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    Elevated-temperature behaviour of LiNi0.5Co0.2Mn0.3O2 cathode modified with rGO-SiO2 composite coating

    , Article Journal of Alloys and Compounds ; Volume 843 , 2020 Razmjoo Khollari, M. A ; Khalili Azar, M ; Esmaeili, M ; Tanhaei, M ; Dolati, A ; Hosseini H, S. M ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    An intense decrease in cycling performance and safety is a challenge for elevated temperature application of LiNi0.5Co0.2Mn0.3O2 (NCM) cathode material. In this paper, effect of two types of nano-coatings on improvement of elevated temperature performance of NCM cathode material has been investigated. One of the coatings contains SiO2 nanoparticles and the other one contains composite of reduced graphene oxide and SiO2 nanoparticles (rGO-SiO2). The coatings were fabricated by a facile wet chemical method. The SiO2 coated cathode material showed an excellent elevated temperature cycling stability, however, a decrease in discharge capacity and rate capability of this sample was observed. On...