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    Phase behavior and rheology of emulsions in an alkaline/cosolvent/crude oil/brine system

    , Article Petroleum Science and Technology ; Volume 34, Issue 3 , 2016 , Pages 207-215 ; 10916466 (ISSN) Bahman Abadi, H ; Hemmati, M ; Shariat Panahi, H ; Masihi, M ; Karam Beigi, M. S ; Sharif University of Technology
    Taylor and Francis Inc 
    Abstract
    Phase behavior of active crude oil/alkaline was systematically studied in the presence of cosolvents. For this purpose, several factors have been considered: alkaline concentration, oil concentration, and type of brine. The best composition was used to generate emulsion for rheology and displacement tests. Furthermore, precipitation of alkaline was eliminated by its synergy with EDTA. Next, rheology of emulsion was analyzed by which a Power law model was developed that indicates non-Newtonian behavior of emulsion. Moreover, the viscosity of emulsion was reduced by the addition of cosolvent as well as by the increase of alkaline concentration. Finally, the best formulation (containing... 

    Experimental investigation of constant and concentration-dependent diffusivity of a hydrocarbon solvents-heavy oil system: A comparative study

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Volume 34, Issue 3 , 2011 , Pages 235-245 ; 15567036 (ISSN) Nasirahmadi, E ; Kharrat, R ; Ghazanfari, M. H ; Rashtchian, D ; Sharif University of Technology
    Abstract
    This work is concerned with the experimental investigation of mass transfer, which occurs during diffusion of hydrocarbon solvents in heavy oil based on constant and concentration-dependent diffusion coefficient. Here, a series of free fall diffusion experiments have been conducted in sealed test tubes at fixed temperatures. Pentane, hexane, and octane were used as solvents and were placed on heavy oil in tubes. The diffusivity of heavy oil into solvents was monitored by a digital camera. The image analysis technique was applied to extract concentration profiles in diffusion zones of solvents by means of calibration curves. Fick's second law was used to obtain both constant and... 

    Effective factors in the treatment of kerosene-water emulsion by using UF membranes

    , Article Journal of Hazardous Materials ; Volume 161, Issue 2-3 , 2009 , Pages 1216-1224 ; 03043894 (ISSN) Rezvanpour, A ; Roostaazad, R ; Hesampour, M ; Nyström, M ; Ghotbi, C ; Sharif University of Technology
    2009
    Abstract
    The effects of different parameters including membrane type (regenerated cellulose and polysulphone), transmembrane pressure (TMP), the content of oil in the feed, the flow velocity of the feed and pH on the ultrafiltration of an emulsion of kerosene in water were studied. It was found that the important factors affecting ultrafiltration were, in order, membrane type, pressure and oil concentration. The greatest flux at the optimum conditions here of 3 bar, an oil content of 3% (v/v) and with membrane type C30F was predicted as 108 L/(m2 h) that was within the range of the confidence limit of the measured value of 106 L/(m2 h). The normalised FTIR results of the virgin cellulosic membranes...