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    Oxidative desulfurization of Non-hydrotreated kerosene using hydrogen peroxide and acetic acid

    , Article Chinese Journal of Chemical Engineering ; Volume 17, Issue 5 , 2009 , Pages 869-874 ; 10049541 (ISSN) Molaei Dehkordi, A ; Sobati, M. A ; Nazem, M. A ; Sharif University of Technology
    2009
    Abstract
    The oxidative desulfurization of a real refinery feedstock (i.e., non-hydrotreated kerosene with total sulfur mass content of 0.16%) with a mixture of hydrogen peroxide and acetic acid was studied. The influences of various operating parameters including reaction temperature (T), acid to sulfur molar ratio (nacid/nS), and oxidant to sulfur molar ratio (nO/nS) on the sulfur removal of kerosene were investigated. The results revealed that an increase in the reaction temperature (T) and nacid/nS enhances the sulfur removal. Moreover, there is an optimum nO/nS related to the reaction temperature and the best sulfur removal could be obtained at nO/nS8 and 23 for the reaction temperatures of 25...