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    Structure of human errors in tasks of operators working in the control room of an oil refinery unit

    , Article Indian Journal of Science and Technology ; Volume 5, Issue 2 , Feb , 2012 , Pages 2065-2070 ; 09746846 (ISSN) Gholi Nejad, N. S ; Jafari, M. J ; Ghalehnoi, M ; Mehrabi, Y ; Ghadiri, M ; Nikbakht, M ; Sharif University of Technology
    2012
    Abstract
    In the present research, human errors existed in tasks of operators working in two control rooms (Northern and Southern control rooms) in the Tehran oil refinery are identified and evaluated. Then, corrective strategies and actions are advised to decrease errors. At first, using hierarchical task analysis (HTA) method, four positions including shift controller, head operators, control room's operators, and outside operators are analyzed. Afterwards, human errors in the considered positions are identified and assessed using technique for retrospective and predictive analysis of cognitive errors (TRACEr). Results present 670 internal errors and 738 external errors in the Northern sector while... 

    Comparison of furfural degradation by different photooxidation methods

    , Article Chemical Engineering Journal ; Volume 139, Issue 3 , 2008 , Pages 482-488 ; 13858947 (ISSN) Borghei, S. M ; Hosseini, S. N ; Sharif University of Technology
    2008
    Abstract
    In this paper, the degradation of C5H4O2 "Furfural" in aqueous solution by photooxidation technology using UV, UV/H2O2, UV/H2O2/O2, UV/H2O2/Fe2+, UV/O2/Fe2+, O3, UV/O3 process and also oxidation by sodium hypochlorite was investigated in a lab-scale batch photo-reactor. To evaluate the performance of different processes, the efficiency of furfural degradation was studied by measuring the total organic carbon (TOC) throughout the experimentation. Results show that compare to other reactions studied in this research, the UV/H2O2 is a simple and effective process for furfural degradation and presence of Fe2+ ions (UV/H2O2/Fe2+) enhanced removal of furfural in solution. The influence of... 

    Optimization of Water Consumption and Wastewater Treatment in Refinery

    , M.Sc. Thesis Sharif University of Technology Khajian, Nafiseh (Author) ; Shayegan, Jalaloddin (Supervisor)
    Abstract
    Water is used as a key material in different processes of chemical industries. Considering abundant demand of chemical industries for water, pollution that threats this valuable material and the fact that there is currently no proper substitute for water, an urgent necessity is felt for economic utilization of water in industrial processes and optimal use of water resources. A variety of methods have been developed for analysis of water consumption in industrial processes, amongst are Pinch methodology and Mathematical Programming approach. In this thesis a Petroleum Refinery has been preferred as a case study in which optimization of water consumption in the aforementioned petroleum... 

    Heavy oil thermal conversion and refinement to the green petroleum: A petrochemical refinement plant using the sustainable formic acid for the process

    , Article Biointerface Research in Applied Chemistry ; Volume 10, Issue 5 , 2020 , Pages 6088-6100 Norouzi, N ; Talebi, S ; Fabi, M ; Khajehpour, H ; Sharif University of Technology
    AMG Transcend Association  2020
    Abstract
    In this study, heat oil conversion experiments using steam and formic acid as a hydrogen carrier be carried out in a batch reactor at T = 380 degrees of Celsius and P = 165 bar. Material balance and product distribution were calculated after the process. Properties of crude oil before and after thermal conversion, including viscosity, API gravity, SARA measurement, and elemental analysis, were analyzed. It has been presented that the use of formic acid as a hydrogen carrier solvent reduces the formation of coke and gaseous products and enhances the performance of liquid products. Also, the viscosity of the refined oil decreased by 23.2% due to the addition of formic acid compared to the... 

    Development of a Water and Energy Management Tool to Retrofit the Crude Oil Distillation Unit of a Refinery

    , M.Sc. Thesis Sharif University of Technology Charkhestani, Saeed (Author) ; Avami, Akram (Supervisor)
    Abstract
    The aim of this research is retrofit of a crude oil distillation refinery unit in terms of water and energy. To do this, the refinery distillation unit is ategorized to different zones from the perspective of water and energy to determine the saving potentials. The energy network consists of the four sub-types includes exchangers and the water network consist of seven sub-sets including water and steam. In the next stage, the retrofit of the energy network and the process heat exchangers are done by using pinch analysis in the commercial software and discussed the economical possibility of pinch analysis for 20 heat exchangers in the crude oil preheating unit. Using the flow of flashed crude... 

    The Optimal Model of Energy and Exergy Flow for Evaluating Technology Changes in Oil Refinery (Case Study: North Tehran Oil Refinery)

    , M.Sc. Thesis Sharif University of Technology Hosseinnezhad, Ahmad (Author) ; Saboohi, Yadollah (Supervisor)
    Abstract
    In this project, a comprehensive model is developed for energy and exergy analysis in refineries. By studying Tehran’s North Refinery unit as a case study, the Reference Energy System as the conceptual model of the thesis and also Energy & Exergy Balance table is prepared. Through the exergy balance table, the Exergy efficiency defined. These factors help to settle priority for efficiency improvement investment. Then, the economic and technical relations and costraints are formulized using linear programming model. In this model, the CO2 emission and exergy destruction costs are intended. Using Energy System Model (ESM) software, the thesis model is advanced as RESM stands for Refinery... 

    Optimization of Refinery Crude Distillation unit Production

    , M.Sc. Thesis Sharif University of Technology Osanloo, Mohammad (Author) ; Farhadi, Fatola (Supervisor) ; Bozorgmehry, Ramin (Supervisor)
    Abstract
    The design and optimization of processes was focused in the past on economic issues such as profitability and return on investment, and less attention has been paid to environmental issues. In recent years, by introducing environmental criterion as pillars of sustainable development, environmental optimization of processes has becoming an inseparable element of the process engineering. Therefore, it is necessary to examine the compatibility of environmental indicators with economic objective. The purpose of this study is to investigate environmental indicators and economic objective function in optimizing the Crude Distillation Unit (CDU) of an oil refinery. The CDU is one of the most... 

    A Methodology for the Design of an Integration System for Water Capturing, Carbon Capture, and Heat Recovery from Flue Gas in Power Plants

    , M.Sc. Thesis Sharif University of Technology Hosseini, Mehdi (Author) ; Avami, Akram (Supervisor)
    Abstract
    This work presents a mathematical model for retrofitting the steam power plants in a refinery site. This problem is formulated as a mixed-integer nonlinear program (MINLP). Feasible retrofit alternatives suggested by experienced field engineers are investigated in sequence to examine the saving of those possible modifications. Furthermore, techno economic simulation of water and energy recovery systems from boiler flue gasses has been examined to obtain the optimal condition of these systems. For heat recovery, a systematic model for using organic Rankine cycle has been developed and results showed that toluene is the best possible working fluid in this case. Finally, water absorption cycle... 

    Continues Risk Assessment by Exploiting Artificial Intelligence

    , M.Sc. Thesis Sharif University of Technology Molla Mohammadi Sadafi, Amir (Author) ; Rajabi, Abbas (Supervisor) ; Rashtchian, Davoud (Supervisor)
    Abstract
    The Fourth Industrial Revolution brought about a fundamental change in the system of management and production, especially in the field of industry, which was accompanied by the development of technology in the fields of artificial intelligence, robotics, nanotechnology and biotechnology. In line with these changes, the industry needs a new method to evaluate the reliability of operational equipment using artificial intelligence and intelligent systems, which aims to optimize the balance between a variety of repair methods with the possibility of timely replacement of parts. In this new method, the life of the parts is increased and the unplanned maintenance costs and labor are reduced. One... 

    Fungal leaching of hazardous heavy metals from a spent hydrotreating catalyst

    , Article World Academy of Science, Engineering and Technology ; Volume 76 , 2011 , Pages 726-731 ; 2010376X (ISSN) Gholami, R. M ; Borghei, S. M ; Mousavi, S. M ; Sharif University of Technology
    Abstract
    In this study, the ability of Aspergillus niger and Penicillium simplicissimum to extract heavy metals from a spent refinery catalyst was investigated. For the first step, a spent processing catalyst from one of the oil refineries in Iran was physically and chemically characterized. Aspergillus niger and Penicillium simplicissimum were used to mobilize Al/Co/Mo/Ni from hazardous spent catalysts. The fungi were adapted to the mixture of metals at 100-800 mg L -1 with increments in concentration of 100 mg L -1. Bioleaching experiments were carried out in batch cultures. To investigate the production of organic acids in sucrose medium, analyses of the culture medium by HPLC were performed at... 

    Bacterial leaching of a spent Mo-Co-Ni refinery catalyst using Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans

    , Article Hydrometallurgy ; Volume 106, Issue 1-2 , February , 2011 , Pages 26-31 ; 0304386X (ISSN) Gholami, R. M ; Borghei, S. M ; Mousavi, S. M ; Sharif University of Technology
    2011
    Abstract
    A spent processing catalyst from an Iranian oil refinery was initially characterized physically and chemically. Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans were used to mobilize Al, Co, Mo and Ni from the spent catalysts under optimized conditions in batch cultures. The characteristics of the bioleach solution (pH, Eh, cell concentration and Fe(II)/Fe(III) concentration) were determined along with the concentration of metal values extracted from the catalyst. The results showed that after bioleaching using A. ferrooxidans in the presence of ferrous sulfate, maximum extractions of 63% Al, 96% Co, 84% Mo and 99% Ni were achieved after 30 days at pH 1.8-2.0. However, the... 

    Heavy metals recovery from spent catalyst using acidithiobacillus ferrooxidans and acidithiobacillus thiooxidans

    , Article ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings, 1 August 2010 through 3 August 2010, Kyoto ; 2010 , Pages 331-335 ; 9781424477647 (ISBN) Mafi Gholami, R ; Borghei, S. M ; Mousavi, S. M ; Sharif University of Technology
    2010
    Abstract
    In this investigation, a spent processing catalyst from one of the oil refineries in Iran was initially characterized physically and chemically. Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans were used to mobilize aluminum, cobalt, molybdenum and nickel from hazardous spent catalysts. Bioleaching experiments were performed in batch cultures. The growth characteristics of the bacteria (pH, Eh, cell concentration and ferrous and ferric iron concentration) were determined during bioleaching along with the concentration of metal values extracted from the catalyst. The results obtained from Inductive coupled plasma-optical emission spectrometry (ICP-OES) showed that after the... 

    Process optimization and modeling of heavy metals extraction from a molybdenum rich spent catalyst by aspergillus niger using response surface methodology

    , Article Journal of Industrial and Engineering Chemistry ; Volume 18, Issue 1 , January , 2012 , Pages 218-224 ; 1226086X (ISSN) Mafi Gholami, R ; Mousavi, S. M ; Borghei, S. M ; Sharif University of Technology
    2012
    Abstract
    The present study examines the biorecovery of heavy metals from a spent refinery catalyst obtained from one of the oil refineries in Iran using Aspergillus niger. Bioleaching experiments were carried out in batch cultures using A. niger in the one-step process to mobilize Co, Mo and Ni from hazardous spent catalysts. Response surface methodology (RSM) was applied for the design and analysis of experiments with the optimization of pH, temperature, inoculum percentage, pulp density and rotation speed during the bioleaching of the metals. Experiments were designed as per the central composite design (CCD) technique. Three cubic mathematical models were derived for prediction of the responses.... 

    Crude oil desalter effluent treatment by a hybrid UF/RO membrane separation process

    , Article Desalination ; Volume 238, Issue 1-3 , 2009 , Pages 174-182 ; 00119164 (ISSN) Norouzbahari, S ; Roostaazad, R ; Hesampour, M ; Sharif University of Technology
    2009
    Abstract
    Crude oil desalter effluent from a Tehran oil refinery was treated by a hybrid UF/RO membrane separation process. Ultrafiltration (UF) was used primarily to remove the emulsified oil droplets followed by the removal of total dissolved solids (TDS) via reverse osmosis (RO). The UF membrane was a hydrophilic flat sheet polysulfone ultrafiltration membrane with MWCO of 100 kDa while the RO membrane was a spiral-wound thin-film composite polyamide. Effect of operating conditions such as transmembrane pressure and crossflow velocity were studied in UF pretreatment. The experimental results showed that the UF membrane removed more than 75% of the oil and can be considered as an effective... 

    Experimental and analytical studies on the prediction of forming limit diagrams

    , Article Computational Materials Science ; Volume 44, Issue 4 , 2009 , Pages 1252-1257 ; 09270256 (ISSN) Ahmadi, S ; Eivani, A. R ; Akbarzadeh, A ; Sharif University of Technology
    2009
    Abstract
    Metal forming processes are widely used in industrial productions, automobile bodies, food industries, oil refineries, and liquid and gas transmission systems. Analyzing these processes is very important to reduce wastes and optimize the processes. Study of some main factors such as physical and mechanical properties of material and its formability, die geometry, die material, lubrication and pressing speed has been the topic of many research projects. In this paper, forming limit diagrams (FLDs) for LC and ULC steels and the effect of different parameters like the work-hardening exponent, n, and the plastic strain ratio, r, on these diagrams have been evaluated and simulated using... 

    Efficient biodegradation of naphthalene by a newly characterized indigenous achromobacter sp. FBHYA2 isolated from Tehran oil refinery complex

    , Article Water Science and Technology ; Volume 66, Issue 3 , March , 2012 , Pages 594-602 ; 02731223 (ISSN) Farjadfard, S ; Borghei, S. M ; Hassani, A. H ; Yakhchali, B ; Ardjmand, M ; Zeinali, M ; Sharif University of Technology
    IWA Pub  2012
    Abstract
    A bacterial strain, FBHYA2, capable of degrading naphthalene, was isolated from the American Petroleum Institute (API) separator of the Tehran Oil Refinery Complex (TORC). Strain FBHYA2 was identified as Achromobacter sp. based on physiological and biochemical characteristics and also phylogenetic similarity of 16S rRNA gene sequence. The optimal growth conditions for strain FBHYA2 were pH 6.0, 30°C and 1.0% NaCl. Strain FBHYA2 can utilize naphthalene as the sole source of carbon and energy and was able to degrade naphthalene aerobically very fast, 48 h for 96% removal at 500 mg/L concentration. The physiological response of Achromobacter sp., FBHYA2 to several hydrophobic chemicals... 

    Two schemes for production of biosurfactant from Pseudomonas aeruginosa MR01: Applying residues from soybean oil industry and silica sol–gel immobilized cells

    , Article Colloids and Surfaces B: Biointerfaces ; Volume 152 , 2017 , Pages 159-168 ; 09277765 (ISSN) Bagheri Lotfabad, T ; Ebadipour, N ; Roostaazad, R ; Partovi, M ; Bahmaei, M ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Rhamnolipids are the most common biosurfactants and P. aeruginosa strains are the most frequently studied microorganisms for the production of rhamnolipids. Eco-friendly advantages and promising applications of rhamnolipids in various industries are the major reasons for pursuing the economic production of these biosurfactants. This study shows that cultivation of P. aeruginosa MR01 in medium contained inexpensive soybean oil refinery wastes which exhibited similar levels and homologues of rhamnolipids. Mass spectrometry indicated that the Rha-C10-C10 and Rha-Rha-C10-C10 constitute the main rhamnolipids in different cultures of MR01 including one of oil carbon source analogues. Moreover,...