific order and period, causes the desired external magnetic field variation through the tube. Changing the period and the mode of activation and deactivation of the solenoids, which are called switching time and switching mode, respectively,... 

Fluid control, namely pumping and valving, is a critical factor in the performance of micro-fluidic systems. In recent years a variety of micro-fluidic systems are developed for the purpose of miniaturizing fluid handling, and chemical analysis to develop Lab On a Chip (LOC) technology. The mentioned facts resulted in design and fabrication of a novel hydromagnetic flow controller. The idea behind this device is that magnetic particles, mixed and dispersed in a carrier liquid, can be accumulated in the form of a piston. Depending upon dragging speed of these pistons, which itself is a function of switching time, this device can be used to either increase (pumping) or decrease (valving) the... 

The size and morphology of secondary phase and intermetallic compounds in gas atomized Al- 20Si-5Fe-2X (X=Cu, Ni, Cr) powders were studied. It was shown that the microstructure compromised of fine particle-like primary Si, aciculate δ-Al9FeSi3 intermetallic compound containing small amount of dissolved alloying elements, and fine Al-Si eutectic matrix. Decreasing the powder particle size yields finer primary silicon but its morphology is not affected. Also, significant refinement in the size of δ-Al9FeSi3 intermetallic was observed as the particles become finer. This particle size effect on the microstructure of Al-20Si-5Fe alloy was found to be influenced by the presence of chromium. Here,... 

The novel idea of the Hydromagnetic Micropump and Flow Controller (HMFC) is used in this paper to construct a laboratory setup capable of bidirectional pumping and controlling the flow in microtubes. A laboratory setup, which contains no moving parts, is integrated with a pressure-driven flow setup to make the presented HMFC device. The device operation is based on controllable motion of magnetic particles, added to the carrier fluid, caused by the magnetic field, produced by solenoids located just next to the microtube. The magnitude of these forces is proportional to the strength and gradient of magnetic field which, in turn, is related to the electrical current and arrangement of the... 

Co-Ce doped Ni nanocrystalline ferrites having composition Ni0.8Ce0.2CoxFe2-xO4 with x = 0.00, 0.25, 0.50, 0.75, 1.00 were fabricated by sol gel auto combustion method. Synthesized samples were investigated by thermal gravimetric and differential thermal analysis (TGA-DTA), Fourier transform infrared spectroscopy (FTIR), x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis (EDX) and vibrating sample magnetometer (VSM) to study the phase, vibrational modes, structure, surface analysis and magnetic properties respectively. Structural parameters (lattice parameters, cell volume, crystallite size and micro strains) were also calculated from XRD recorded data....