Sharif Digital Repository

In this paper, thermal and catalytic hydrocracking of liquid paraffin hydrocarbons, from Tehran refinery, is studied using a pilot plant reactor. The experimental system consisted of a vertical tubular flow reactor where hydrogen and liquid products were fed from the top of the reactor and after passing through a bed of catalyst (or quartz beads in the case of thermal hydrocracking experiments), the liquid and gaseous products were separated and sampled for subsequent analyses. The reaction temperature was in the range of 410-430°C for catalytic hydrocracking and 440-470°C for thermal hydrocracking experiments. The space velocities for both sets of experiments varied between 0.5 to 1.5... 

In this paper, we would like to know how to synthesize soot in a paraffin-oil flame. To do this, we use an in-house developed numerical code and simulate the soot formation in a turbulent paraffin-oil flame. However, it is necessary to evaluate first this code to ensure its reliable prediction of the soot formation and thermal behavior of the flame. So, we simulate a benchmark turbulent paraffin-oil flame and compare our obtained results against the available experimental data. The comparison insinuates the capability of current numerical code in correct predictions of both flame structure and pollution species. Then, a glass slide is installed inside the combustor. This disk-shaped glass... 

In this paper, we would like to know how to synthesize soot in a paraffin-oil flame. To do this, we use an in-house developed numerical code and simulate the soot formation in a turbulent paraffin-oil flame. However, it is necessary to evaluate first this code to ensure its reliable prediction of the soot formation and thermal behavior of the flame. So, we simulate a benchmark turbulent paraffin-oil flame and compare our obtained results against the available experimental data. The comparison insinuates the capability of current numerical code in correct predictions of both flame structure and pollution species. Then, a glass slide is installed inside the combustor. This disk-shaped glass... 

The boiling of a fluid dripping on the surface of molten phase-change materials provides an efficient means for heat exchange or cooling of the melt. For the first time, in this study, the impact of acetone drops onto molten paraffin as a direct-contact solidification method is experimentally investigated to get a better insight into the interaction between the drop boiling and the heat extraction process from the phase change materials during impact. As the acetone drop impacts the molten paraffin surface, acetone starts to boil, and a portion of molten paraffin is solidified. Four impact Weber numbers (corresponding to heights of 10, 20, 30, and 40 cm) for the acetone drop and six surface... 

A mathematical model for a fixed bed radial flow catalytic reactor was developed for dehydrogenation of heavy paraffins over Pt-Sn/Al2O3 catalyst. The model included appropriate kinetic rate expressions for the main dehydrogenation reaction as well as side reactions and catalyst deactivation. The reactor model consisted of a set of partial and ordinary as well as algebraic equations that were solved numerically to determine the concentration of various species along the radius of the bed as a function of time. The Nelder-Mead optimization method was used to obtain the optimum kinetic parameters. The validity of the model was demonstrated by comparing the predicted paraffin conversion and... 

Most reservoirs in Iran are heterogeneous fractured carbonate reservoirs. Heterogeneity causes an earlier breakthrough and an unstable front which leads to a lower recovery. A series of experiments were conducted whereby the distilled water displaced n-Decane in strongly oil-wet glass micro-models containing a single fracture. Experimental data from image analysis of immiscible displacement processes are used to modify the Buckley-Leverett and fractional flow equations by a heterogeneity factor. It is shown that the heterogeneity factor in the modified equations can be expressed as a function of fracture length and orientation  

The main purpose of this work is to present a free-volume combinatorial term in predicting vapor-liquid equilibrium (VLE) and solid-liquid equilibrium (SLE) of polymer/solvent and light and heavy hydrocarbon/hydrocarbon mixtures. The proposed term is based on a modification of the original Freed Flory-Huggins model, replacing the molar volume with a free-volume (FV) term. Using an extensive database for athermal polymer solutions at finite dilution, the single parameter of the model has been well adjusted. The results obtained from the model proposed in this work were favorably compared with those obtained from the well-established entropic-FV based models, i.e., the original entropic-FV... 

Crude oil reservoirs have different temperatures, compositions, and pressures, therefore oil recovery performance by CO2 injection varies from one case to another. Furthermore, it is predicted that lower interfacial tension between injected CO2 and reservoir fluid results in more oil recovery. In this study, we investigate the effect of temperature on the equilibrium interfacial tension between CO2 and three different oil fluids at different pressures. Also minimum miscible pressure (MMP) is measured by the vanishing interfacial tension (VIT) technique to determine the temperature effect on the CO2 miscible gas injection. The results on different pure and mixtures of hydrocarbon fluids show... 

Effect of several auxiliary carbon sources such as crude oil, different precultures, and quality of adding crude oil in treatment of petroleum wax deposits by an isolated bacterial strain, BBRC9012, was investigated. First and second experiments which compered effect of molasses, glucose and crude oil, indicated that glucose and molasses causes more microbial growth, biosurfactant production and bioemolsification than crude oil. Both optometry and Surface tension measurements showed that using molasses-BHB preculture for wax treatment is not suitable and when crude oil is used as auxiliary carbon source a one day lag phase is unavoidable. It was also shown that when crude oil is added to... 

The low melting and solidification rates of phase change materials (PCM), which traces back to their low thermal conductivity coefficient, has led the application of these materials to face limitations. This paper aims to explore the effectiveness of a novel method called intermediate boiling fluid (IBF) in speeding up the energy storage and transfer processes in PCMs during a complete charging-discharging cycle. Throughout this novel technique, paraffin and acetone are utilized as PCM and IBF, respectively. In the solidification process, there is no direct contact between the cold source and the molten paraffin, while acetone, as an intermediate fluid, is being boiled via absorbing... 

Nitrogen has emerged as a competitive gas injection alternative for gas-based enhanced oil recovery processes in the past two decades. The injection of nitrogen into the reservoirs has improved the oil recovery efficiency in various oil reservoirs from heavy to volatile oils. As it is known, interfacial tension (IFT) plays a key role in any enhanced oil recovery process, particularly gas injection processes; therefore, its accurate determination is crucial for the design of any gas injection process especially at reservoir condition. In this study, an axisymmetric drop shape analysis (ADSA) was utilized to measure the equilibrium IFTs between crude oil and N2 at different temperature levels... 

In this study, a mixture of nano-encapsulated phase change materials in water has been used as the working fluid in a pulsating heat pipe in order to investigate its thermal performance. The results of the experiments showed that using the nano-encapsulated paraffin dispersed in water as working fluid improves heat transfer and decreases the thermal resistance of the pulsating heat pipe. On the other hand, among the tested concentrations for nano-encapsulated paraffin, there is an optimal value in which increasing the concentration causes an increase in the thermal resistance of the pulsating heat pipe due to the increased dynamic viscosity of the fluid. Enhancement in the thermal... 

The low thermal conductivity of phase change materials (PCM) results in the slowdown in the discharging process of PCM which limits the usability of these materials in the field of Thermal Energy Storage (TES). In this research, an innovative solution is proposed to significantly accelerate the solidification speed, up to two orders of magnitude greater than conventional methods. Using acetone as the intermediate boiling fluid (IBF), the paraffin discharge rate as a phase-change material is significantly improved which is known as super-fast discharge (SFD) in this article. In this method, liquid acetone takes the heat by boiling in liquid paraffin and causes it to solidify. As the liquid... 

A batch extraction of an essential amino acid, phenylalanine, from an aqueous solution of different concentrations by an Emulsion Liquid Membrane (ELM) was developed using D2EHPA as a cationic carrier, Span 80 as the surfactant, paraffin, and kerosene as the diluents, and HCl as the internal electrolyte. All effective parameters such as the initial pH of the aqueous external phase, the electrolyte concentration in the aqueous internal phase, carrier, and surfactant concentration in the emulsion, the volume ratio of the organic to aqueous internal phase (Roi), the volume ratio of the W/O emulsion to the aqueous external phase (Rew) and time were examined and optimized using the Taguchi...