Sharif Digital Repository

Asphaltene deposition, the heaviest and most polar component of crude oil, which causes great economic damage inside the reservoir, near wells, pipelines and well equipment, is an important challenge in the production of oil reservoirs. The main purpose of this study is to prob the adsorption kinetics and the mechanism of asphaltene adsorption on the metal surface by a quartz crystal microbalance device under different conditions of temperature, flow rate and degree of asphaltene instability. In this study, indirect uv-vis spectroscopic method was used to determine the onset of asphaltene precipitation, then experiments were designed using Taguchi method. A new QCM device has been designed... 

Developing a simple, cost effective and accurate detection method for L-lysine (Lys), L-leucine (Leu) and glycine (Gly) as the important analytes in clinical diagnostics, biological processes and food industries is of great interest. Therefore, in the first part of this research, cellulose nanofibrils (CNFs) were coated on a quartz crystal microbalance (QCM) surface by spin coating to achieve a QCM biodetector for Gly. Thus, the two-layer CNFs coating was selected as sensing film and was applied for following experiments. In the next step, the coated QCMs were carefully characterized before and after interaction with Gly using water contact angle (WCA), Fourier transform infrared... 

Asphaltene deposition, considered as the heaviest and the most polarizable fraction of crude oil, can cause severe problems in oil production and extraction systems. Oil production companies annually bear huge reduction or even cessation in production and, in turn, costs due to asphaltene precipitation and deposition in wellbore or production tubings. To gain more and better insight into asphaltene formation in production systems, the conceptual investigation on the mechanisms of asphaltene adsorption and deposition on a solid surface is indispensable. In this study Asphaltene's particle adsorption and deposition onto the metal surface under the effect of flow is investigated by experimental... 

Asphaltene precipitation and deposition are sources of a number of problems for petroleum industry. Thus, solving the problem of precipitation and deposition is very important. In order to measure deposition level, study of other asphaltene flocculation is vital; since there is a time interval between precipitation and deposition. Use of chemical inhibitors is one of the best methods for prevention of asphaltene precipitation that could postpone precipitation point and prevent formation of huge flocculations. In this study, effects of asphaltene flocculation size on deposition with or without using inhibitors were investigated. In this regard, QCM was used for measuring the amount of... 

Inorganic scale deposition has been found to affect many industrial processes,including water injection into the oil reservoirs. Major formation damage because of incompatibility of high sulfate ion content of seawater with formation water containing calcium ion results in formation damage and production decline.In this study, several simultaneous techniques are utilized for qualitative and quantitative analysis of calcium sulfate scale to get more insight into the damage of formation during smart water flooding at micro and Nano scales. In the experimental section, calcium sulfate deposition due to the mixing of the formation water and seawater samples was investigated using the dynamic... 

Quartz crystal microbalance (QCM) is a piezoelectric sensor used to measure the mass of adsorbent deposition at the nanoscale on the surface, real-time and non-destructively. The QCM technique has recently gained extensive attention in the chemical and oil industries and other research fields such as medicine and nanotechnology due to its various applications in the advanced sciences. This technique provides comprehensive insights to scientists in the field of phase equilibrium of low-solubility and solid-liquid interactions. Therefore, many attempts have been made to investigate the interaction phenomenon mechanistically using QCM.Scale formation can have many adverse effects, and... 

Developing a simple, cost effective and accurate detection method for L-lysine (Lys), L-leucine (Leu) and glycine (Gly) as the important analytes in clinical diagnostics, biological processes and food industries is of great interest. Therefore, in the first part of this research, cellulose nanofibrils (CNFs) were coated on a quartz crystal microbalance (QCM) surface by spin coating to achieve a QCM biodetector for Gly. Thus, the two-layer CNFs coating was selected as sensing film and was applied for following experiments. In the next step, the coated QCMs were carefully characterized before and after interaction with Gly using water contact angle (WCA), Fourier transform infrared... 

The study of low-salinity water flooding or smart water flooding as secondary or tertiary oil recovery methods started in 1960 and many researchers have studied the effect of ions types on asphaltene precipitation/deposition during the injecting water into the oil reservoirs. To reduce the asphaltene challenges, one needs to properly investigate this phenomenon and better understanding of the cause of precipitation. It is already known that the amount of asphaltene deposition can be reduced by controlling the deposition criteria. For example, water microemulsion in the oil phase would cause the asphaltenes to be adsorbed on the water oil interface by hydrogen bonds due to heteroatom... 

In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. The main objective of this study is to contribute to the thermodynamic and transport modeling of asphaltene in order to predict its precipitation, aggregation and deposition. For a better knowledge of the flow properties of asphaltene containing crude oils, it is necessary to understand how asphaltene affect the rheological properties. In this work, the information on such rheological properties of oil-asphaltene slurry systems is provided. The results of rheological experiments for two Iranian crude oils show that the...