Sharif Digital Repository

Electrodes made of group VIII and IB metals were examined for their redox process and electrocatalytic activities towards the oxidation of ethylene glycol in alkaline solutions. The method of cyclic voltammetery (CV) and Open circuit potentials measurement (OCP) was employed. It is found that considerable electrooxidation current are observed for silver and copper but lower anodic overpotential for oxidation is obtained for gold and platinum. Oxide layer produced on the surface of all electrodes in alkaline solution under anodic scan participates in ethylene glycol electrooxidation. Oxidation current observed in the reverse scans for platinum and gold are higher than those observed in... 

Here in this research, a modified interface between the electron transport layer (ETL) and the perovskite layer in a perovskite solar cell (PSC) is provided by adding the ammonium chloride (NH4Cl) to the tin oxide (SnO2) as the modified ETL of a planar structure as follows: fluorine-doped tin oxide (FTO)/NH4Cl-SnO2/Mixed cation perovskite/Copper indium disulfide (CIS)/Gold (Au). The effects of NH4Cl on ETL are investigated in different amounts from 0.003 to 0.02 M and the best results were obtained in the amount of 0.013 M. The best NH4Cl-SnO2 ETL could increase the power conversion efficiency (PCE) of fabricated planar PSC by 16.79% with open-circuit voltage (Voc) of 1.15 V and negligible... 

Here in this research, a modified interface between the electron transport layer (ETL) and the perovskite layer in a perovskite solar cell (PSC) is provided by adding the ammonium chloride (NH4Cl) to the tin oxide (SnO2) as the modified ETL of a planar structure as follows: fluorine-doped tin oxide (FTO)/NH4Cl-SnO2/Mixed cation perovskite/Copper indium disulfide (CIS)/Gold (Au). The effects of NH4Cl on ETL are investigated in different amounts from 0.003 to 0.02 M and the best results were obtained in the amount of 0.013 M. The best NH4Cl-SnO2 ETL could increase the power conversion efficiency (PCE) of fabricated planar PSC by 16.79% with open-circuit voltage (Voc) of 1.15 V and negligible... 

We have investigated the influence of perovskite morphology on slow and fast charge transport in the perovskite solar cells. Solar cells with different perovskite cuboid sizes (50-300 nm) have been fabricated using various methylammonium iodide concentrations. Both the low-frequency capacitance and hysteresis are maximum for the cell with the largest perovskite grains (300 nm). The low-frequency capacitance is about three orders of magnitude greater than the intermediate frequency capacitance, indicating the great role of ions on the slow responses and hysteresis. The measurement of open-circuit voltage decay indicates that for the large grains of 300 nm up to 70% of Voc remains across the... 

PbS on Pb thin film (Pb/PbS) was deposited on conductive glass (CG) substrate (CG/Pb/PbS) using electrochemical techniques to investigate the Schottky junction in solution. The CG/Pb/PbS electrode was investigated by different techniques based on thermionic emission theory. Electrochemical cell consisted of the CG/Pb/PbS as a working electrode in an alkaline solution showed character of the Schottky junction. Reduction and oxidation of H2O on the CG/Pb/PbS electrode were enhanced under illumination. Water photo splitting is the main process. Study of linear sweep voltammetry at around open circuit potential (OCP) allowed proposing a model based on the Schottky junction which is charged at... 

Linear alkylbenzene sulfonate (LAS), one of the most widely used synthetic surfactants in laundry detergent industry, is considered a hazardous contaminant in wastewater. In the present study, a microbial fuel cell (MFC) based biosensor is developed to quantitively determine the LAS concentration in wastewater. To do so, the developed MFC is fed with LAS concentration of 60 mg l−1. Finally, a sustained biofilm is formed after almost 34 days and the highest open circuit potential of 425 mV is recorded. The maximum power and current densities of 75 mW m−3 and 663 mA m−3 are obtained, respectively; and the internal resistance of the MFC-based biosensor is calculated to be about 1 kΩ. After 98... 

Interleaved DC-DC boost converters are interesting choices in applications like fuel cells and photovoltaic systems. Although this converter offers low current ripple, but an open-circuit switch fault can lead to unacceptable current ripples. In this paper, a very fast and simple method is proposed to detect an open-circuit switch fault and its location. This method doesn't need any additional sensors, is efficient in CCM and DCM modes of operation, and can detect the fault in less than one switching period. Moreover, this method is suitable for implementation on an FPGA, due to the use of simple math and state machine blocks. Simulations are carried out to validate the effectiveness of this... 

In this paper, an FPGA-controlled fault tolerant back-to-back converter for DFIG-based wind energy conversion application is studied. Before an open-circuit failure in one of the semiconductors, the fault tolerant converter operates as a conventional back-to-back six-leg one. After the fault occurrence in one of the switches, the converter will continue its operation with the remaining five healthy legs. Design, implementation, simulation and experimental verification of a reconfigurable control strategy for the fault tolerant six/five leg converter used in wind energy conversion are discussed. The proposed reconfigurable control strategy allows the uninterrupted operation of the converter... 

Solar cells with high efficiency, low cost, and high stability are the target for the new generation of solar cells. A fully printable perovskite (CH3NH3PbI3) solar cell (PSC) with device architecture FTO/TiO2/Al2O3/NiOx/C is fabricated in the current research as a low-cost and relatively stable structure and is investigated to determine how different fabrication factors such as the thickness of the insulating spacer layer (Al2O3) or treatments such as heat and UV-O3 treatments can affect the interfacial properties of this multilayer mesoporous structure. X-ray photoelectron spectra (XPS) show that UV-O3 treatment increases the Ni3+(Ni2O3) phase on the surface of the black nickel oxide layer... 

In this paper, a fast and practical method is proposed for open-circuit (OC) fault diagnosis (FD) in a three-phase quasi-Z-source inverter (q-ZSI). Compared to the existing fast OC FD techniques in three-phase voltage-source inverters (VSIs), this method is more cost-effective since no ultra-fast processor or high-speed measurement is required. Additionally, the method is independent of the load condition. The proposed method is only applicable to Z-source family inverters and is based on observing the effect of shoot-through (SH) intervals on the system variables during switching periods. The proposed algorithm includes two consecutive stages: OC detection and fault location identification.... 

Due to several advantages, three-phase Dual Active Bridge (DAB) converter is widely used in numerous applications nowadays. On the other hand, this converter is very vulnerable to Transistor Open-Circuit Fault (TOCF). Therefore, a fault-tolerant (FT) scheme has been proposed in this paper to solve the problem. First, normal and faulty conditions are investigated, and according to the results, a fault-diagnosis (FD) approach is introduced. Using the outcomes of FD unit, a new post-fault strategy is proposed for the converter. The FD method is based on the DC component of transformer phase currents, and the basis of FT technique is shedding the faulty phase. Some benefits of the proposed... 

In this paper, a fast and practical method is proposed for open-circuit (OC) fault diagnosis (FD) in a three-phase quasi-Z-source inverter (q-ZSI). Compared with the existing fast OC FD techniques in three-phase voltage source inverters, this method is more cost-effective since no ultrafast processor or high-speed measurement is required. Additionally, the method is independent of the load condition. The proposed method is only applicable to Z-source family inverters and is based on observing the effect of shoot-through intervals on the system variables during switching periods. The proposed algorithm includes two consecutive stages: OC detection and fault location identification. When both... 

In this article, a new soft switching isolated push-pull dc-dc converter using a three-winding transformer is proposed. The proposed hybrid resonant and pulse width modulated converter employs a conventional push-pull structure in the primary side, a voltage doubler in the secondary side, and a bidirectional switch besides the transformer, altogether help offering a high efficiency over a wide range of input and output voltage signals with an unsophisticated fixed-frequency control mechanism. The primary-side switches are commutated under zero voltage switching with low switching current and the secondary-side diodes are commutated under zero current switching. In this article, we first... 

Core/shell structure of ZnO nanowires coated with a monolayer of TiO 2 is investigated using Density Functional Theory (DFT). The electronic states of the semiconductor is calculated and compared before and after coating of the TiO2 monolayer on a ZnO [101 0] surface. The effect of TiO2 coating induce surface states changes and shifts the conduction and valence band edges to higher energies. Our results, in qualitative agreement with the experimental work of Matt Law et al. (J. Phys. Chem. B, 110, 22652), show an increase in open circuit voltage and a decrease in short circuit current in ZnO/TiO2 core shell dye sensitized solar cells. Regarding the semiconductor density of states (DOS), TiO2... 

This study attempts to find an optimum combination of the welding tool rotation rate (ω) and traveling speed (υ), concerning the corrosion and mechanical properties of Friction Stir Welded (FSWed) AA5052 Aluminum alloy. The effect of the tool speeds on the FSWed AA5052 are investigated via potentiodynamic polarization, open circuit potential (OCP) monitoring, test of the susceptibility to intergranular corrosion, weight loss, tension and micro-hardness tests. Optical microscope and Scanning Electron Microscopy (SEM) were employed for studying the morphology and analyzing the probable intergranular attacks. It was found that by increasing υ up to 200. mm/min at ω=400 rpm, the microstructural... 

Efficient control of gas metal arc welding process enables us to have high quality products in consequence of achieving high quality weld. In this paper, an extended dynamic matrix controller is designed and applied on the gas metal arc welding process, which is considered as a nonlinear multi-inputs multi-outputs system. In order to reach a high quality weld, the outputs, welding current and arc length, are effectively controlled by open circuit voltage and wire feed speed. The structure and performance of the proposed controller are discussed in detail, and then a set of simulation results is presented to verify its efficiencies  

Here, we report on utilizing a photoactive protein, bacteriorhodopsin (bR), as a light harvester in combination with TiO2 nanoparticles in biosensitized solar cell application. Experiments have been conducted to investigate the capability of surface adsorption of bR on nanoparticular TiO2photoanodes. Different pretreatment processes have been done to modify the interface of TiO2 nanoparticles and bR as a biophotosensitizer. Our results indicate the feasibility of efficient immobilization and photoinduced charge transfer of bR to the nanostructured TiO2 photoelectrode. Under illumination of simulated AM1.5 sunlight, the solar-light-to-electricity... 

A comparative study has been made of hybrid solar cells based on poly(3-hexylthiophene) (P3HT) and different nano-structures of TiO2. Electrospinning, which is a low cost production method for large area nanofibrous films, was employed to fabricate TiO2 nanofibers and spin coating method was employed to fabricate organic-inorganic hybrid solar cells based on P3HT and TiO2 nanostructures. The performance of the hybrid solar cells was analyzed for four density levels of the TiO2 nanostructure. It was found that higher densities of TiO2 leads to more interface area and generates excitons, so that the power conversion efficiency increases to... 

Parameter extraction of the five-parameter single-diode model of solar cells and modules from experimental data is a challenging problem. These parameters are evaluated from a set of nonlinear equations that cannot be solved analytically. On the other hand, a numerical solution of such equations needs a suitable initial guess to converge to a solution. This paper presents a new set of approximate analytical solutions for the parameters of a five-parameter single-diode model of photovoltaic (PV) cells and modules. The proposed solutions provide a good initial point which guarantees numerical analysis convergence. The proposed technique needs only a few data from the PV current-voltage... 

Perovskite solar cells (PSCs) use perovskites with an APbX3 structure, where A is a monovalent cation and X is a halide such as Cl, Br, and/or I. Currently, the cations for high-efficiency PSCs are Rb, Cs, methylammonium (MA), and/or formamidinium (FA). Molecules larger than FA, such as ethylammonium (EA), guanidinium (GA), and imidazolium (IA), are usually incompatible with photoactive “black”-phase perovskites. Here, novel molecular descriptors for larger molecular cations are introduced using a “globularity factor”, i.e., the discrepancy of the molecular shape and an ideal sphere. These cationic radii differ significantly from previous reports, showing that especially ethylammonium (EA)...