Sharif Digital Repository

Simultaneous water and CO2 injection has been performed on a sandstone core to evaluate oil recovery under the secondary and tertiary near-miscible injection modes. It is demonstrated that secondary SWACO2 injection as well as tertiary flood is an effective method for the oil/residual oil recovery from oil saturated/water-flooded porous media. In the secondary SWACO2 injection, the ultimate oil recovery increases by increasing SWAG ratio from 0.2 to 0.4 but due to some limits, e.g. topological effects, prohibiting contacting of injected gas with residual oil in pores, altering SWAG ratio from 0.4 to 0.6 showed no effect on ultimate oil recovery. Secondary SWACO2 injection can recover higher... 

Most investigations showed that the prevalent thermodynamic models are incapable of predicting asphaltene precipitation without extensive data fitting. This is primarily due to lack of knowledge of the asphaltene properties, its complex nature and the large number of parameters affecting precipitation. Hece, several authors tried to generate a simple and universe mathematical model in order to predict the amount of asphaltene precipitation. In spite of these efforts, the authors only considered temperature and type of solvents as the effective parameters in generating their scaling equations. The major disadvantage of these models is their inability in predicting the amount of asphaltene... 

We have used the Maxwell-Stefan diffusion theory to model the mass transfer between tertiary-injected gas and residual oil blocked by water, in order to predict the time required for the rupture of the water barrier due to oil swelling. We have also designed and conducted a set of visualization micromodel experiments on various pure and multicomponent oil-gas systems to measure the water rupture time in tertiary gas injection processes. The experimental results show that the initial pressure and dimensions of the system, the oil and gas composition, and the gas solubility in water control the oil swelling process. The experimentally measured rupture times are then employed to evaluate the... 

The amount of residual oil trapped in the matrix of a fractured reservoir after water drive, either natural water drive or water injection, depends on the wettability of the matrix rocks. Gas oil gravity drainage (GOGD) has been proposed as the tertiary oil recovery process for this type of oil reservoir. The current work focuses on experimental investigation of tertiary GOGD in fractured porous media under different types of matrix wettability. Results of a set of experiments performed in artificial porous media composed of sand packs and glass beads of different wettability have been used to check the GOGD rate and the ultimate oil recovery for previously waterflooded models. A novel... 

Dilute Surfactant flooding has been recognized as one of the significant processes in chemical flooding. Many oil reservoirs became appropriate candidates for surfactant/water flooding when screening criteria was developed. Injected surfactant tried to mobilize the residual oil that was trapped in interstice. The main contributing mechanism to enhance oil recovery by surfactant flooding was defined as rock wettability alteration. Wettability is one of the substantial parameters to choose the best approach for a successful surfactant flooding in which tiny change in wettability will lead to improve oil recovery fundamentally. In this experimental study the effect of different aging time and... 

This work concerns simultaneous determination of relative permeability, capillary pressure, pore size distribution (PSD), and residual oil saturation data by optimization of well testing data, and introduces a new capillary pressure relationship, based on the Weibull distribution function, for direct determination of the PSD function from capillary pressure parameters. Three consecutive injection, fall off, and production well tests are performed on a predefined synthetic reservoir through simulation, and an optimization algorithm is used to find the parameters of relative permeability and capillary pressure curves as well as the value of residual oil saturation. The PSD function is also... 

The strength of a newly formulated surfactant with an alkali and polymer (AS/ASP) to improve an acidic heavy oil recovery was laboratory evaluated by various flooding experiments. The comparative role of the parameters like chemical nature, surface wettability, salinity, temperature and injection scheme were explored at high temperature and pressure on Berea sandstone rocks. According to the results the anionic surfactant is capable of providing proper oil displacement under high salinity conditions around 15 wt%. Continuous monitoring of differential pressure response and effluents’ state clearly represented the formation of an emulsified oil in high saline solutions with both alkali and... 

In order to understand the potential role of divalent ions involved in smart water, fluid-fluid and rock-fluid interactions are studied through contact angle and interfacial tension (IFT) measurements. Then, the suitable brines in changing contact angle and IFT are brought into measurement with spontaneous imbibition experiments to evaluate the co-impact of fluid-fluid and rock-fluid interactions. The results show the importance of SO42− ions during smart water injection as removing them from the injection water leads to a sharp drop in ultimate oil recovery. Accordingly, when the concentration of SO42− within the injection water increases four times, 10% ultimate oil recovery is recovered.... 

Microbial enhanced oil recovery (MEOR) is receiving renewed interest worldwide in recent years as a viable method while not damaging the reservoir is proven to be remarkably effective, however to some extent costly. This method is based on microorganisms' activities to reduce residual oil of reservoirs, which is dependent on behavior of inherent microorganisms or injection of bioproduct of external microorganisms. In this work, five bacterial species were taken from MIS crude oil that is one of the aging Persian fractured reservoirs. These microorganisms are substantially strong in increasing oil recovery especially by reducing IFT and other MEOR mechanisms such as change of wettability of... 

Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

This study concerns with the microscopic and macroscopic fluid distribution and flow behavior during water alternating solvent (WAS) injection process to heavy oil using micromodel generated from thin section of a real rock which has rarely attended in the available literature. In this study, a one-quarter five-spot glass micromodel was deployed to examine the effect of flow media topology on microscopic displacements as well as macroscopic efficiency of WAS process. The micromodel was initially saturated with the heavy oil, and then the hydrocarbon solvent and water were injected alternately into it. The observations confirmed that WAS injection scheme is an effective method for the... 

Displacement experiments of the gas-oil system are performed on long core scale models by varying the petrophysical properties and flowing conditions. Experiments are conducted in situations where capillary, gravity and viscous forces are comparable. From oil production history and picture analysis, the threshold for the stability is determined. The experimental findings are comparable to the results of a gradient percolation theory. The effect of destabilized front velocity on relative permeability and residual saturation is investigated. The relative permeabilities determined by using analytical and numerical approaches indicate that higher displacement velocity leads to a higher gas... 

Low salinity waterflooding (LSWF) is a process in which by lowering the ionic strength and/or manipulation of the composition of the injection water, the long term equilibrium in oil/brine/rock system is disturbed to reach a new state of equilibrium through which the oil production will be enhanced due to fluid/fluid and/or rock/fluid interactions. In spite of recent advances in the simulation of the LSWF at core scale and beyond, there are very few works that have modelled and simulated this process at the pore scale specially using direct numerical simulation (DNS). As a result the effects of wettability alteration and/or Interfacial Tension (IFT) change on the distribution of the phases... 

A bacterial strain was isolated and cultured from the oil excavation areas in tropical zone in southern Iran. It was affiliated with Pseudomonas. The biochemical characteristics and partial sequenced 16S rRNA gene of isolate, MR01, was identical to those of cultured representatives of the species Pseudomonas aeruginosa. This bacterium was able to produce a type of biosurfactant with excessive foam-forming properties. Compositional analysis revealed that the extracted biosurfactant was composed of high percentages lipid (∼65%, w/w) and carbohydrate (∼30%, w/w) in addition to a minor fraction of protein (∼4%, w/w). The best production of 2.1 g/l was obtained when the cells were grown on...