Sharif Digital Repository

Due to unique properties of NiTi shape memory alloys such as high corrosion resistance, biocompatibility, super elasticity and shape memory behavior, NiTi shape memory alloys are suitable materials for medical applications. Although TiO2 passive layer in these alloys can prevent releasing of nickel to the environment, high nickel content and stability of passive layer in these alloys are very debatable subjects. In this study a NiTi shape memory alloy with nominal composition of 50.7 atom% Ni was investigated by corrosion tests. Electrochemical tests were performed in two physiological environments of Ringer solution and NaCl 0.9% solution. Results indicate that the breakdown potential of... 

Effects of post weld heat treatment (PWHT) on mechanical properties and corrosion behavior of NiTi shape memory wire, laser welded to the 304 stainless steel wire were investigated. The results showed that PWHT at 200 °C increased corrosion resistance and tensile strength of the joint up to ~1.8 times that of the as-weld joint, with no heat treatment. On the contrary, precipitation of neoteric intermetallic compounds like Fe2Ti, Cr2Ti, FeNi, Ni3Ti, and Ti2Ni in the welded region deteriorated these properties, when PWHT was conducted at 400 °C. Due to the vital effects of the PWHT performed after the laser welding, careful control of the PWHT temperature was found to be a prerequisite for... 

In the present research work the binary NiTi alloys with various compositions in the range of 50.3-51 at.% Ni were used. Samples have been annealed at 850 °C for 15 min and then quenched in water. In order to characterize transformation temperatures and enthalpy changes of the forward and the reverse martensitic transformation, Differential Scanning Calorimetric (DSC) experiments were performed. The enthalpy and entropy changes as a function of Ni atomic content have been thermodynamically investigated. Results show that enthalpy and entropy changes of martensitic transformation decrease when Ni atomic content increases. The variation of enthalpy and entropy of martensitic transformation... 

Attempts have been made to quantify the amount of contaminants absorbed by liquid metal from commercial ZrO2-, Al2O3-, and SiC-base crucibles used for vacuum melting of Ni-45 wt pet Ti alloy. The molten alloy was held under vacuum for 90 minutes at 1450°C to become homogenized. Reactions between the liquid metal and the crucible were investigated by visual observation, chemical analysis, scanning electron microscopy (SEM) image processing, and X-ray mapping. The relative degree of contamination declined in the following sequence: commercially pure SiC > SiC-5 wt pct Al2O3-5 wt pet SiO2] > slurry cast alumina > recrystallized alumina > zircon type A > oxygen deficient high-purity zirconia.... 

We produced bifurcated bone-like shape memory implant (BL-SMI) with desirable tooth-root fixation capability by compact-sintering of TiH2–Ni-urea mixture. The primary constituents of the porous product were Ni and Ti. We could adjust the pores' shape, size, and interconnectivity for favorite bone ingrowth by using urea as a space holder. Without urea, we obtained an average porosity of 0.30, and a mean void size of 100 μm. With 70 vol % urea, we got 62% interconnected pores of 400 μm average size. Aging allowed us to tune the austenite-martensite transformation temperatures towards the needed body tissue arouse. Differential scanning calorimetry measured the transformation temperatures.... 

The unique properties of NiTi alloy, such as its shape memory effect, super-elasticity and biocompatibility, make it ideal material for various applications such as aerospace, micro-electronics and medical device. In order to meet the requirement of increasing applications, great attention has been given to joining of this material to itself and to other materials during past few years. Laser welding has been known as a suitable joining technique for NiTi shape memory alloy. Hence, in this work, a comparative study on laser welding of NiTi wire to itself and to AISI 304 austenitic stainless steel wire has been made. Microstructures, mechanical properties and fracture morphologies of the... 

In this study, the effects of stress-assisted heat treatment on the microstructure and phase transformation of a Ti-rich (Ti-49.52 at.% Ni) shape memory alloy were investigated. For this purpose, the alloy was heat treated at temperature of 500 °C for 10 h under applied stresses of 100 and 200 MPa. XRD, TEM, and repeated thermal cycling were employed to study the microstructure and transformation behavior of the heat-treated materials. Room temperature XRD diffractogram of the stress-free heat-treated material showed a weak reflection of austenite (B2), while that for the stress-assisted heat-treated materials had a high intensity implying the presence of residual austenite in the... 

In this study, a near equiatomic NiTi shape memory alloy was hot rolled at 800°C using thethickness reductions of 30 and 50%. Optical and transmission electron microscopy, together withX-ray diffraction were used to demonstrate the microstructural changes associated with the hotrolling at different thickness reductions. Repeated transformation cycling was employed toinvestigate the evolution of R phase during cycling. Microstructural observations revealed thepresence of deformation twins embedded in an elongated grain matrix in the hot rolled material.Moreover, it was found that with increasing degree of thickness reduction, the size and number ofdeformation twins increased throughout the... 

In this study, a set of constitutive equation corrected for deformation heating is proposed for a near equiatomic NiTi shape memory alloy using isothermal hot compression tests in temperature range of 700 to 1000 °C and strain rate of 0.001 to 1 s -1. In order to determine the temperature rise due to deformation heating, Abaqus simulation was employed and varied thermal properties were considered in the simulation. The results of hot compression tests showed that at low pre-set temperatures and high strain rates the flow curves exhibit a softening, while after correction of deformation heating the softening is vanished. Using the corrected flow curves, the power-law constitutive equation of... 

The present paper reports the effects of Nd:YAG laser welding on the microstructure, phase transformation, cyclic deformation behavior, and corrosion resistance of Ti-55 wt.% Ni wire. The results showed that the laser welding altered the microstructure of the weld metal which mainly composed of columnar dendrites grown epitaxially from the fusion line. DSC results indicated that the onset of the transformation temperatures of the weld metal differed from that of the base metal. Cyclic stress-strain behavior of laser-welded NiTi wire was comparable to the as-received material; while a little reduction in the pseudo-elastic property was noted. The weld metal exhibited higher corrosion... 

During recent years, many investigations have been carried out to determine how to select different materials for the making of Micro Electro Mechanical Systems (MEMS) and bio-MEMS. The NiTi shape memory alloy thin film has been much regarded as a promising candidate for MEMS due. to its unique shape memory effect and high energy output. In this research, NiTi thin film was fabricated using a sputtering technique from separate elemental Ni and Ti targets. The characterizations of the deposited films were, investigated using different analysis techniques, such as Field Emission SEM, DSC, XR.D, electrical resistivity measurement and nanoindentation. © Sharif University of Technology, June 2009... 

A new inelastic mechanism, detwinning-induced plasticity (DIP), is proposed to model the response of NiTi SMAs to cyclic loading, based on thermodynamic considerations. DIP is incorporated into a constitutive framework for NiTi SMA. The constitutive framework also includes well-established inelastic mechanisms of phase transformation, transformation-induced plasticity, residual martensite, and detwinning. The model is constructed at the single crystal scale using the framework of thermodynamics and a crystal plasticity formulation. An explicit scale-transition rule is adopted for the simulation of polycrystalline materials, allowing direct comparison of the model predictions with published... 

Understanding the effect of crystallographic orientation on the twinnin/detwinning mechanisms in NiTi shape memory alloys at an atomistic scale can help to control and tune the mechanical properties and failure behavior of such materials. In this work, we employed classical molecular dynamics (MD) and density functional theory (DFT) computational methods to better understand how twinning and detwinning occurs through a combination of slip, twin, and shuffle on 〈0 1 0〉, 〈1 1 0〉, and 〈1 1 1〉 crystallographic orientations under uniaxial tensile test. Elastic constants including Young's Modulus (E), Bulk modulus (B), Poisson's ratio (ν), and Shear Modulus (G) are obtained and computed for... 

The hot workability of a wrought 49.8 Ni-50.2 Ti (at pct) alloy was assessed using the hot compression tests in temperature range of 700-1000°C, strain rate of 0.001-1s-1, and the total strain of 0.7. The constitutive equations of Arrhenius-type hyperbolic-sine function was used to describe the flow stress as a function of strain rate and temperature. The preferable regions for hot workability of the alloy were achieved at Z (Zener-Holloman parameter) values of about 109-1013 corresponding to the peak efficiency of 20-30% in the processing map. However, a narrow area in the processing map including the deformation temperature of 1000°C and strain rate of 1s-1 is inconsistent with the related... 

The influence of Cu addition on the hot deformation behavior of NiTi shape memory alloys was investigated using hot compression test. A series of alloys with different Cu contents of Ti50.4Ni49.6-xCux (x = 0, 3, 5, 7 at.%) were deformed under compression to a true strain of 0.7 at the temperature range of 700-1000 °C with 100 °C intervals and constant strain rate of 0.1 s-1. The stress-strain curves showed that the addition of Cu to NiTi alloy made the flow curves shift upward. This was confirmed by the calculated critical stress, σc, obtained from inflections in θ-σ plots, which is attributed to the formation of high strength Cu containing precipitates and solid solution hardening caused by...