Sharif Digital Repository

Eu3+- and Ce3+-doped yttrium silicate, as well as Eu2+-doped zinc silicate nanoparticles, were grown in a porous SiO2 matrix using an impregnation method. For Y2Si 2O7:Eu3+, particles of about 50 nm size were obtained that exhibited several photoluminescence (PL) peaks in red. Different peaks showed slightly different decay times; however, their excitation mechanism was found the same. Increasing the Eu concentration increased the PL intensity while reducing the decay time. Y2Si2O7:Ce 3+ nanoparticles in the porous matrix showed bright blue emission, consisting of two peaks at 358 nm and 378 nm. Re-impregnation process was found effective in changing the relative intensity of the two peaks.... 

Titania nanofibers were prepared using a colloidal solution of Titania nanoparticles and a templating method. The preparation comprises impregnation of cellulose fibers in the solution containing Titania nanoparticles followed by thermal removal of the cellulose template. It is evidenced by scanning electron microscopy (SEM) that the residue substance consists of micron size fibers with a microstructure of nanofibers. The pore size distribution of the substance is multi-scale and fractal morphology was demonstrated with two fractal regimes with dimensions of 1.78 and 2.97 for sizes below and above 7.5nm, respectively. The surface area of the Titania fibers was measured about 250m2/g. The... 

Porous poly-silicon (PPS) is a cheaper alternative to single crystal porous silicon and is a favorable choice for making gas sensors. In this study, porous poly-silicon samples were prepared using different HF concentrations and the structural and gas-sensing properties were studied. The topography of the surface was investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The variation of electrical conductivity of the samples in the presence of dry air-diluted acetone, ethanol and methanol showed that for a constant etching current, the sensitivity was highest for samples prepared in 13% HF solution. The structure of the films in the optimum HF... 

In this paper, similarity solution of free convection from inclined permeable wall embedded in a stratified porous medium is investigated. It is assumed that the heated wall has constant temperature and permeability along the wall is variable. Energy equation and Darcy's law as momentum have been used. Due to similarity solution we consider only large wall inclination angle. Effects of mass flux, permeability variation function, and wall inclination angle on thermal and velocity boundary layer thickness and heat transfer at the wall are investigated. Copyright © 2005 by ASME  

The correct quantification of porosity is essential in all studies pertaining to porous media. A host of existing works employs a constant, bulk value for porosity, even when the porous sample is attached to a free fluid. Since the volume fraction of the solid matrix near the interface region differs from that in the core, the porosity undergoes a spatial variation. Here we present a novel relation for the porosity as a function of depth below the interface, using the concept of surface roughness applied on the classical definition of open porosity. This relation has been verified by computational modeling as well as non-invasive laser experiments. It has been shown that this depth-dependent... 

In this article, transient two-dimensional mixed convection of nanofluids in the entrance region of a vertical channel has been studied carefully. The geometry under consideration consisted of a parallel-plate channel partly filled with a porous medium with a constant wall temperature. In the free flow region, the two-dimensional flow field has been governed by the Navier-Stokes equations. The general formulation of the momentum equations accounting for the inertial and the viscous effects in the presence of a porous medium has been used. Viscous dissipation effects have also been incorporated in the thermal energy equation. Effects of Brownian diffusion and thermophoresis have also been... 

Metallic or ceramic micro/nanoporous materials have attracted particular attention due to some interesting structural and functional properties. There exist a variety of methods for producing porous materials by which optimized features can be reached. Spark plasma sintering (SPS) is one of these new-emerging approaches. This technique is often combined with conventional technologies and produce a variety of porous structures with tailorable microstructure and physicomechanical properties. This review addresses SPS and obtainable porous materials with nanoscale and microscale microstructural features. The processing methods, microstructural phenomena, and physicomechanical properties of... 

The flow behavior of a semi-solid A356 alloy at high solid fraction was studied. The mushy zone was considered as an effective two-phase, so that the solid continuum can be compressible porous media, and the liquid phase interaction with the solid skeleton was of Darcy type. The semi-solid flow through the upsetting test was modeled in ABAQUS finite element method software. The Gurson yield criterion has been developed for the modeling process of the flow behavior of solid porous medium. Specimens were globulized by a thermomechanical process and then were tested for various percentages of upsetting. The distribution of solid fraction along the radius of the specimens at different height... 

This work presents an experimental study of the effect of a magnetic field on laminar forced convection of a ferrofluid flowing in a tube filled with permeable material. The walls of the tube are subjected to a uniform heat flux and the permeable bed consists of uniform spheres of 3-mm diameter. The ferrofluid synthesis is based on reacting iron (II) and iron (III) in an aqueous ammonia solution to form magnetite, Fe3O4. The magnetite is mixed with aqueous tetra methyl ammonium hydroxide, (CH3) 4NOH, solution. The dependency of the pressure drop on the volume fraction, and comparison of the pressure drop and the temperature distribution of the tube wall is studied. Also comparison of the... 

We have investigated an oxidation of substrate effect on structural morphology of zinc oxide (ZnO) rods. ZnO rods are grown on porous silicon (PS) and on thermally oxidized porous silicon substrates by carbothermal reduction of ZnO powder through chemical vapour transport and condensation. Porous silicon is fabricated by electrochemical etching of silicon in hydrofluoric acid solution. The effects of substrates on morphology and structure of ZnO nanostructures have been studied. The morphology of substrates is studied by atomic force microscopy in contact mode. The texture coefficient of each sample is calculated from X-ray diffraction data that demonstrate random orientation of ZnO rods on... 

The solute transport model MODFLOW has become a standard tool in risk assessment and remediation design. However, particle transport models that take into account both particle agglomeration and deposition phenomena are far less developed. The main objective of the present study was to evaluate the feasibility of adapting the standard code MODFLOW/MT3D to simulate the agglomeration and transport of three different types of polymer-modified nanoscale zerovalent iron (NZVI) in one-dimensional (1-D) and two-dimensional (2-D) saturated porous media. A first-order decay of the particle population was used to account for the agglomeration of particles. An iterative technique was used to optimize... 

Pore network modeling uses a network of pores connected by throats to model the void space of a porous medium and tries to predict its various characteristics during multiphase flow of various fluids. In most cases, a non-realistic regular lattice of pores is used to model the characteristics of a porous medium. Although some methodologies for extracting geologically realistic irregular networks from pore space images have been presented, these methods require some experimental data which are either unavailable or costly to obtain. 3-dimensional image or 2-dimensional SEM images are among these types of data. In this paper a new irregular lattice algorithm for the construction of these... 

In this work, the thermal and hydrodynamic performance of ferromagnetic fluid, which flows through a copper tube in thermal entrance region, has been studied. The flow in the tube is laminar and subjected to constant heat flux. A part of the tube contains a porous medium with paramagnetic properties and porosity of 0.46. Ferrofluid is composed of Fe3o4 and water with (CH3)4NOH as a surfactant that is prepared in three different volume fractions. The effects of constant and oscillating magnetic fields on convective heat transfer coefficient were examined for various Reynolds numbers, frequencies and volume fractions. The results show that the maximum enhancements of average heat transfer... 

Purpose: Although magnetite nanoparticles (MNPs) are promising agents for hyperthermia therapy, insufficient drug encapsulation efficacies inhibit their application as nanocarriers in the targeted drug delivery systems. In this study, porous magnetite nanoparticles (PMNPs) were synthesized and coated with a thermosensitive polymeric shell to obtain a synergistic effect of hyperthermia and chemotherapy. Materials and methods: PMNPs were produced using cetyltrimethyl ammonium bromide template and then coated by a polyethylene glycol layer with molecular weight of 1500 Da (PEG1500) and phase transition temperature of 48 ± 2 °C to endow a thermosensitive behavior. The profile of drug release... 

Flexible all-solid-state supercapacitors are promising electronic devices have been developed in the past decade. Recent efforts to develop such systems are as to construction of free standing electrodes with high specific capacitance. Among these developments, construction of carbon-based current collectors, with high surface areas and good mechanical properties via a facile and economic way, has been taken a great deal of attention. In this study, porous graphene were used as current collector for placement of the carbon fibers functionalized with polyaniline, to prepare a free-standing supercapacitor electrode through a new and facile method. This method begins through blending of the... 

The solute transport model MODFLOW has become a standard tool in risk assessment and remediation design. However, particle transport models that take into account both particle agglomeration and deposition phenomena are far less developed. The main objective of the present study was to evaluate the feasibility of adapting the standard code MODFLOW/MT3D to simulate the agglomeration and transport of three different types of polymer-modified nanoscale zerovalent iron (NZVI) in one-dimensional (1-D) and two-dimensional (2-D) saturated porous media. A first-order decay of the particle population was used to account for the agglomeration of particles. An iterative technique was used to optimize... 

In this paper, a multiscale homogenization approach is developed for fully coupled saturated porous media to represent the idealized sugar cube model, which is generally employed in fractured porous media on the basis of dual porosity models. In this manner, an extended version of the Hill-Mandel theory that incorporates the microdynamic effects into the multiscale analysis is presented, and the concept of the deformable dual porosity model is demonstrated. Numerical simulations are performed employing the multiscale analysis and dual porosity model, and the results are compared with the direct numerical simulation through 2 numerical examples. Finally, a combined multiscale-dual porosity... 

Concerning the geometrical effect of inner cylindrical hot pins, the natural convective heat transfer of nanofluid in a homogenous porous medium in a squared enclosure is numerically studied, using lattice Boltzmann method (LBM). In order to investigate the arrangement of inner cylinders for better heat transfer performance, five different configurations (including one, three, and four pins) were compared, while the total heat transfer area of inner pins were held fixed. Squared cavity walls and inner cylinder's surfaces were constantly held at cold and warm temperatures, respectively. In our simulation, Brinkman and Forchheimerextended Darcy models were utilized for isothermal... 

The Elder problem is one of the well-known examples of an unstable density-driven flow (DDF) and solute transport in porous media. The goal of this research is to investigate the influence of fracture networks on this benchmark problem due to the great importance of the fractured heterogeneity effect on unstable DDF. For this aim, the fractured Elder problem is solved using COMSOL Multiphysics, which is a finite element method simulator. Uniform and orthogonal fracture networks are embedded to analyze free convective flow and development of unstable salt plumes. The results indicate that the mesh sensitivity of the fractured Elder problem is greater than the homogeneous case. Furthermore, it...