Sharif Digital Repository

The hot deformation characteristics of 7075 aluminum alloy (AA7075) are investigated by means of hot compression tests carried out in the temperature range of 200-450 C and strain rate range of 0.0003-1 s-1. Two novel processing maps based on flow localization parameter and enhanced DMM are developed and compared with conventional DMM results. It is observed that processing maps based on flow localization parameter can be used successfully to predict AA7075 thermomechanical behavior. Also, the comparison of the DMM results indicates that the new approach to calculate DMM power dissipation efficiency and instability criteria corresponds better with experimental observations. The occurrence of... 

Linear and nonlinear (in both steady and transient shear flows) rheological properties of polyamide 6/acrylonitrile-butadiene-styrene (PA6/ABS) nanocomposite blends have been investigated. Characterization of nanocomposite samples morphology by scanning electron microscopy revealed that with increasing nanoclay loading, size of dispersing phase droplets decreases significantly and their uniformity improved considerably. Transmission electron microscopy observations clearly display a coexistence of intercalate and exfoliate structure for nanoclay in the polymer-blend nanocomposite. On the other hand, we see that the tactoids are collected of a few silicate layers and possibly also of a single... 

Application of the colloidal gas aphrons (CGAs) in minimizing formation damage by plugging pore mechanism is now wildly accepted due to numerous successful field experience. One of the pivotal factors which affects the pore blockage ability of micro-bubbles is their stability. This experimental study tries to investigate the possible synergistic effect of nanoparticles on improving the stability and other properties of non-aqueous CGA drilling fluids, in both bulk and porous media. In particular, two types of hydrophobic nanoparticles including silicon dioxide nanopowder coated with 2 wt% Silane and nanoclay, in presence of a treated version of bentonite (Bentone 34) as a stabilizer and... 

Despite the fact that hydrophobic nanosilica can improve the stability of water/oil emulsion, there exist controversies pertaining to its influence on oil-based drilling fluid rheological behavior and the subsequent formation damage. The present study addresses the above using a surface modified nanosilica, where the particles were functionalized with different silane-based groups to alter their hydrophilicity: 3-glycidoxypropyl-triethoxy silane (GPTS) and combined GPTS and propyl silane (PGPTS). The NPs were characterized through FTIR analysis, particle size, and zeta-potential measurements followed by flow behavior experiments, core-scale mud flow tests, Computed Tomography (CT) scanning... 

The presence of asphaltene means additional difficulties related to transport and processing due to the increased crude oil viscosity caused by the asphaltene. For a better knowledge of the flow properties of asphaltene containing crude oils, it is necessary to understand how asphaltene affects the rheological properties. The aim of this article is to provide information on such rheological properties of oil-asphaltene slurry systems. The results of rheological experiments show that the non-Newtonian flow curves can be approximated by the Bingham plastic model to determine the apparent viscosity and the yield stress as a function of asphaltene concentration and temperature. An explanation is... 

Gelcasting, as a ceramic forming technique, is getting worldwide attention, in that it can be used to make high-quality, complex-shaped ceramic parts with a wide range of powders. However, a model, which can appropriately describe the shear rate dependence behavior of the slurry in casting process simulation, is limited. Therefore, this study mainly sought to investigate the best model representing the behavior of as-prepared gelcast slurry. A premix solution was prepared with monomer/cross linker of AM/MBAM with ratio of 25:1. In this procedure, ammonium polyacrylate sodium (NHPANa) was used as the dispersant and the solid load included Al2O3/20 vol% ZrO2 powder mixture. Series of slurries... 

This paper presents a new landslide-generated wave (LGW) model based on incompressible Euler equations with Savage-Hutter assumptions. A two-layer model is developed including a layer of granular-type flow beneath a layer of an inviscid fluid. Landslide is modeled as a two-phase Coulomb mixture. A well-balanced second-order finite volume formulation is applied to solve the model equations. Wet/dry transitions are treated properly using a modified non-linear method. The numerical model is validated using two sets of experimental data on subaerial and submarine LGWs. Impulsive wave characteristics and landslide deformations are estimated with a computational error less than 5 %. Then, the... 

Master curves of asphalt binders and mixtures have been traditionally used to evaluate their rheological behavior in the linear viscoelastic range. Different analytical models are available to describe the master curves of bituminous binders and mixtures. No models are currently considered universal for all modeling purposes. In this research, the general structure and capabilities of some of the most commonly used analytical models were investigated. Then, based on the patterns of phase angle master curves of ten neat and modified asphalt binders, four groups of master curve shapes were defined. The goodness of fit of the models for the different groups of master curves was used to develop... 

In this paper, the flow behavior of Leonov-Like conformational rheological model, which has root in the generalized Poisson bracket formalism based on the conformation tensor, have been studied in the circular die flow. Prediction of the normal stress differences during the flow of these fluids lets us to follow and calculate relaxation dependent phenomena such as die swell. The model predictions have been compared for the four families of mobility expressions. The Study of the model prediction sensitivity to its mobility term shows that model predictions can cover a wide range of rheological behaviors generally observed for polymer melts and solutions in the circular die flow. Copyright ©... 

Nanofluids are widely used as the continuous phase during droplet formation in microsystems due to their impressive features such as excellent thermal, magnetic, and interfacial properties. Although it is well-known that nanofluids are susceptible to exhibit non-Newtonian behavior even at a low concentration of nanoparticles, effects of non-Newtonian behavior of nanofluids have not been studied on droplet formation thus far. In this study, oil-in-water droplet formation with a relatively high viscosity ratio of the immiscible phases was studied numerically in a T-junction microchannel. To inspect the non-Newtonian effects of aqueous nanofluids on droplet formation, empirical data on the... 

Herein, poly (acrylic acid) (PAA) microgels were synthesized via alcohol type cross-linked by a free radical precipitation polymerization approach. At the first time, 1,6-hexanediol (1–6 diol), trimethylolpropane (TMP), and pentaerythritol (PEN) were selected as multifunctional cross- linking agent to synthesize cross-linked poly(acrylic acid) microgels. Alcohol type cross-linking agents can connect the PAA chains. The cross-linking reaction takes place due to reaction between hydroxyl groups of various cross-linkers and carboxyl groups of PAA chains. All of the hydroxyl groups do not participate in the reaction with acid groups of polymer chains through the polymerization stage; therefore,... 

This paper numerically studies the interaction of a flowing granular material with an entrainable granular bed, while materials are mixed at the interface of two materials. The rheological behavior of this granular mixture is characterized by a generalized viscoplastic model that includes local volume fraction of materials as well as their physical properties, i.e. size, density, and friction angle. Additionally, the effect of the dynamics of entrained bed-type particles on the rheology of the granular mixture is considered. The governing equations of the flow are discretized using the Incompressible Smoothed Particle Hydrodynamics (SPH) method in which mixing of particles can be... 

Rheological behavior of two crude oils and their surfactant-stabilized emulsions with initial droplet sizes ranging from 0.5 to 75 μm were investigated at various temperatures under steady and dynamic shear testing conditions. In order to evaluate the morphology and Stability of emulsions, microscopic analysis was carried out over three months and average diameter and size distribution of dispersed droplets were determined. The water content and surfactant concentration ranged from 10 to 60% vol/vol and 0.1 to 10% wt/vol, respectively. The results indicated that the rheological properties and the physical structure and stability of emulsions were significantly influenced by the water content... 

The biomicrofluidic devices utilizing electrophoresis for sample manipulation are usually encountered with non-Newtonian behavior of working fluids. Hence, developing theoretical models capable of predicting the electrophoretic velocity of colloidal particles in non-Newtonian fluids is of high importance for accurate design and active control of these devices. The present investigation is dealing with the electrophoresis of a spherical particle in a biofluid obeying the Quemada rheological model. The sphere radius is considered to be significantly larger than the Debye length. Moreover, it is assumed that the particle zeta potential is small so that the Debye-Hückel linearization is... 

The use of polymer flooding as one of enhanced oil recovery methods has recently increased. The occurrence of high shear rates in reservoir and near well bore through perforation nozzles during polymer flooding cause shear degradation of polymers and therefore polymer viscosity has decreased. Rheological behavior of polymer solution in different conditions of oil reservoir is one of the key factors to develop use of polymer solutions. A few researches are available regarding improving rheological behavior of polymeric solution. In this study, to investigate the effect of nanoparticles on rheological behavior of polymer solutions two samples were prepared: polyacrylamide solution in water and... 

This research deals with the numerical simulation of two viscoelastic uids ow in an open capillary of a reservoir. Oldroyd-B and Leonov models have been used to describe the rheological behavior of polymer solutions. The finite volume method on a structured and collocated grid has been used for discretization of the governing equations. The discrete elastic viscous stress splitting technique has also been used. The steady state, isothermal and incompressible uids past through a two dimensional micropore have been considered. The numerical method has been validated through the comparison of numerical results by the analytical solutions of Oldroyd-B uid ow through a planar channel. The effects... 

The objective of this study was to investigate the effects of two compatibilizers, namely maleated polypropylene (PP-g-MA) and maleic anhydride grafted poly (ethylene-co-octene) (EOC-g-MA), on the morphology and thus properties of ternary nanocomposites of polypropylene (PP)/ethylene-octene copolymer (EOC)/clay nanocomposite. In this regard the nanocomposites and their neat polymer blend counterparts were processed twice using a twin screw extruder. X-ray diffraction, transmission electron microscopy, Energy dispersive X-ray spectroscopy, and scanning electron microscopy were utilized to characterize nanostructure and microstructure besides mechanical and rheological behaviors of the...