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    Fourier transform infrared spectroscopy and scanning tunneling spectroscopy of porous silicon in the presence of methanol

    , Article Sensors and Actuators, B: Chemical ; Volume 132, Issue 1 , 2008 , Pages 40-44 ; 09254005 (ISSN) Razi, F ; Rahimi, F ; Iraji zad, A ; Sharif University of Technology
    2008
    Abstract
    Porous silicon samples were obtained from p+- and n-type silicon wafers. Gas sensing measurements showed that the electrical conductivity of porous Si on p+- and n-type wafers increases strongly and decreases weakly in the presence of methanol gas, respectively. Scanning tunneling spectroscopy (STS) indicates that the adsorption of methanol on the surface of n-porous silicon decreases the average density of states especially in the band gap. Fourier transform infrared (FTIR) spectroscopy reveals that after methanol exposure partial surface oxidation occurs which produces electron traps as well as methanol adsorption on the porous surfaces. These observations imply that the number of...