Sharif Digital Repository

The environmental and economic benefits of recycling asphalt pavements have received much attention in recent years. Because of the increase in the cost of raw materials and energy carriers, the reuse of large portions of reclaimed asphalt pavement (RAP) is critical in reducing both the cost and environmental footprint of asphalt pavements. High-RAP mixtures are more prone to low temperature cracking and poor mixture workability because of the higher stiffness of RAP binder. Recycling agents are one of the additives which are used to improve these deficiencies. However, there is some ambiguity about the optimum content of recycling agent to assure proper performance of recycled asphalt... 

A highly efficient and simple procedure for the synthesis of quinazolin-4(3H)-ones from the condensation of 2-aminobenzamide with triethylorthoesters in presence of a catalytic amounts of heteropolyacids in various solvents is reported  

In this study, the reusability and process stability of nano-reengineered horseradish peroxidase was investigated in a fluorescence-based sensing system for hydrogen peroxide determination as a model application. To this end, dendron macromolecules were attached to the enzyme surface through bio-conjugation techniques. The resulting enzyme-polymer nanoparticles, with an average size of 14(±2) nm, showed significant life time and thermal stability. For enzyme recovery and reusability purposes, the enzyme-polymer nanoparticles were labelled with magnetic nanoparticles with a labelling yield of 90 %. These labelled enzyme molecules showed significant process stability, i.e., up to 7 recycling... 

The thermal decomposition of manganese and cobalt-terephthalate Metal-Organic Framework precursors was utilized as a synthetic route for fabrication of Co3O4, Mn3O4 and Mn2O3 nanoparticles. The prepared metal oxide nanoparticles of Co3O4, Mn3O4 and Mn2O3 possess average size diameter of 40, 60 and 80 nm respectively. The findings demonstrate that spinel structure nanoparticles of Co3O4 and Mn3O4 exhibit efficient catalytic activity toward heterogeneous olefin epoxidation in the presence of tert-butyl hydroperoxide. In... 

A simple and mild procedure for the trimethylsilylation of a wide variety of phenols with hexamethyldisilazane (HMDS) on the surface of silica gel dispersed with NaHSO4 at r.t. in a few minutes with excellent yields under neutral conditions is reported. This procedure also allows an excellent selectivity for the silylation of phenols in the presence of amine and CO 2H groups  

In this paper, a numerical simulation involving fluid flow and heat transfer is presented in order to improve the understanding of rotary furnaces. The finite element model is employed to simulate the furnace rotation and analyse the energy flows inside the furnace. A transient dynamic analysis is carried out to predict the evolution and distribution of temperatures in a rotary furnace by modelling and analysing the furnace under different flame positions. The finite element modelling system ELFEN is used to develop models of the furnace. The results clearly indicate the temperature distribution for different angular velocities along with a comparison of temperature variation under different... 

Nowadays, applying sustainable development strategies in designation and production of various products has attracted specific attention. In order to consider ecological sustainable development for a product, reducing its environmental impacts should be observed. Concrete technology and its products are not exceptions, and therefore, the same has been a concern for concrete industry. Alongside, concrete recycling is one of the measures used to reduce the environmental impacts of concrete products during their life cycle. On the other side, positive performance of silica nano-particles has been proven in numerous researches as one super pozzolanic material. Hence, in this study, we aimed on... 

A very efficient and mild procedure for the trimethylsilylation of a wide variety of alcohols, including primary, allylic, benzylic, secondary, hindered secondary, tertiary, and phenols with hexamethyldisilazane on the surface of silica gel dispersed with LiClO4 in room temperature at few minutes in excellent yields under neutral conditions is reported. This procedure also allows the excellent selectivity under LP-SiO2 system for silylation of alcohols in the presence of amine and phenolic hydroxy groups  

This research aims to expand the body of information that researchers require before starting electronic waste (E-waste) recovery experiments. With this purpose, the basic metal contents, alkalinity, polymer components, iron magnetic separation, metal recovery priority and economic values of different types of waste printed circuit boards (PCBs) were investigated. The selected wastes were computer PCBs (CPCBs), CPCBs with wires, mobile phone PCBs (MPPCBs), television PCBs (TVPCBs), fax machine PCBs (FPCBs), copy machine PCBs (COPCBs) and central processing units (CPUs). These E-wastes were prepared in the three fraction sizes of F1<1 mm, 1 < F2<3 mm, and 3 < F3<8 mm to evaluate the metal... 

In this report, the possibility of recovering zinc oxide from zinc containing wastes, also the effect of temperature, time and depth of bed on recycling has been studied. Zinc oxide with a purity of 93.5% was obtained  

In this paper, a robust design method is developed for reducing cost and improving quality in aluminium recycling. An experimental investigation into the process parameter effects is presented to determine the optimum configuration of design parameters for performance, quality and cost. The Taguchi method is applied initially to plan a minimum number of experiments. Orthogonal array techniques are used to investigate the simultaneous variation of several parameters and the investigation of interactions between parameters. Matrix experiments using standard L4 and L9 orthogonal arrays are employed to evaluate the effects of parameters in recycling of aluminium dross and scrap materials. A... 

The fracture behavior of a hybrid-rubber-modified epoxy system was investigated. The modified epoxy included amine-terminated butadiene acrylonitrile (ATBN) rubber and recycled tire particles as fine and coarse modifiers, respectively. The results of the fracture toughness (K IC) measurement of the blends revealed synergistic toughening in the hybrid system when 7.5-phr small particles (ATBN) and 2.5-phr large particles (recycled tire) were incorporated. Transmission optical micrographs showed different toughening mechanisms for the blends; fine ATBN particles increased the toughness by increasing the size of the damage zone and respective plastic deformation in the vicinity of the crack... 

Binary blends of recycled high-density polyethylene (R-HDPE) with poly(ethylene terephthalate) (R-PET) and recycled polystyrene (R-PS), as well as the ternary blends, i.e. R-HDPE/R-PET/R-PS, with varying amounts of the constituents were prepared by twin screw extruder. The mechanical, rheological, thermal, and scanning electron microscopy (SEM) analyses were utilized to characterize the samples. The results revealed that both R-HDPE/R-PET and R-HDPE/R-PS blends show phase inversion but at different compositions. The R-PET was found to have much higher influence on the properties enhancement of the R-HDPE compared to R-PS, but at the phase inverted situation, a significant loss in the tensile... 

This study addresses the issue of using recycled materials to obtain low-cost structural products for practical applications. Through the use and re-extrusion of virgin high-density polyethylene (HDPE), the effects of the degradation level of HDPE as a matrix phase on its mechanical properties and the mechanical performance of composites produced with the degraded polyethylene have been examined. The degradation level of HDPE caused by reextrusion has been evaluated by the measurement of the melt flow index and mechanical properties of virgin and degraded HDPEs. The results indicate that the modulus and strength of HDPE significantly increase with the addition of polypropylene filled with 30... 

Rotating dissolved air flotation (RDAF) has been utilized for several decades in paper-recycling wastewater treatment; however, it has rarely been addressed in the literature, which makes research into this system challenging and complicated. However, in this work, a full-scale industrial wastewater treatment system for a paper-recycling mill in Mazandaran province, Iran, was evaluated. Experiments indicated that under the same wastewater and chemical conditions, there are differences in the removal efficiencies. This finding was investigated by conducting simulation in ANSYS CFX R18.0 and experimentation simultaneously. Thus, the main purpose of this research was to optimize the operation... 

Different aliphatic and aromatic aldehydes such as isobutyraldehyde, ethanal, n-propanal, n-butanal, n-hexanal, n-octanal, and substituted benzaldehydes were cyclotrimerized into their corresponding 2,4,6-trialkyl-1,3, 5-trioxanes in the presence of commercial bulk zinc oxide at room temperature under neat conditions within a short span of time with high yield and excellent selectivity. Liquid products were formed as a separate phase and were decanted easily, whereas solid products were isolated by simple extraction. Effect of different additives, mol % of catalyst, kind of substrate, and reaction temperature were examined on the progress of cyclotrimerization reaction  

Three newly synthesized room temperature ionic liquids containing molybdate anion, [DMIm][MoO 2(NCS) 4], [RPy][MoO 2(NCS) 4] (R = butyl or decyl), and previously reported [BMIm][MoO 2(NCS) 4] were used as catalysts for the reduction of sulfoxides. For facilitating the recyclability of the catalysts, the ionic liquids [RMIm][PF 6] and [RPy][PF 6] (RMIm = 1-n-alkyl-3-methylimidazolium, RPy = 1-n-alkylpyridinium) were applied as ionic solvents and toluene is used as solvent for the organic phase. Molybdenum salts immobilized in RTILs constituted a reusable and efficient heterogeneous catalyst system. A maximum conversion (>99%) was achieved for reduction of diphenyl sulfoxide to diphenyl... 

A mesophilic iron oxidizing bacterium, Acidithiobacillus ferrooxidans, has been isolated (33 °C) from a typical chalcopyrite copper concentrate of the Sarcheshmeh copper mine in the region of Kerman located in the south of Iran. In addition, a thermophilic iron oxidizing bacterium, Sulfobacillus, has been isolated (60 °C) from the Kooshk lead and zinc mine near the city of Yazd in central Iran. Effects of some variable parameters such as solids concentration, temperature and pH on the bioleaching of chalcopyrite obtained from Sarcheshmeh copper mine were investigated. Bioleaching experiments were carried out in two batch airlift bioreactors with a recycling stream. The results indicate that...