Loading...
Search for: physico-chemical-mechanisms
0.005 seconds

    Toward mechanistic understanding of heavy crude oil/brine interfacial tension: The roles of salinity, temperature and pressure

    , Article Fluid Phase Equilibria ; Vol. 375, issue , August , 2014 , p. 191-200 ; ISSN: 03783812 Moeini, F ; Hemmati-Sarapardeh, A ; Ghazanfari, M. H ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

    Toward mechanistic understanding of heavy crude oil/brine interfacial tension: The roles of salinity, temperature and pressure

    , Article Fluid Phase Equilibria ; Vol. 375, issue , 2014 , Pages 191-200 ; ISSN: 03783812 Moeini, F ; Hemmati-Sarapardeh, A ; Ghazanfari, M. H ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

    Evaluation of ascorbic acid-loaded calcium phosphate bone cements: Physical properties and in vitro release behavior

    , Article Ceramics International ; Vol. 40, issue. 3 , April , 2014 , pp. 3961-3968 ; ISSN: 02728842 Hemmati, K ; Hesaraki, S ; Nemati, A ; Sharif University of Technology
    Abstract
    In this study, different concentrations of ascorbic acid (50, 100 and 200 μg/mL) were added to the liquid phase of a calcium phosphate cement (CPC). The cements were immersed in simulated body fluid (SBF) for different intervals and physical, physicochemical and mechanical properties of them were evaluated. The release of added ascorbic acid from CPCs into the SBF solution was also studied. From the results, both setting time and injectability of CPC decreased by adding ascorbic acid, however the compressive strength was sharply increased before soaking in SBF solution. But, the compressive strength values of all cements (with or without ascorbic acid) soaked in SBF solution for more than 7... 

    Production of granulated-copper oxide nanoparticles for catalytic application

    , Article Journal of Materials Research ; Volume 25, Issue 10 , 2010 , Pages 2025-2034 ; 08842914 (ISSN) Hosseinpour, M ; Ahmadi, S. J ; Mousavand, T ; Outokesh, M ; Sharif University of Technology
    2010
    Abstract
    Ultra fine CuO nanoparticles In the range of 2 ± 0.2 nm were synthesized by the supercritical hiydrotliermal method in a batch reactor. Itwas demonstrated that elevating the pH of the Cu2+ precursor solution to around 6 (neutral condition) not only does not lead to excessive agglomeration of the particles, but also reduces particle size and in general promotes their nanoscale characteristics. Prepared nanoparticles were immobilized in the biopolymcric matrix of barium alginate and calcined at different temperatures resulting in micro spherical granules of high porosity and elevated mechanical strength. The fabricated samples were characterized using x-ray diffractometry (XRD), transmission... 

    A porous hydrogel-electrospun composite scaffold made of oxidized alginate/gelatin/silk fibroin for tissue engineering application

    , Article Carbohydrate Polymers ; Volume 245 , 2020 Hajiabbas, M ; Alemzadeh, I ; Vossoughi, M ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In the article, a bilayer nanocomposite scaffold made of oxidized alginate (OAL), gelatin (G), and silk fibroin (SF) has been prepared via combining electrospinning, in situ gas foaming, in situ crosslinking and freeze drying methods. The physicochemical and mechanical properties, as well as thermal stability of the proposed composite, have been investigated by SEM, FTIR, XRD, tensile, and TGA analysis. The data indicate that structure and degree of crosslinking play a vital role in adjusting the physical and mechanical properties of composite scaffolds. Further, the authors find a favorable adipose-derived mesenchymal stem cell's (AMSC) attachment and distribution within this novel... 

    Hybrid silk fibroin–gelatin nanofibrous sheet for drug delivery and regenerative medicine: In-vitro characterization and controlled release of simvastatin/protein

    , Article Polymers for Advanced Technologies ; 2020 Hajiabbas, M ; Alemzadeh, I ; Vossoughi, M ; Sharif University of Technology
    John Wiley and Sons Ltd  2020
    Abstract
    Blend drug-loading method in electrospun scaffolds has gained much attention as a cost-effective and simple delivery system in regenerative medicine. However, it has some drawbacks, such as the burst release of encapsulated drugs and denaturing active agents in harsh organic solvents. In this study, a new silk fibroin-gelatin (SF–G) fibrous sheet has been introduced as an engineered scaffold and a straightforward drug delivery system for skin tissue engineering applications. The hybrid sheets have been prepared via co-electrospinning and in-situ crosslinking methods without corrosive solvents and toxic crosslinking agents. To evaluate the proposed scaffold as a controlled release system, the... 

    Hybrid silk fibroin–gelatin nanofibrous sheet for drug delivery and regenerative medicine: In-vitro characterization and controlled release of simvastatin/protein

    , Article Polymers for Advanced Technologies ; Volume 32, Issue 3 , 2021 , Pages 1333-1344 ; 10427147 (ISSN) Hajiabbas, M ; Alemzadeh, I ; Vossoughi, M ; Sharif University of Technology
    John Wiley and Sons Ltd  2021
    Abstract
    Blend drug-loading method in electrospun scaffolds has gained much attention as a cost-effective and simple delivery system in regenerative medicine. However, it has some drawbacks, such as the burst release of encapsulated drugs and denaturing active agents in harsh organic solvents. In this study, a new silk fibroin-gelatin (SF–G) fibrous sheet has been introduced as an engineered scaffold and a straightforward drug delivery system for skin tissue engineering applications. The hybrid sheets have been prepared via co-electrospinning and in-situ crosslinking methods without corrosive solvents and toxic crosslinking agents. To evaluate the proposed scaffold as a controlled release system, the... 

    Effect of graphene oxide nanosheets on visible light-assisted antibacterial activity of vertically-aligned copper oxide nanowire arrays

    , Article Journal of Colloid and Interface Science ; Volume 521 , 2018 , Pages 119-131 ; 00219797 (ISSN) Kiani, F ; Ashari Astani, N ; Rahighi, R ; Tayyebi, A ; Tayebi, M ; Khezri, J ; Hashemi, E ; Rothlisberger, U ; Simchi, A ; Sharif University of Technology
    Academic Press Inc  2018
    Abstract
    In the present work, the effect of graphene oxide (GO) nanosheets on the antibacterial activity of CuO nanowire arrays under visible light irradiation is shown. A combined thermal oxidation/electrophoretic deposition technique was employed to prepare three-dimensional networks of graphene oxide nanosheets hybridized with vertically aligned CuO nanowires. With the help of standard antibacterial assays and X-ray photoelectron spectroscopy, it is shown that the light-activated antibacterial response of the hybrid material against gram-negative Escherichia coli is significantly improved as the oxide functional groups of the GO nanosheets are reduced. In order to explore the physicochemical...