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    A highly thermal-resistant electrospun-based polyetherimide nanofibers coating for solid-phase microextraction Microextraction Techniques

    , Article Analytical and Bioanalytical Chemistry ; Vol. 406, issue. 8 , March , 2014 , p. 2141-2149 Bagheri, H ; Akbarinejad, A ; Aghakhani, A ; Sharif University of Technology
    Abstract
    A high-temperature-resisant solid-phase microextraction (SPME) fiber was prepared based on polyetherimide (PEI) by the electrospinning method. The PEI polymeric solution was converted to nanofibers using high voltages and directly coated on a stainless steel SPME needle. The scanning electron microscopy images of PEI coating showed fibers with diameter range of 500-650 nm with a homogeneous and smooth surface morphology. The SPME nanofibers coating was optimized for PEI percentage, electrospinning voltage, and time. The extraction efficiency of the coating was investigated for headspace SPME of some environmentally important polycyclic aromatic hydrocarbons from aqueous samples followed by... 

    Development of a Solid-Phase Microextraction Method Based on Electrospun Polyetherimide Nanofibers for Determination of Polycyclic Aromatic Hydrocarbons in Aqueous Samples

    , M.Sc. Thesis Sharif University of Technology Akbarinejad, Alireza (Author) ; Bagheri, Habib (Supervisor)
    Abstract
    Attentions to nano materials due to their vast applications in different branches of science and technology have been remarkably increased in recent years. Nanofibers are an important class of nano materials which could be used as novel sorbents because of their high surface to volume ratio as a result of long lengths and nano-to-micro-scale diameters. Electrospinning is a broadly used technology which utilizes high electrostatic forces for producing nanofibers. In this study a novel high temperature resistant solid phase microextraction (SPME) fiber was prepared besed on Polyetherimide (PEI) by this method. The porosity of the PEI fiber was investigated by scanning electron microscopy... 

    Influence of novel surface modifying macromolecules and coagulation media on the gas permeation properties of different polymeric gas separation membranes

    , Article Journal of Applied Polymer Science ; Volume 124, Issue 3 , 2012 , Pages 2300-2310 ; 00218995 (ISSN) Savoji, H ; Rana, D ; Matsuura, T ; Soltanieh, M ; Tabe, S ; Sharif University of Technology
    2012
    Abstract
    Integrally skinned asymmetric membranes for the separation of O 2 and N 2 were fabricated by the phase inversion technique from polysulfone, polyetherimide, and polyimide. Two types of surface modifying macromolecules (SMMs) including hydrophilic SMM (LSMM) and charged SMM (cSMM) were synthesized and blended with the casting solution to modify the membrane surface. The cast film was then immersed in the first coagulant alcohol (methanol, ethanol, or isopropanol) for a predetermined period, before being immersed in the second coagulant (water). The SMMs used in these experiments were laboratory synthesized by the two-step process of polyurethane prepolymer synthesis and end capping, before...