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Complexity of density dependencies of thermal and internal pressure compared to that of total pressure
, Article Industrial and Engineering Chemistry Research ; Volume 52, Issue 23 , May , 2013 , Pages 8034-8045 ; 08885885 (ISSN) ; Parsafar, G ; Sharif University of Technology
2013
Abstract
A simple equation of state (EoS) has recently been introduced (J. Phys. Chem. B2009, 113, 11977-11987) as (Z - 1)v2 = e + f/ρ + gρ2, where Z ≡ pv/RT is the compressibility factor, v = 1/ρ is molar volume, and e, f, and g are temperature dependent parameters. This EoS has been found to be accurate for all types of nano and bulk solids and bulk fluids, in the entire temperature and pressure ranges for which experimental data are reported, except for the isotherms within 1 ≤ T r = T/Tc ≤ 1.1 for the spherical and near spherical species and for a wider temperature range for the cylindrical molecules. The aim of this work is to investigate the validity of a three-term expression similar to the...