Sharif Digital Repository

The performance of commercially available poly (2,6-dimethyl-1,4-phenylene oxide) (PPO) and Cardotype polyimide (PI) hollow fiber membranes was investigated in removing hydrogen sulfide from methane in a series of bench-scale experiments. It was observed that in the concentration range of hydrogen sulfide in methane from 101 to 401 ppm, the methane permeability decreased in the presence of hydrogen sulfide for Cardo-type polyimide hollow fiber membranes, whereas the PPO membrane performance was not affected. The separation coefficients of hydrogen sulfide/methane were 6 and 4 for PI and PPO membranes, respectively. Effects of temperature on the performance of PI and PPO membranes were... 

Porphyrin-POM hybrid materials with excellent NLO properties are supposed to be a worthy entrant for forthcoming telecommunication, optical fibers, optical data storage and optical limiting devices, but due to adverse solubility problems, they are replaced by polymeric materials. Herein, we assessed third order NLO and second hyperpolarizability of porphyrin-polyimide compounds (NH-PI and Zn-PI) synthesized from the reaction of 4,4ʹ-hexafluoroisopropylidene-diphthalic anhydride (6FDA) with C44H32N6 (NH-DATPP) and C44H30N4Zn (Zn-DATPP) porphyrins under ambient conditions. The Z-scan measurement of these compounds revealed reverse saturation absorption as well as self-defocusing performance.... 

Gas separation properties of commercially available polyphenylene oxide (PPO) and Cardo-type polyimide (PI) hollow fiber membranes were investigated by CO2/CH4 and O2/N2 separation experiments. The pure gas permeation and the mixed gas separation experiments indicated that the two hollow fiber membranes were suitable candidates for O2/N2 and CO2/CH4 separations. Average O2/N2 permselectivities of 3.9 and 5.7 for PPO and PI hollow fibers, respectively, average CO2/CH4 permselectivities of 16.4 and 36.0 for PPO and PI hollow fibers, respectively, CO2 permeances of 210 and 110 GPU at 100 psig for PPO and PI hollow fibers, and O2 permeances of 40 GPU and 15 GPU for PPO and PI hollow fibers were... 

This paper presents a new method for tuning linear controllers such as Proportional-Integrating (PI) and Proportional-Resonant (PR) structures which are frequently used in different power electronic and power system applications. Those controllers are placed within a general structure offered by the Internal Model Principle (IMP) of control theory. In this paper, the first perspective uses the well-known concept of Linear Quadratic Regulator (LQR) to address the problem as a regulation problem. Matrix Q of the LQR design is then finely adjusted in order to assure desired transient response for the system. The second perspective is based on redefining the LQR problem in order to make it... 

In this study, a two-stage membrane system for the separation of CH4/CO2 was designed based on a series of laboratory-scale experiments obtained using two types of commercial hollow fiber membranes including polyphenylene oxide (PPO) and Cardo-type polyimide (PI). The former showed high permeability and low to moderate selectivity, while the latter exhibited high selectivity and moderate permeability. In this design, the permeate from the first stage - rich in CO2 but containing considerable amount of methane - is fed into the second stage to recover its methane content. The performances of double- and single-stage system designs were compared in terms of methane loss (the ratio of methane... 

Integrally skinned asymmetric membranes for the separation of O 2 and N 2 were fabricated by the phase inversion technique from polysulfone, polyetherimide, and polyimide. Two types of surface modifying macromolecules (SMMs) including hydrophilic SMM (LSMM) and charged SMM (cSMM) were synthesized and blended with the casting solution to modify the membrane surface. The cast film was then immersed in the first coagulant alcohol (methanol, ethanol, or isopropanol) for a predetermined period, before being immersed in the second coagulant (water). The SMMs used in these experiments were laboratory synthesized by the two-step process of polyurethane prepolymer synthesis and end capping, before... 

It is proposed to employ melting rate, heat input, and detaching droplet diameter as controlled variables to control heat and mass transfer to work piece in a gas metal arc welding process. A two-layer architecture with cascade configuration of PI and MPC controllers is implemented to incorporate existing constraints on the process variables, improve transient behavior of the closed-loop responses and reduce interaction level. Computer simulation results are presented to indicate usefulness of the proposed controlled variables selection and applying two-layer control architecture to control heat and mass transfer to work piece  

The effects of water vapor on CO2/CH4 separation using commercially available poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and Cardo-type polyimide hollow fiber membranes were investigated. Pure methane and CO2/CH4 mixture permeation experiments were carried out in the absence and presence of water vapor (60% RH). Pure methane permeance decreased in the presence of water vapor for both membrane types. The decrease was 28% for hydrophilic Cardo-type polyimide and 6% for hydrophobic PPO membranes. The decline in the permeance was also observed for CO2/CH4 mixture separation through both membranes. However, selectivities of the two membranes were affected differently by water vapor. The...