Sharif Digital Repository

One of the most relevant negative characteristics of high-capacity cathodes for lithium batteries is indeed non-flat voltage-time (V-t) or voltage-capacity (V-C) behaviour during charge-discharge. A clear rationale for this behaviour has not yet been addressed in the literature. Here, by means of density functional theory (DFT) calculations corroborated by basic experimental electrochemical characterization, we investigated both the thermodynamic and the kinetic aspects relevant to voltage variations during charge-discharge of Li2FeSiO4 intended as a model case. A simple physical model allowed us to take into account all the experimental evidence. We suggested that voltage deviations from... 

In this paper, we have derived two equations of state, one for the metallic and ionic solids and the other for the remaining solids on the basis of the concept of the average effective pair potential (AEPP). According to the former EOS, (Z-1)υ2 is linear with respect to 1/ρ, where Z is the compressibility factor and υ = 1/ρ is the molar volume for each isotherm. On the basis of the latter EOS, (Z-1)υ2 is a linear function in terms of ρ2 for each isotherm. As these EOSs suggest, the temperature dependencies of the internal energy is separable from its density dependencies. Hence, the heat capacity of a solid is independent of its density, interaction potential parameters and non-ideal thermal... 

A new architecture for analog sampled-data filters is presented. This architecture is based on implementing the difference equation of the filter using a neural network. It results in lower sensitivity of filter coefficients to hardware nonidealities. Different tradeoffs in the hardware implementation of the filter are discussed. A design example is also presented. © 2005 IEEE  

We propose an observer for attitude and position estimation of a rigid body using translational and angular velocity measurements together with a single landmark. Under an observability condition depending on landmark position, global and asymptotic convergence of attitude and position estimation errors to zero is achieved. We extend the observer for the case of nonideal velocity measurements. Simulation examples demonstrate convergence properties of the observer in the face of noise and bias in velocity measurements  

We study a two-player zero-sum game in which one of the players is restricted to mixed strategies with limited randomness. More precisely, we consider the maximum payoff that the maximizer (Alice) can secure with limited randomness h. This problem finds an operational interpretation in the context of repeated games with non-ideal sources of randomness. The computational aspects of this problem has not received much attention in the game theory literature. We begin by observing the equivalence of this problem with entropy minimization problems in other scientific contexts. Next, we provide two explicit lower bounds on the entropy-payoff tradeoff curve. To do this, we provide and utilize new... 

The transformer leakage inductance (TLI) is an important parameter in the design phase of the isolated power supplies. Hence, the TLI estimation before the transformer construction is very useful for the designers. The previous works considered an ordered winding turn arrangement (WTA) for the transformers. This assumption considers only ideal windings which may result in a significant error from what will be achieved after the construction of the transformer. This article concentrates on the transformers with nonideal windings in which the turns are not ordered. The uneven distribution of the turns in the layers is mainly due to the wrapping machine error. Hence, for a specific transformer... 

Considering the non-ideal behavior of fluids and their effects on hydrodynamic and mass transfer in multiphase. flow is very essential. Simulations were performed that take into account the effects of mass transfer and mixture non-ideality on the hydrodynamics reported by Bozorgmehry et al In this paper, by assuming the density of phases to be. constant and using Raoult's law instead of EOS and the fugacity coefficient definition, respectively, for both liquid and gas phases, the importance of nonideality effects on mass transfer and hydrodynamic behavior was studied. The results for a system of octane/propane (T = 323 K and P = 445 kPa) also indicated that the assumption of constant density... 

The trade-off between the aliasing in integral imaging (II) and the level of interference among adjacent elemental images is mathematically studied in this paper. It is then shown that the multiple-access techniques successfully used in communication systems, e.g. frequency-division multiple access (FDMA), canbeinvoked to ease the trade-off. Implementation of spatial FDMA technique in three-dimensional II is discussed together with its nonidealities and limitations. Elemental images of three toy cars and their corresponding three-dimensional image are finally provided to demonstrate the superiority of the here-proposed spatial FDMA technique  

A new method for modelling and analysis of non-linearity errors caused by the capacitor mismatches and op-amp non-idealities in two-step analogue-to-digital converters (ADCs) is presented. Analytical formulas for estimation of the ADC integral non-linearity (INL) are derived. Using the proposed method, the ADC INL can be calculated in terms of the capacitor mismatches standard deviations. Therefore time-consuming Monte Carlo simulations which are conventionally used to evaluate the effect of random capacitor mismatches on the ADC linearity can be avoided. The effect of op-amp non-idealities, which are frequently examined by the circuit-level simulations, can also be evaluated using the... 

In this paper, we investigate the influence of nonideal boundary conditions on the nonlinear vibration of damped Euler-Bernoulli beams subjected to harmonic loads. These nonidealities allow for small deflections and/or moments at the supports of the beam. Using the iteration perturbation method, analytical expressions for the case of simply supported beams with immovable end conditions are provided. The results reveal that the first order of approximation obtained by the proposed method is more accurate than the perturbation solutions. Moreover, compared with the previous studies, some interesting phenomenon is predicted. We have shown that in some special combinations of the nonidealities... 

The effect of clock skew and duty-cycle on the performance of high-Q N-phase band-pass filters (BPFs) have been examined in this paper. Following a mathematical approach and using the analytical derivations carried out, the effects of such non-idealities as clock skew and duty-cycle error are determined in an N-path filter. It is analytically proved that image signals from all integer multiples of the clock signal, rather than just those at (1 ± kN) multiples of the clock signal, land atop the wanted RF spectrum. In a real world clock generator, with non-idealities in effect, filtering property and proper behavior of the filter is adversely affected. Finally, system level simulation along... 

A novel sturdy multi-stage noise-shaping sigma-delta modulator that cancels the first-stage quantisation error at the output of the modulator is presented. Since any stage of the modulator has unity signal transfer function, the modulator would be very robust to circuit non-idealities such as finite op-amp gain. Furthermore, the signal processing timing issue in the critical paths of the proposed topology has been relaxed due to shifting the delay of the last integrator to the feedback path of the modulator. Moreover, this topology can be implemented in the circuit level by a fewer active blocks. Therefore, it practically would be suitable for low-voltage and low-oversampling applications.... 

Considering non-ideal behavior of fluids and its effects on hydrodynamic and mass transfer in multiphase flow is very essential. Simulations were performed that takes into account the effects of mass transfer and mixture non-ideality on hydrodynamics reported by Irani et al. In this paper, by assuming the density of phases to be constant and Raullt's law instead of using EOS and fugacity coefficient definition, respectively for both the liquid and gas phases, the importance of non-ideality effects on mass transfer and hydrodynamic behavior was studied. The results for a system of octane/propane (T=323 K, P =445 kpa) also indicated that the assumption of constant density in simulation had... 

Water shielding phenomenon generally occurs after waterflooding in water-wet rocks, and impedes direct contact between the oil and the injected gas in tertiary gas injection processes. In this work, a set of visualization experiments were performed on micromodel patterns including designed dead-end pores with a film of water on the surface of pore bodies, which is a more realistic representation of porous media. The experiments were conducted at different miscibility conditions, and the required time for water to be displaced from the throat by the swelling of oil was measured for first contact miscible (n-C5/CO2) and immiscible (n-C10/CO2) systems. In the next step, a model was proposed to... 

This paper deals with simulation of transport phenomena in micro and nano pores. The number of cavities and the cavity radius were estimated by using Henry's law for adsorption of Argon onto ZSM-5 and NaX zeolites. This work showed both of zeolites have pores with average size less than 1 nm. Then with using micro- nano channel assumption instead of micro-nano pores, gas flow and heat transfer were investigated. Subsonic nonideal gas flow and heat transfer for different Knudsen number are investigated numerically using the Direct Simulation Monte Carlo method modified with a consistent Boltzamnn algorithm. The collision rate is also modified based on the Enskog theory for dense gas. It is...