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Plasma surface functionalization of boron nitride nano-sheets
, Article Diamond and Related Materials ; Volume 77 , 2017 , Pages 110-115 ; 09259635 (ISSN) ; Achour, A ; Solaymani, S ; Islam, M ; Vizireanu, S ; Arman, A ; Ahmadpourian, A ; Dinescu, G ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
On silicon substrates, boron nitride nanosheets (BNNS) consisting of interconnected hexagonal boron nitride nano-layers were produced via chemical vapor deposition process at 1200 °C whose roughness's are at the micrometer- and nanometer-scale. The BNNS were functionalized in argon plasma admixed with ammonia or nitrogen or oxygen. The samples were characterized to investigate the surface chemistry and structural changes after plasma treatment using X-ray photoelectron spectroscope and Micro-Raman spectroscope techniques, respectively. While no significant changes in the surface features, upon plasma treatments of the BNNS, were noticed during SEM and TEM examination, the oxygen functional...
The role of oxygen defects in magnetic properties of gamma-irradiated reduced graphene oxide
, Article Journal of Alloys and Compounds ; Volume 784 , 2019 , Pages 134-148 ; 09258388 (ISSN) ; Nemati, A ; Zarrabi, A ; Shokrgozar, M. A ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
Recently, graphene oxide and its unconventional magnetism have attracted much interest due to their novel applications in spintronics, memory chips and theranostics. Owing to the excellent biocompatibility, cellular uptake, bio-conjugation possibilities, flexible chemical modification and characteristic broad-wavelength absorbance, graphene oxide and its derivatives have been utilized as contrast agents for various imaging modalities such as photoluminescence, photoacoustic or ultrasound. Despite their suitable applications in bioimaging and due to lack of magnetic moment, graphene oxide cannot confer magnetic resonance imaging contrast without incorporating the magnetic component. Such...
H 2 adsorption mechanism in Mg modified multi-walled carbon nanotubes for hydrogen storage
, Article International Journal of Hydrogen Energy ; Volume 37, Issue 2 , January , 2012 , Pages 1919-1926 ; 03603199 (ISSN) ; Mortazavi, S. Z ; Mirershadi, S ; Golikand, A. N ; Moshfegh, A. Z ; Sharif University of Technology
Abstract
Multi-walled carbon nanotubes (MWCNTs) with diameter of about 50 nm were synthesized using thermal chemical vapor deposition. We have investigated the influence of Mg doping to the MWCNTs on its hydrogen storage property. TEM micrographs showed that Mg was attached to the MWCNTs and discontinuous arrangement of the carbon walls was recognized in the MWCNTs. According to XPS and BET analyses, the surface functional groups and pore size of the Mg-MWCNTs are increased by interactions between the Mg and the MWCNT's outer walls. The electrochemical discharging curves of the MWCNTs and Mg-doped MWCNTs revealed that the hydrogen storage capacity was 363 and 450 mAhg -1, respectively. Volumetric...