Sharif Digital Repository

Production of NiTi alloy from elemental powders was conducted by mechanical alloying (MA) and sintering of the raw materials. Effects of milling time and milling speed (RPM) on crystallite size, lattice strain, and XRD peak intensities were investigated by X-ray analysis of the alloy. Powder compaction and sintering time and temperature effects on pore percentage of the as-mixed and the mechanically alloyed samples were empirically evaluated. The crystallite size of the mechanically alloyed Ni50Ti50 samples decreased with MA duration and with the milling speed. Depending on the crystal structure of the raw materials, the lattice strain increases with the milling duration. Metallographic... 

In the present research work the binary NiTi alloys with various compositions in the range of 50.3-51 at.% Ni were used. Samples have been annealed at 850 °C for 15 min and then quenched in water. In order to characterize transformation temperatures and enthalpy changes of the forward and the reverse martensitic transformation, Differential Scanning Calorimetric (DSC) experiments were performed. The enthalpy and entropy changes as a function of Ni atomic content have been thermodynamically investigated. Results show that enthalpy and entropy changes of martensitic transformation decrease when Ni atomic content increases. The variation of enthalpy and entropy of martensitic transformation... 

Nickel titanium shape memory alloys (NiTi-SMAs) were successfully produced from elemental Ni/Ti powders by powder metallurgical method and then subjected to age treatment. Microstructure was examined by SEM and XRD and phase transformation temperatures were measured by dilatometric method. The phase transformation temperatures increased with both duration and temperature of the age treatment. The porous product exhibited desirable shape memory effect. © 2009 Elsevier B.V. All rights reserved  

The influence of Cu addition on the hot deformation behavior of NiTi shape memory alloys was investigated using hot compression test. A series of alloys with different Cu contents of Ti50.4Ni49.6-xCux (x = 0, 3, 5, 7 at.%) were deformed under compression to a true strain of 0.7 at the temperature range of 700-1000 °C with 100 °C intervals and constant strain rate of 0.1 s-1. The stress-strain curves showed that the addition of Cu to NiTi alloy made the flow curves shift upward. This was confirmed by the calculated critical stress, σc, obtained from inflections in θ-σ plots, which is attributed to the formation of high strength Cu containing precipitates and solid solution hardening caused by... 

In this study, Porous NiTi shape memory alloy has been produced by mechanical alloying of the elemental Ni and Ti powders. The compacting process was done at two temperatures (warm and cold press) and then sintering at 980 and 1050°C was performed on the specimens. Microstructure and mechanical prop-erties of the samples were investigated by optical microscopy, scanning electron microscopy (SEM) and X-ray diffraction. Moreover, shear punch test (SPT) employed to investigate the effect of compaction pressure and sintering temperature on the mechanical properties of the fabricated samples. It was revealed that warm compaction/sintering resulted in 15% yield stress improvement and 20% ultimate... 

In this study, a set of constitutive equation corrected for deformation heating is proposed for a near equiatomic NiTi shape memory alloy using isothermal hot compression tests in temperature range of 700 to 1000 °C and strain rate of 0.001 to 1 s -1. In order to determine the temperature rise due to deformation heating, Abaqus simulation was employed and varied thermal properties were considered in the simulation. The results of hot compression tests showed that at low pre-set temperatures and high strain rates the flow curves exhibit a softening, while after correction of deformation heating the softening is vanished. Using the corrected flow curves, the power-law constitutive equation of... 

Hot tensile properties of as cast NiTi and NiTiCu shape memory alloys were investigated by hot tensile test at temperature range of 700-1100°C using the strain rate of 0.1s-1. The NiTi alloy exhibited a maximum hot ductility at temperature range of 750-1000°C, while the NiTiCu alloy showed it at temperature range of 800-1000°C. It was found that at temperatures less than 750°C, diffusion-assisted deformation mechanism was inactive leading to semi-brittle type of failure and limited ductility in both alloys. Also it was found that at temperature range of 800-1000°C, dynamic recrystallization is dominant leading to high ductility. Likewise, the fracture surface of the specimens presenting the... 

Nickel-titanium (NiTi) shape memory alloys have been widely used as implant materials, due to their superior shape memory properties and similar mechanical behavior to bone tissue. The presence of nickel on the surface of nickel-titanium alloy and release of this ion in the body environment will result in some allergic reactions. In current study, we used shot pinning process to produce nanocrystalline nickel-titanium alloy with increased corrosion resistance. Field emission scanning electron microscopy (FE-SEM), x-ray diffraction (XRD) analysis, and atomic force microscopy were employed to investigate the surface features of samples. The quantitative chemical analysis of NiTi and modified... 

The deformation behavior of a 49.8 Ni-50.2 Ti (at pct) alloy was investigated using the hot compression test in the temperature range of 700 °C-1100 °C, and strain rate of 0.001 s-1 to 1 s-1. The hot tensile test of the alloy was also considered to assist explaining the related deformation mechanism within the same temperature range and the strain rate of 0.1 s-1. The processing map of the alloy was developed to evaluate the efficiency of hot deformation and to identify the instability regions of the flow. The peak efficiency of 24-28% was achieved at temperature range of 900 °C-1000 °C, and strain rates higher than 0.01 s -1 in the processing map. The hot ductility and the deformation...