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    Pr at Gd or Ba site in GdBa2Cu3O7: Appearance of superconductivity

    , Article Physical Review B - Condensed Matter and Materials Physics ; Volume 68, Issue 10 , 2003 ; 10980121 (ISSN) Mohammadizadeh, R ; Akhavan, M ; Sharif University of Technology
    2003
    Abstract
    Gd(Ba2-xPrx)Cu3O7+δ single phase polycrystalline samples with 0.0 < − x < − 1.0 were investigated for their structural and electronic properties. Due to the solubility limit, the 123 structure forms in the 0.0 < − x < −0.50 range; for x > −0.6, a decomposition of the perovskite-type phases occurs. For x=0.2, there is an orthorhombic-tetragonal phase transition, concurrent with a metal-insulator transition, which is evident in the normal state resistivity. For xc=0.35, the superconductor-insulator transition occurs. An unusual hump has been observed on the resistivity vs temperature curve of the samples for particular values of Pr doping. Based on the Rietveld refinement of the x-ray... 

    Effects of Pr doping and magnetic field on vortex pinning in Gd-123 based HTSC

    , Article Physica Status Solidi C: Conferences ; Volume 1, Issue 7 , 2004 , Pages 1883-1886 ; 16101634 (ISSN) Mohammadizadeh, M. R ; Akhavan, M ; Sharif University of Technology
    2004
    Abstract
    The magnetoresistance of single phase polycrystalline Gd(Ba 2-xPrx)Cu3O7-δ samples have been studied within thermally activated flux creep model. The decrease of pinning energy with applied magnetic field can be scaled to two power law relations for magnetic fields, smaller and also larger than about 1 kOe. The derived pinning energy shows that the Pr-doping, similar to weak links, decreases the vortex flux pinning energy. It is also concluded that the substitution of Pr at Ba site has a more destructive effect on the flux dynamics than Pr at rare earth site. © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim  

    Synthesis and Investigation of Effect of Pr Doping on the Compound Y(3-x) Pr x Ba5 Cu8 O(19-δ)-F

    , M.Sc. Thesis Sharif University of Technology Jafari Gharyeh Ali, Hamid Reza (Author) ; Akhavan, Mohammad (Supervisor)
    Abstract
    Synthesis and Investigation of Effect of Pr Doping on the Compound Y_(3-x) 〖Pr〗_x 〖Ba〗_5 〖Cu〗_8 O_(19-δ)-FInvestigation of doping of the parent compounds with different elements is important to understand the origin of high-Tc superconductivity. Several research groups have attempted to improve the properties of superconductivity and better understand the superconductivity mechanism of cuprate through doping different elements. In this research, at first, optimization of Y_3 〖Ba〗_5 〖Cu〗_8 O_(19-δ) F_z samples with z=0.2 ,0.4 ,0.6 ,0.8 ,1 ,2 ,3 ,4 have been done. By doping fluorine instead of oxygen, we expected an increase in the transition temperature, based on some the reports. But after... 

    Magnetic field effects on electrical resistivity of (Gd 1-xPrx)Ba2Cu3O7-δ and Gd(Ba2-xPrx)Cu3O7+δ

    , Article Physica Status Solidi C: Conferences ; Volume 1, Issue 7 , 2004 , Pages 1887-1890 ; 16101634 (ISSN) Mohammadizadeh, M. R ; Akhavan, M ; Sharif University of Technology
    2004
    Abstract
    The magnetoresistance measurements of single phase polycrystalline Gd(Ba2-xPrx)Cu3O7+δ and Gd1-xPrx)Ba2Cu3O 7-δ samples have been compared and analyzed by the Ambegaokar and Halperin phase slip model. The derived power law dependences of pinning energy to applied magnetic field and temperature have been studied for different amounts of Pr doping. The power factors depend on the Pr doping. Moreover, in both systems, the magnetic field dependence of the pinning energy power factor increases for small amounts of Pr doping, while for larger amount of Pr doping, it decreases. The critical current power law dependence to magnetic field decreases with increasing Pr doping. Pr substitution at Ba or... 

    Role of Pr doping in Gd1113

    , Article Physica Status Solidi C: Conferences ; Volume 1, Issue 7 , 2004 , Pages 1855-1858 ; 16101634 (ISSN) Kariminezhad, M ; Khosroabadi, H ; Akhavan, M ; Sharif University of Technology
    2004
    Abstract
    Tetragonal Gd1-xPrxBaSrCu3O 7-δ polycrystalline samples (0 ≤ x ≤ 0.9) have been prepared by the standard solid-state reaction and characterized by XRD. A hump on the ρ(T) curve have been observed at about 80 K for large values of x. The normal state resistivity have been investigated with two and three dimensional variable range hopping (2&3D-VRH) and Coulomb gap (CG). For low concentration of Pr, 2D-VRH is the dominant mechanism, but with the increase of x, 3D-VRH is dominant. The magnetoresistance measurements of the samples have been analysed by the Ambegakor and Halperin (AH) phase slip model. The field dependences of the pinning energy and critical current density have been studied for... 

    Thermally activated phase slip and variable range hopping in Tm(Ba 2-xPrx)Cu3O7+δ

    , Article Physica Status Solidi C: Conferences ; Volume 1, Issue 7 , 2004 , Pages 1891-1894 ; 16101634 (ISSN) Mokhtari, Z ; Khosroabadi, H ; Akhavan, M ; Sharif University of Technology
    2004
    Abstract
    The magnetoresistance measurement of single phase polycrystalline Tm(Ba2-xPrx)Cu3O7+δ samples have been analyzed by the Ambegaokar and Halperine (AH) phase slip model. The magnetic field dependence of pinning energy power factors increase with the increase of Pr doping. The derived critical current density from the AH theory decreases with increasing magnetic field and Pr-doping for all superconducting samples. It shows that the Pr-doping plays the role of weak link. We have also investigated the normal state resistivity with the hopping model. We have found a CG-VRH cross-over with the increase of Pr content near metal insulator transition. The deacrease of the localization length of the... 

    Effect of Doping of La in Pr Site and Cu/Fe in Ni site on Crystal Structure, Oxygen Non-stoichiometry level and Electrical Conductivity of Pr2NiO4 as Intermediate Temperature Solid Oxide Fuel Cell Cathode

    , M.Sc. Thesis Sharif University of Technology Farhat, Pooneh (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Nowadays, one of the most important research goals is to develop intermediate-temperature solid oxide fuel cells (IT-SOFC) operated at 500–800 °C. However, the large cathode polarization resistance caused by the reduced temperature is a major barrier against such an urgent demand for commercialization. In this regard, it is necessary to select a proper material as a cathode working efficiently at reduced temperatures without losing its desired performance. Various mixed ionic electron conductors (MIECs), especially Ruddlesden–Popper-type oxides, are used to improve the cathode performance at intermediate temperatures. Among these layered oxides, Pr2NiO4 has been reported to possess the... 

    Semi-spatiotemporal fMRI brain decoding

    , Article Proceedings - 2013 3rd International Workshop on Pattern Recognition in Neuroimaging, PRNI 2013 ; 2013 , Pages 182-185 ; 9780769550619 (ISBN) Kefayati, M. H ; Sheikhzadeh, H ; Rabiee, H. R ; Soltani Farani, A ; Sharif University of Technology
    2013
    Abstract
    Functional behavior of the brain can be captured using functional Magnetic Resonance Imaging (fMRI). Even though fMRI signals have temporal and spatial structures, most studies have neglected the temporal structure when inferring mental states (brain decoding). This has two main side effects: 1. Degradation in brain decoding performance due to lack of temporal information in the model, 2. Inability to provide temporal interpretability. Few studies have targeted this issue but have had less success due to the burdening challenges related to high feature-to-instance ratio. In this study, a novel model for incorporating temporal information while maintaining a low feature-to-instance ratio, is... 

    Effect of Pr doping on transport properties of Nd(Ba2-xPr x)Cu3O7+8

    , Article Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers ; Volume 44, Issue 11 , 2005 , Pages 7934-7942 ; 00214922 (ISSN) Maleki, P ; Akhavan, M ; Sharif University of Technology
    2005
    Abstract
    Solid-state-reacted polycrystalline Nd(Ba2-xPr x)Cu3O7+8 materials have been prepared and investigated using X-ray diffraction and resistivity measurements. Our results show that Nd(Ba2-xPrx)Cu3O7+8 is a superconductor when x < 0.3. The Tc depression in superconductivity of Pr at Ba sites is due to both hole filling/localization and depairing effects. The normal state conductivity undergoes a dimensional crossover from two-dimensional to three-dimensional in the frame of the variable range hopping regime. The localization length of carriers shows that Pr doping localizes carriers in the normal state and causes the Tc depression. The magnetoresistance of the samples has been investigated... 

    Flux dynamics, superconducting, and normal state properties of Gd(Ba 2-xPrx)Cu3O7+δ

    , Article European Physical Journal B ; Volume 42, Issue 3 , 2004 , Pages 321-336 ; 14346028 (ISSN) Mohammadizadeh, M. R ; Akhavan, M ; Sharif University of Technology
    2004
    Abstract
    Gd(Ba2-xPrx)Cu3O7+δ single phase polycrystalline samples with 0.0 ≤ x ≤ 1.0 were investigated for structural, electronic and flux dynamics properties. Two-dimensional variable range hopping (VRH) is the dominant conduction mechanism in the normal state of the system. Pr doping strongly localizes the carriers in normal state, and finally causes the suppression of superconductivity. The effect of Pr substitution in 123 structure of HTSC at R or Ba sites is to increase the pseudogap temperature Ts, although, Pr at Ba sites has a stronger effect on the increase of Ts and suppression of superconductivity. The magnetoresistance of the samples have been studied within thermally activated flux creep... 

    Effect of Doping la/nd in pr Site and fe/cu in ni Site on Thermal Stability of the Pr2NiO4+δ as the Cathode of Intermediate Temperature Solid Oxide Fuel Cell

    , M.Sc. Thesis Sharif University of Technology Behsam, Shadi (Author) ; Fagihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Solid oxide fuel cells (SOFCs) are a route to highly efficient and clean power, which have been attracting interest due to the issues associated with the ever-increasing energy demand and pollution. However, their commercialization is hindered by the high operating temperatures (700-1000℃). One of the challenges faced by intermediate temperature solid oxide fuel cells (IT-SOFCs) with operating temperature in the range of 500-700℃ is the increased overpotentials of the components, especially cathode. Lanthanide nickelates (Ln2NiO4+δ, Ln = La,Pr,Nd) with mixed ionic and electronic conduction (MIEC) have already been introduced as promising IT-SOFC cathode materials. Among them, Pr2NiO4+δ... 

    Synthesis and Characterization of Praseodymium Nickelate for Low Temperature Solid Oxide Fuel Cell Cathode

    , M.Sc. Thesis Sharif University of Technology Naeini, Mina (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Solid oxide fuel cells as high temperature electrochemical devices draw much attention in the last decades due to their fuel flexibility, high efficiency and low pollution. However, lowering operating temperature from about 850°C to around 650°C without significant overpotential loss, in order to lower costs and increase cells life time has remained a challenge. Recently, a new family of mixed ionic and electronic conducting ceramics (MIECs) which are formulated Ln2NiO4+δ (Ln= La,Nd,Pr) and crystallized in Ruddlesden–Popper structure, have been regarded as appropriate cathode materials for the low or intermediate temperature solid oxide fuel cells (IT-SOFC). Amongst these compounds,... 

    Oxygen and Rare Earth Doping Effects on REn 2BanCu2n 2Om Superconductor Compounds

    , Ph.D. Dissertation Sharif University of Technology Sandoghchi, Mohammad (Author) ; Akhavan, Mohammad (Supervisor)
    Abstract
    There are two challenging problems with the physical properties of the recently discovered cuprate, Y3Ba5Cu8O19 δ (Y358): (1) the value of its transition temperature (Tc) and (2) its unknown crystal structure. While some reports argue that Tc of Y358 and its crystal structure are completely different from those of the YBa2Cu3O7 δʹ (Y123) compound, other reports indicate the similarity of both transition temperatures and XRD patterns (or crystal structure) of these materials. It has been suggested that these similarities are due to oxygen deficiency (δ) of Y3Ba5Cu8O19 δ or the decomposition of Y358 to Y123. In this thesis, we address these issues. At first, we have tried to answer the... 

    Electrochemical Properties and Stability of Ruddlesden-Popper (RP) Nickelates as Cathodes for IT-SOFC

    , Ph.D. Dissertation Sharif University of Technology Khoshkalam, Mohammad (Author) ; Faghihi Sani, Mohammad Ali (Supervisor) ; Madaah Hosseini, Hamid Reza (Co-Supervisor)
    Abstract
    For improving cost competitiveness of both SOEC and SOFC technology, it is desirable to reduce the temperature of operation preferably down towards 500 oC – 600 oC, as this will slow down the rate of various degradation processes and allow use of much cheaper materials for auxiliary components. In this range, the oxygen electrode typically dominates the cell resistance, and hence there is a need to develop cost effective electrodes with improved performance at low temperature. Whereas the oxygen exchange on Ruddlesden-Popper type Ni based compounds like Pr2NiO4 with interstitial oxygen defects is known to be very fast, reported electrode performance of micron-sized composites based on these... 

    A novel LQR based optimal tuning method for IMP-based linear controllers of power electronics/power systems

    , Article Proceedings of the IEEE Conference on Decision and Control, 12 December 2011 through 15 December 2011 ; 2011 , Pages 7711-7716 ; 01912216 (ISSN) ; 9781612848006 (ISBN) Hasanzadeh, A ; Edrington, C. S ; Mokhtari, H ; Sharif University of Technology
    2011
    Abstract
    This paper presents a new method for tuning linear controllers such as Proportional-Integrating (PI) and Proportional-Resonant (PR) structures which are frequently used in different power electronic and power system applications. Those controllers are placed within a general structure offered by the Internal Model Principle (IMP) of control theory. In this paper, the first perspective uses the well-known concept of Linear Quadratic Regulator (LQR) to address the problem as a regulation problem. Matrix Q of the LQR design is then finely adjusted in order to assure desired transient response for the system. The second perspective is based on redefining the LQR problem in order to make it... 

    Investigation of quantum conductance in semiconductor single-wall carbon nanotubes: Effect of strain and impurity

    , Article Journal of Applied Physics ; Volume 110, Issue 6 , 2011 ; 00218979 (ISSN) Rabiee Golgir, H ; Faez, R ; Pazoki, M ; Karamitaheri, H ; Sarvari, R ; Sharif University of Technology
    2011
    Abstract
    In this paper the effect of strain and impurity on the quantum conductance of semiconducting carbon nanotubes (CNTs) have been studied by ab-initio calculations. The effect of strain and impurity on the CNT conducting behavior and physical characteristics, like density of states (DOS), band structure, and atomic local density of state (LDOS), is considered and discussed separately and simultaneously. Our results show that the quantum conductance of semiconductor CNTs is increased by compression strain, elongation strain, and replacing nitrogen and boron doping in its structure. The amount of increasing in the conductance depends on the type of strain and impurity. Conductance of CNT can be... 

    Enhanced Activity of Pr6O11 and CuO Infiltrated Ce0.9Gd0.1O2 Based Composite Oxygen Electrodes

    , Article Journal of the Electrochemical Society ; Volume 167, Issue 2 , January , 2020 Khoshkalam, M ; Faghihi Sani, M. A ; Tong, X ; Chen, M ; Hendriksen, P. V ; Sharif University of Technology
    Institute of Physics Publishing  2020
    Abstract
    Operation of solid oxide fuel/electrolysis cells (SOFC/SOEC) at high temperatures (T > 850 °C) is accompanied by degradation phenomena, which severely affect the operational lifetime of the cell. Degradation processes are expected to occur slower at low temperatures. However, significant reduction in electrocatalytic activity of the oxygen electrode, is one of the major challenges in decreasing the operating temperature down to 500 °C-650 °C. Recently, Pr6O11 infiltrated Ce0.9Gd0.1O2 (CGO) based electrodes have been proposed to realize high electrochemical performance at intermediate temperature. In this study, Pr-oxide has been infiltrated into a well performing sub-micro... 

    Doping of Sm3Ba5Cu8O19 compound with praseodymium

    , Article Journal of Low Temperature Physics ; Volume 198, Issue 5-6 , 2020 , Pages 252-268 Sandoghchi, M ; Akhavan, M ; Sharif University of Technology
    Springer  2020
    Abstract
    An investigation has been carried out on the effects of praseodymium doping in Sm3−xPrxBa5Cu8O19 for different values of x. Results indicate that the transition temperature reduces almost linearly with x. Based on the Abrikosov–Gor’kov pair-breaking theory, it has been concluded that the exchange interaction constant is large (Jex = 110 meV) in the Sm3Ba5Cu8O19 compound. In addition, it seems that the hybridization of Pr4f states with O2p–Cu3d states has an important role in the depression of transition temperature of Sm3−xPrxBa5Cu8O19 for the Pr content < 10%. However, for the higher values of Pr, the two observed plateaus at the transition temperatures of ~ 60 K and ~ 17 K, respectively,... 

    Ag Raman modes of RBCO (R = Gd, Pr) by density functional theory approach

    , Article European Physical Journal B ; Volume 51, Issue 2 , 2006 , Pages 161-165 ; 14346028 (ISSN) Khosroabadi, H ; Tavana, A ; Akhavan, M ; Sharif University of Technology
    2006
    Abstract
    Ab initio total energy calculations have been performed for superconducting GdBa2Cu3O7 and insulating PrBa 2Cu3O7 using the full-potential linear augmented plane-wave method in the local density approximation (LDA) and generalized gradient approximation (GGA). The comparison of the calculated unit cell volume and lattice parameters with the experimental data indicates the improvement of these parameters in the GGA relative to LDA. LDA and GGA give the equilibrium unit cell volume about 6% smaller and 1.25% larger than the experimental data, respectively for both systems. Thus frozen phonon calculations have been performed to determine the eigenvalues and eigenvectors of the k=0 Ag modes of... 

    Electronic and phonon structures of BaFe2As2 superconductor by Ab-initio density functional theory

    , Article Journal of Superconductivity and Novel Magnetism ; Volume 26, Issue 1 , January , 2013 , Pages 93-100 ; 15571939 (ISSN) Sandoghchi, M ; Khosroabadi, H ; Almasi, H ; Akhavan, M ; Sharif University of Technology
    2013
    Abstract
    Electronic and phonon structures of the BaFe2As2 superconductor in the magnetic-orthorhombic phase have been investigated by the ab-initio density functional theory using the pseudopotential Quantum Espresso code. Density of state and electronic band structure for this phase has been studied, but phonon dispersion has been obtained only for the nonmagnetic-orthorhombic phase. Electronic band structure and density of states are in good agreement with other calculations in the literature. The electronic state near the Fermi energy are essentially made from Fe3d and As4p orbital that indicate in-plane conductivity in FeAs layers in this system. Comparing calculated phonon dispersions with...