Sharif Digital Repository

Due to important applications and benefits of mass transfer in engineering and especially in nano-scales engineering, nano-science researchers have focused on this field. Considerably, in classical fluid dynamics applications, the fluid can be transported using differential pressure gradient. But the classical methods require moving components, which are usually expensive and not applicable in nano-sizes. To avoid these problems in nano-size transportation, we can use electro-osmotic process to perform mass transfer in low transfer rates. In electro-osmotic process, we can move electrolyte solvent with the aid of an external electrical field. Due to importance of this process in... 

The bis(cyclometalated) platinum(II) complexes of the type [Pt(ppy)(p′py)], in which ppy = p′py = 2-(p-tolyl)pyridine, 6; ppy = 2-(3-bromophenyl)pyridine, p′py = 2-(p-tolyl)pyridine, 7; ppy = 2-(2,4-difluorophenyl)pyridine, p′py = 2-(p-tolyl)pyridine, 8; ppy = 2-(2,4-difluorophenyl)pyridine, p′py = 2-(2,4-difluorophenyl)pyridine, 9, have been prepared from the reaction of the cyclometalated platinum(II) complex [Pt(ppy)Me(SMe2)] with one equiv p′py and one equiv B(C6F5)3. The structure of 6, 7 and 10 determined using X-ray crystallography in solid state. However NMR spectroscopy methods have been used for structural characterization of the complexes in solution phase. The bis(cyclometalated)...