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      Synthesis and characterization of a new zwitterionic palladium complex as an environmentally friendly catalyst for the Heck-Mizoroki coupling reaction in GVL

      , Article Molecular Catalysis ; Volume 474 , 2019 ; 24688231 (ISSN) Bagherzadeh, M ; Mahmoudi, H ; Ataie, S ; Bahjati, M ; Kia, R ; Raithby, P. R ; Vaccaro, L ; Sharif University of Technology
      Elsevier B.V  2019
      Abstract
      A new zwitterionic Palladium (II) complex has been synthesized by the one-pot mixing of Pd(OAc)2, 2-aminophenol and (3-formyl-4-hydroxy-5-methylbenzyl) triphenylphosphonium chloride, in refluxing ethanol. The metal complex formed was characterized by 1H NMR, 13C NMR, 31P NMR and X-ray crystallographic technique and its efficiency tested as a homogeneous pre-catalyst in Heck-Mizoroki cross coupling reaction using γ-Valerolactone (GVL) as a biomass-derived green medium. All the products were obtained in good to excellent yields. © 2019  
    Total 1 records