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pyridinium-derivative
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Efficient recyclable catalytic system for deoxygenation of sulfoxides: Catalysis of ionic liquid-molybdenum complexes in ionic liquid solution
, Article New Journal of Chemistry ; Volume 36, Issue 4 , Dec , 2012 , Pages 971-976 ; 11440546 (ISSN) ; Ghazali Esfahani, S ; Sharif University of Technology
2012
Abstract
Three newly synthesized room temperature ionic liquids containing molybdate anion, [DMIm][MoO 2(NCS) 4], [RPy][MoO 2(NCS) 4] (R = butyl or decyl), and previously reported [BMIm][MoO 2(NCS) 4] were used as catalysts for the reduction of sulfoxides. For facilitating the recyclability of the catalysts, the ionic liquids [RMIm][PF 6] and [RPy][PF 6] (RMIm = 1-n-alkyl-3-methylimidazolium, RPy = 1-n-alkylpyridinium) were applied as ionic solvents and toluene is used as solvent for the organic phase. Molybdenum salts immobilized in RTILs constituted a reusable and efficient heterogeneous catalyst system. A maximum conversion (>99%) was achieved for reduction of diphenyl sulfoxide to diphenyl...
Pyridinium salts - Versatile reagents for the regioselective synthesis of functionalized thiazocino[2,3-b]indoles by tandem dinucleophilic reactions of thiooxindoles
, Article Tetrahedron ; Volume 68, Issue 47 , 2012 , Pages 9685-9693 ; 00404020 (ISSN) ; Moghaddam, F. M ; Gormay, P. V ; Semeniuchenko, V ; Villinger, A ; Langer, P ; Iaroshenko, V. O ; Sharif University of Technology
2012
Abstract
The reaction of thiooxindoles with various 2- and 3-substituted pyridinium salts afforded a variety of functionalized thiazocinoindoles. The products have been prepared in good to excellent yields by regioselective dinucleophilic C/S-cyclocondensation of thiooxindoles with pyridinium salts